Citation: Tong-Sheng YANG, Renagul ABDURAHMAN, Qian-Ting YANG, Xue-Feng SUN, Gang-Hui CHU. Preparation and Optical Properties of Size Controllable Near-Infrared Emitting Zn_1.4Ga_1.97-2xO₄∶1.5%Cr, xIn Persistent Luminescent Nanoparticles[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(3): 449-458. doi: 10.11862/CJIC.2022.049 shu

Preparation and Optical Properties of Size Controllable Near-Infrared Emitting Zn_1.4Ga_1.97-2xO₄∶1.5%Cr, xIn Persistent Luminescent Nanoparticles

Laboratory of Xinjiang Native Medicinal and Edible Plant Resources Chemistry, College of Chemistry and Environmental Science, Kashi University, Kashi, Xinjiang 844006, China

Corresponding author: Renagul ABDURAHMAN, renagul111@aliyun.com Gang-Hui CHU, cghks5@126.com
Received Date: 23 September 2021
Revised Date: 10 January 2022

Figures(8)

Size controllable near infrared-emitting ZGO∶1.5%Cr, xIn (Zn_1.4Ga_1.97-2xO₄∶1.5%Cr, xIn, x=0%, 0.1%, 0.2%, 0.3%, 0.4%, 0.5%) persistent luminescent nanoparticles (PLNPs) were prepared via a facile one-step hydrothermal method. The size and persistent luminescence properties of ZGO∶1.5%Cr, xIn PLNPs depended on codoping amounts of In³⁺.The results showed that when the doping amount of In³⁺ was 0.2%, the average particle size of ZGO∶1.5%Cr, xIn PLNPs was the smallest (13.79 nm), and the NIR luminescence was the strongest. The afterglow time was estimated for 5 d, and can be re-excited by LED lamp. ZGO∶1.5%Cr, xIn PLNPs were pure spinel structure, and the doping of In³⁺ did not affect the crystal structure of PLNPs.
- persistent luminescent nanoparticles,
- size controllable,
- In³⁺ doping
1. [1]
  Li X, Zhang H B, Zhang C Y, Huang C, Wei J. Time-Dependent Pho-toluminescence Patterns Based on Cr³⁺-Doped and Co-doped Zn₃Ga₂Ge₂O₁₀[J]. J. Photochem. Photobiol. A, 2021,418113403. doi: 10.1016/j.jphotochem.2021.113403
2. [2]
  Lécuyer T, Teston E, Ramirez-Garcia G, Maldiney T, Viana B, Seguin J, Mignet N, Scherman D, Richard C. Chemically Engineered Persis-tent Luminescence Nanoprobes for Bioimaging[J]. Theranostics, 2016,6(13):2488-2524. doi: 10.7150/thno.16589
3. [3]
  LIU W G, ABDURAHMAN R, AIWAILI R. Research Progress in Modification of Long afterglow Nanoparticles[J]. Micronanoelectronic Technology, 2021,58(11):976-984.
4. [4]
  YANG Q T, ABDURAHMAN R, YAN Y, MAIMAITYIMIN G. Appli-cation of Cr³⁺ Doped Long Afterglow Luminescent Nanoparticles in Biomedical Research[J]. Laser & Optoelectronics Progress, 2021,58(8)0800003.
5. [5]
  Pei P, Chen Y, Sun C X, Fan Y, Yang Y M, Liu X, Lu L F, Zhao M Y, Zhang H X, Zhao D Y, Liu X G, Zhang F. X-ray-Activated Persistent Luminescence Nanomaterials for NIR-Ⅱ Imaging[J]. Nat. Nanotechnol., 2021,16:1011-1018. doi: 10.1038/s41565-021-00922-3
6. [6]
  Li Y J, Yan X P. Synthesis of Functionalized Triple-Doped Zinc Gallo-germanate Nanoparticles with Superlong Near-Infrared Persistent Luminescence for Long-Term Orally Administrated Bioimaging[J]. Nanoscale, 2016,8(32):14965-14970. doi: 10.1039/C6NR04950H
7. [7]
  Abdurahman R, Yang C X, Yan X P. Conjugation of a Photosensitizer to Near Nnfrared Light Renewable Persistent Luminescence Nanopar-ticles for Photodynamic Therapy[J]. Chem. Commun., 2016,52(90):13303-13306. doi: 10.1039/C6CC07616E
8. [8]
  Wei X J, Huang X D, Zeng Y, Jing L H, Tang W, Li X N, Ning H R, Sun X D, Yi Y P, Gao M Y. Longer and Stronger: Improving Persistent Luminescence in Size-Tuned Zinc Gallate Nanoparticles by Alcohol-Mediated Chromium Doping[J]. ACS Nano, 2020,14(9):12113-12124. doi: 10.1021/acsnano.0c05655
9. [9]
  Gong Z, Liu Y X, Yang J, Yan D T, Zhu H C, Liu C G, Xu C S, Zhang H. A Pr³⁺ Doping Strategy for Simultaneously Optimizing the Size and Near Infrared Persistent Luminescence of ZGGO: Cr³⁺ Nanoparticles for Potential Bio-Imaging[J]. Phys. Chem. Chem. Phys., 2017,19(36):24513-24521. doi: 10.1039/C7CP02909H
10. [10]
  ABDUKEUMU A, TURDI A, ABDURAHMAN R, TURSON M, NURMAITI N. Preparation and Luminescence Properties of Dy, Cr Co-doped ZnGa₂O₄ Long Afterglow Nanoparticles[J]. J. Inorg. Mater., 2016,31(12):1363-1369.
11. [11]
  Verma S, Chand J, Singh M. Effect of In³⁺ Ions Doping on the Struc-tural and Magnetic Properties of Mg_0.2Mn_0.5Ni_0.3In_xFe_2xO₄ Spinel Fer-rites[J]. J. Magn. Magn. Mater., 2012,324(20):3252-3260. doi: 10.1016/j.jmmm.2012.04.053
12. [12]
  Patel D K, Girija K G, Naidu B S, Vishwanadhd B, Sayede F N, Vatsaa R K, Sudarsana V, Kulshreshtha S K. In³⁺ Doped ZnGa₂O₄ Nanoparticles: Difference in the Luminescence Properties upon Opti-cal and Electrical Excitations[J]. J. Alloys Compd., 2021,884161021. doi: 10.1016/j.jallcom.2021.161021
13. [13]
  Kolekar C B, Kamble P N, Vaingankar A S. Structural and Dc Elec-trical Resistivity Study of Gd³⁺-Substituted Cu-Cd Mixed Ferrites[J]. J. Magn. Magn. Mater., 1994,138:211-215. doi: 10.1016/0304-8853(94)90418-9
14. [14]
  Sen S K, Paul T C, Dutta S, Hossain M N, Mia M N H. XRD Peak Profle and Optical Properties Analysis of Ag-Doped h-MoO₃ Nanorods Synthesized via Hydrothermal Method[J]. J. Mater. Sci. Mater. Electron., 2020,31(2):1768-1786. doi: 10.1007/s10854-019-02694-y
15. [15]
  Allix M, Chenu S, Véron E, Poumeyrol T, Kouadri-Boudjelthia E A, Alahraché S, Porcher F, Massiot D, Fayon F. Considerable Improve- ment of Long-Persistent Luminescence in Germanium and Tin Sub-stituted ZnGa₂O₄[J]. Chem. Mater., 2013,25(9):1600-1606. doi: 10.1021/cm304101n
16. [16]
  Abdukayum A, Yang C X, Zhao Q, Chen J T, Dong L X, Yan X P. Gadolinium Complexes Functionalized Persistent Luminescent Nanoparticles as a Multimodal Probe for Near-Infrared Lumines-cence and Magnetic Resonance Imaging In Vivo[J]. Anal. Chem., 2014,86(9):4096-4101. doi: 10.1021/ac500644x
17. [17]
  Jiang R Y, Yang J, Meng Y Q, Yan D T, Liu C G, Xu C S, Liu Y X. X-ray/Red-Light Excited ZGGO: Cr, Nd Nanoprobes for NIR-Ⅰ/Ⅱ Afterglow Imaging[J]. Dalton Trans., 2020,49(18):6074-6083. doi: 10.1039/D0DT00247J
18. [18]
  Gao Y F, Zou R, Chen G F, Liu B M, Zhang Y, Jiao J, Wong K L, Wang J. Large-Pore Mesoporous-Silica-Assisted Synthesis of High-Performance ZnGa₂O₄∶Cr³⁺/Sn⁴⁺ @MSNs Multifunctional Nanoplat-form with Optimized Optical Probe Mass Ratio and Superior Residu-al Pore Volume for Improved Bioimaging and Drug Delivery[J]. Chem. Eng. J., 2021,420:130021-130122. doi: 10.1016/j.cej.2021.130021
19. [19]
  Srivastava B B, Gupta S K, Mohan S, Mao Y. Molten Salt Assisted Annealing for Making Colloidal ZnGa₂O₄∶Cr Nanocrystals with High Persistent Luminescence[J]. Chem. Eur. J., 2021,27:11398-11405. doi: 10.1002/chem.202101234
20. [20]
  Kumari P, Mondal A, Choudhary A K, Ambast D S K. Structural and Optical Properties of Chromium Doped Zinc Gallate Long Persistent Phosphor Prepared by Surfactant Assisted Hydrothermal Method[J]. J. Phys. Conf. Ser., 2021,1913(1)012039. doi: 10.1088/1742-6596/1913/1/012039
21. [21]
  SUN L L, YANTAK R, WANG Q L, HE J Y, STILKE A. Lumines-cence Properties and Energy Transfer of Er³⁺, Cr³⁺ Co-Doped BaAl₂Si₂O₈ Phosphors[J]. Acta Photonica Sinica, 2020,49(3):123-129.
22. [22]
  Dai W J, Chi F F, Lou B B, Wei X T, Cheng J, Liu S L, Yin M. Temperature-Dependent Luminescent Properties of Cr³⁺ Doped ZnGa₂O₄ Far-Red Emitting Phosphor[J]. Opt. Mater., 2021,116:111104-111111. doi: 10.1016/j.optmat.2021.111104
23. [23]
  Zhu Q, Xiahou J Q, Guo Y, Li H L, Ding C, Wang J, Li X D, Sun X D, Li J G. Zn₃Ga₂Ge₂O₁₀: Cr³⁺ Uniform Microspheres: Template-Free Synthesis, Tunable Bandgap/Trap-Depth, and In Vivo Rechargeable Near-Infrared Persistent Luminescence[J]. ACS Appl. Bio Mater., 2019,2:577-587.
24. [24]
  Li Y, Gecevicius M, Qiu J R. Long Persistent Phosphors—From Fun-damentals to Applications[J]. Chem. Soc. Rev., 2016,45(8):2090-2136. doi: 10.1039/C5CS00582E
25. [25]
  Zhao B Q, Zhu Q, Sun X D, Li J G. Co-Doping Zn²⁺/Sn⁴⁺ in ZnGa₂O₄∶ Cr³⁺ for Dynamic Near-Infrared Luminescence and Advanced Anti-Counterfeiting[J]. Ceram. Int., 2021,47(12):17000-17007. doi: 10.1016/j.ceramint.2021.02.271
26. [26]
  Hu Z F, Ye D H, Lan X J, Zhang W, Luo L, Wang Y H. Influence of Co-Doping Si Ions on Persistent Luminescence of ZnGa₂O₄∶Cr³⁺ Red Phosphors[J]. Opt. Mater. Express., 2016,6(4):1329-1338. doi: 10.1364/OME.6.001329
27. [27]
  Pan Z, Lu Y Y, Liu F. Sunlight-Activated Long-Persistent Lumines-cence in the Near-Infrared from Cr³⁺-Doped Zinc Gallogermanates[J]. Nat. Mater., 2011,11(1):58-63.
28. [28]
  LIU W, CUI R R, DENG C Y. Preparation and Luminescence Prop-erties of Zn₃Ga ₄Ge_xO_9+2x∶1%Cr³⁺ as a Novel NIR Ultra-Long After-glow Material[J]. Journal of Optoelectronics·Laser, 2016,27(2):150-155.
29. [29]
  JIAO D, XIAO S G. Luminescence and Long Afterglow Properties of In³⁺, Si⁴⁺ Co-doped ZnBi_0.02Ga_1.98O₄∶Cr³⁺[J]. Spectroscopy and Spectral Analysis, 2020,40(12):3716-3721.
30. [30]
  ABDURAHMAN R, YANG T S, LIU W G, YAN Y. Preparation and Optical Properties of Zn_(1+x)Ga_{(2-0.01 -y)}Ge_xO_(3x+4)∶ 0.01Cr, yBi Long Afterglow Nanoparticles[J]. Laser & Optoelectronics Progress, 2021,58(21)2116001.
31. [31]
  Tuerdi A, Abdukayum A. Dual-Functional Persistent Luminescent Nanoparticles with Enhanced Persistent Luminescence and Photo-catalytic Activity[J]. RSC Adv., 2019,9(31):17653-17657. doi: 10.1039/C9RA02235J
32. [32]
  Que M D, Que W X, Zhou T, Shao J Y, Kong L B. Enhanced Photolu-minescence Property of Sulfate Ions Modified YAG∶Ce³⁺ Phosphor by Co-precipitation Method[J]. J. Rare Earths, 2017,35(3):217-222. doi: 10.1016/S1002-0721(17)60902-5
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通讯作者: 陈斌, bchen63@163.com

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Preparation and Optical Properties of Size Controllable Near-Infrared Emitting Zn1.4Ga1.97-2xO4∶1.5%Cr, xIn Persistent Luminescent Nanoparticles

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通讯作者: 陈斌, bchen63@163.com

Preparation and Optical Properties of Size Controllable Near-Infrared Emitting Zn_1.4Ga_1.97-2xO₄∶1.5%Cr, xIn Persistent Luminescent Nanoparticles