Citation: Yan-Fen PENG, Tian-Bao LIU, Qiu-Yan WU, Meng-Qing WU. Syntheses and Luminescence of Three Zinc Complexes Constructed by Rigid 4-Substituted Bis(1, 2, 4-triazole) Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(2): 344-352. doi: 10.11862/CJIC.2022.035 shu

Syntheses and Luminescence of Three Zinc Complexes Constructed by Rigid 4-Substituted Bis(1, 2, 4-triazole) Ligand

College of Materials and Environmental Engineering, Key Laboratory of Micro-Nano Powder and Advanced Energy Materials of Anhui Higher Education Institutes, Chizhou University, Chizhou, Anhui 247000, China

Corresponding author: Yan-Fen PENG, pengyanfen1978@126.com
Received Date: 9 June 2021
Revised Date: 16 November 2021

Figures(7)

Three new coordination polymers, {[Zn(4-Nbdc) (btx)]·2H₂O}_n (1·2H₂O), [Zn(btx)_1.5(1, 3-bdac)]_n (2) and {[Zn(mbtx) (1, 3-bdc) (H₂O)₂]·H₂O}_n (3) (btx=1, 4-bis(4H-1, 2, 4-triazole)benzene, mbtx=1, 3-bis(4H-1, 2, 4-triazole) benzene, 4-Nbdc=4-nitrophthalate, 1, 3-bdac=1, 3-phenylenediacetate, 1, 3-bdc=1, 3-benzenedicarboxylate), were synthesized under room temperature condition and characterized by single-crystal X-ray diffraction, elemental analyses, powder X-ray diffraction. Sing-crystal X-ray structural analysis show that complex 1 is 2D waved (4, 4) network. 2 and 3 exhibit 1D chain, and the 1D chains are connected into a 3D network by π-π interaction in 2. The adjacent 1D chains are connected into a 2D network by intermolecular hydrogen bond in 3. Two sets of equivalent 2D networks catenate with each other to give a 2D+2D → 2D network through intermolecular hydrogen bond. Luminescence and thermogravimetric analysis of the three complexes were discussed.
- 1, 3-bis(4H-1, 2, 4-triazole)benzene,
- 1, 4-bis(4H-1, 2, 4-triazole)benzene,
- π-π interaction,
- luminescence
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