Preparation of CeTiO4/g-C3N4 Composite with Efficient Photocatalytic Activity for Dye-Degradation
- Corresponding author: Xiao-Wei CHEN, chenxw@ycit.edu.cn Xin-Guo XI, xxg@ycit.cn
Citation:
Zhong-Qin LI, Xiao-Wei CHEN, Yan WANG, Ting CHENG, Yi HUANG, Peng-Yu DONG, Wu-You WANG, Bei-Bei ZHANG, Xin-Guo XI. Preparation of CeTiO4/g-C3N4 Composite with Efficient Photocatalytic Activity for Dye-Degradation[J]. Chinese Journal of Inorganic Chemistry,
;2022, 38(1): 53-62.
doi:
10.11862/CJIC.2022.009
Koh C W, Lee U H, Song J K, Lee H R, Kim M H, Suh M, Kwon Y U. Mesoporous Titania Thin Film with Highly Ordered and Fully Accessible Vertical Pores and Crystalline Walls[J]. Chem. Asian J., 2010,3(5):862-867.
Oveisi H, Jiang X F, Nemoto Y, Beitollahi A, Yamauchi Y. CeriumDoped Mesoporous TiO2 Thin Films: Controlled Crystallization of Anatase with Retention of Highly Ordered Mesostructure[J]. Microporous Mesoporous Mater., 2011,139(1):38-44.
Abdullah H, Khan M R, Pudukudy M, Yaakob Z, Ismail N A. CeO2TiO2 as a Visible Light Active Catalyst for the Photoreduction of CO2 to Methanol[J]. J. Rare Earths, 2015,33(11):1155-1161. doi: 10.1016/S1002-0721(14)60540-8
Wu M Y, Zhang Y G, Szeto W, Pan W D, Huang H B, Leung D Y C. Vacuum Ultraviolet (VUV) - Based Photocatalytic Oxidation for Toluene Degradation over Pure CeO2[J]. Chem. Eng. Sci., 2019,200:203-213. doi: 10.1016/j.ces.2019.01.056
Yan D F, Mo S P, Sun Y H, Ren Q M, Feng Z T, Chen P R, Wu J L, Fu M L, Ye D Q. Morphology-Activity Correlation of Electrospun CeO2 for Toluene Catalytic Combustion[J]. Chemosphere, 2020,247125860. doi: 10.1016/j.chemosphere.2020.125860
Contreras - García M E, García - Benjume M L, Macías - Andrés V I, Barajas-Ledesma E, Medina-Flores A, Espitia-Cabrera M I. Synergic Effect of the TiO2-CeO2 Nanoconjugate System on the Band-Gap for Visible Light Photocatalysis[J]. Mater. Sci. Eng. B, 2014,183:78-85. doi: 10.1016/j.mseb.2014.01.007
Hailili R, Jacobs D L, Zang L, Wang C Y. Morphology Controlled Synthesis of CeTiO4 Using Molten Salts and Enhanced Photocatalytic Activity for CO2 Reduction[J]. Appl. Surf. Sci., 2018,456:360-368. doi: 10.1016/j.apsusc.2018.06.048
Lu X W, Li X Z, Qian J C, Miao N M, Yao C, Chen Z. Synthesis and Characterization of CeO2/TiO2 Nanotube Arrays and Enhanced Photocatalytic Oxidative Desulfurization Performance[J]. J. Alloys Compd., 2016,661:363-371. doi: 10.1016/j.jallcom.2015.11.148
Lu X W, Li X Z, Chen F, Chen Z G, Qian J C, Zhang Q. Biotemplating Synthesis of N - Doped Two - Dimensional CeO2 - TiO2 Nanosheets with Enhanced Visible Light Photocatalytic Desulfurization Performance[J]. J. Alloys Compd, 2020,815152326. doi: 10.1016/j.jallcom.2019.152326
Otsuka - Yao - Matsuo S, Omata T, Yoshimura M. Photocatalytic Behavior of Cerium Titanates, CeTiO4 and CeTi2O6 and Their Composite Powders with SrTiO3[J]. J. Alloys Compd., 2004,376(1):262-267.
Qamaruddin M, Khan I, Ajumobi O O, Ganiyu S A, Qurashi A. Sulfur Doped Ceria - Titania (S - CeTiO4-x) Nanocomposites for Enhanced Solar-Driven Water Splitting[J]. Sol. Energy, 2019,188:890-897. doi: 10.1016/j.solener.2019.05.058
Wen J Q, Xie J, Chen X B, Li X. A Review on g-C3N4-Based Photocatalysts[J]. Appl. Surf. Sci, 2017,391:72-123. doi: 10.1016/j.apsusc.2016.07.030
Ye S, Wang R, Wu M Z, Yuan Y P. A Review on g-C3N4 for Photocatalytic Water Splitting and CO2 Reduction[J]. Appl. Surf. Sci., 2015,358:15-27. doi: 10.1016/j.apsusc.2015.08.173
Hu S Z, Ma L, You J G, Li F Y, Fan Z P, Lu G, Liu D, Gui J Z. Enhanced Visible Light Photocatalytic Performance of g-C3N4 Photocatalysts Co-Doped with Iron and Phosphorus[J]. Appl. Surf. Sci., 2014,311:164-171. doi: 10.1016/j.apsusc.2014.05.036
Wang M J, Liu C, Zhang X B, Fan Z C, Xu J S, Tong Z W. In Situ Synthesis of CsTi2NbO7@g - C3N4 Core - Shell Heterojunction with Excellent Electrocatalytic Performance for the Detection of Nitrite[J]. J. Mater. Res., 2018,33(23):3936-3945. doi: 10.1557/jmr.2018.354
Xue J J, Ma S S, Zhou Y M, Zhang Z W, He M. Facile Photochemical Synthesis of Au/Pt/g - C3N4 with Plasmon - Enhanced Photocatalytic Activity for Antibiotic Degradation[J]. ACS Appl. Mater. Interfaces, 2015,7(18):9630-9637. doi: 10.1021/acsami.5b01212
Wang J, Xia Y, Zhao H Y, Wang G F, Xiang L, Xu J L, Komarneni S. Oxygen Defects-Mediated Z-Scheme Charge Separation in g-C3N4/ZnO Photocatalysts for Enhanced Visible - Light Degradation of 4-Chlorophenol and Hydrogen Evolution[J]. Appl. Catal. B, 2017,206:406-416. doi: 10.1016/j.apcatb.2017.01.067
Yin S, Di J, Li M, Sun Y L, Xia J X, Xu H, Fan W M, Li H M. Ionic Liquid-Assisted Synthesis and Improved Photocatalytic Activity of pn Junction g-C3N4/BiOCl[J]. J. Mater. Sci., 2016,51(10):4769-4777. doi: 10.1007/s10853-016-9746-5
Zhan S, Zhou F, Huang N B, Yang Y F, Liu Y J, Yin Y F, Fang Y N. g -C3N4/ZnWO4 Films: Preparation and Its Enhanced Photocatalytic Decomposition of Phenol in UV[J]. Appl. Surf. Sci, 2015,358:328-335. doi: 10.1016/j.apsusc.2015.07.180
Ye R Q, Fang H B, Zheng Y Z, Li N, Wang Y, Tao X. Fabrication of CoTiO 3/g-C3N4 Hybrid Photocatalysts with Enhanced H2 Evolution: Z - Scheme Photocatalytic Mechanism Insight[J]. ACS Appl. Mater. Interfaces, 2016,8(22):13879-13889. doi: 10.1021/acsami.6b01850
Ahamad T, Naushad M, Alzaharani Y, Alshehri S M. Photocatalytic Degradation of Bisphenol-A with g-C3N4/MoS2-PANI Nanocomposite: Kinetics, Main Active Species, Intermediates and Pathways[J]. J. Mol. Liq., 2020,311113339. doi: 10.1016/j.molliq.2020.113339
Lian X Y, Xue W H, Dong S, Liu E Z, Li H, Xu K Z. Construction of S-Scheme Bi2WO6/g-C3N4 Heterostructure Nanosheets with Enhanced Visible-Light Photocatalytic Degradation for Ammonium Dinitramide[J]. J. Hazard. Mater., 2021,412125217. doi: 10.1016/j.jhazmat.2021.125217
Yan J Q, Wu H, Chen H, Zhang Y, Zhang F, Liu S Z F. Fabrication of TiO2/C3N4 Heterostructure for Enhanced Photocatalytic Z-Scheme Overall Water Splitting[J]. Appl. Catal. B, 2016,191:130-137. doi: 10.1016/j.apcatb.2016.03.026
Guan J R, Wang H Q, Li J Z, Ma C C, Huo P W. Enhanced Photocatalytic Reduction of CO2 by Fabricating In2O3/CeO2/HATP Hybrid Multi-Junction Photocatalyst[J]. J. Taiwan Inst. Chem. Eng., 2019,99:93-103. doi: 10.1016/j.jtice.2019.03.007
Pudukudy M, Jia Q M, Yuan J Y, Megala S, Rajendran R, Shan S Y. Influence of CeO2 Loading on the Structural, Textural, Optical and Photocatalytic Properties of Single - Pot Sol - Gel Derived Ultrafine CeO2/TiO2 Nanocomposites for the Efficient Degradation of Tetracycline under Visible Light Irradiation[J]. Mater. Sci. Semicond. Process., 2020,108104891. doi: 10.1016/j.mssp.2019.104891
Ding J, Zhong Q, Cai H R J, Zhang S L. Structural Characterizations of Fluoride Doped CeTi Nanoparticles and Its Differently Promotional Mechanisms on Ozonation for Low-Temperature Removal of NOx (x= 1, 2)[J]. Chem. Eng. J., 2016,286:549-559. doi: 10.1016/j.cej.2015.10.055
Li H P, Liu J Y, Hou W G, Du N, Zhang R J, Tao X T. Synthesis and Characterization of g-C3N4/Bi2MoO6 Heterojunctions with Enhanced Visible Light Photocatalytic Activity[J]. Appl. Catal. B, 2014,160-161:89-97. doi: 10.1016/j.apcatb.2014.05.019
Bai Y, Ye L Q, Wang L, Shi X, Wang P Q, Bai W, Wong P K. g-C3N4/Bi4O5I2Heterojunction with I3-/I- Redox Mediator for Enhanced Photocatalytic CO2 Conversion[J]. Appl. Catal. B, 2016,194:98-104. doi: 10.1016/j.apcatb.2016.04.052
Guo F, Huang X L, Chen Z H, Sun H R, Chen L Z. Prominent CoCatalytic Effect of CoP Nanoparticles Anchored on High-Crystalline g-C3N4 Nanosheets for Enhanced Visible-Light Photocatalytic Degradation of Tetracycline in Wastewater[J]. Chem. Eng. J., 2020,395125118. doi: 10.1016/j.cej.2020.125118
Barathi D, Rajalakshmi N, Ranjith R, Sangeetha R, Meyvel S. Controllable Synthesis of CeO2/g-C3N4 Hybrid Catalysts and Its Structural, Optical and Visible Light Photocatalytic Activity[J]. Diamond Relat. Mater., 2021,111108161. doi: 10.1016/j.diamond.2020.108161
Gao X, Feng Y, Dong P Y, Zhang B B, Chen T, Chen X W, Liu C, Xi X G, Zou Z G. Rational Design 2D/2D BiOCl/H+Ti2NbO7- Heterojunctions for Enhanced Photocatalytic Degradation Activity[J]. Appl. Surf. Sci., 2020,521146334. doi: 10.1016/j.apsusc.2020.146334
Yang C, Zhang G H, Meng Y, Pan G X, Ni Z M, Xia S J. Direct ZScheme CeO2@LDH Core - Shell Heterostructure for Photodegradation of Rhodamine B by Synergistic Persulfate Activation[J]. J. Hazard. Mater., 2021,408124908. doi: 10.1016/j.jhazmat.2020.124908
Naik S S, Lee S J, Yeon S H, Yu Y, Choi M Y. Pulsed Laser-Assisted Synthesis of Metal and Nonmetal-Codoped ZnO for Efficient Photocatalytic Degradation of Rhodamine B under Solar Light Irradiation[J]. Chemosphere, 2021,274129782. doi: 10.1016/j.chemosphere.2021.129782
Liu C, Zhu H J, Zhu Y S, Dong P Y, Hou H J, Xu Q X, Chen X W, Xi X G, Hou W H. Ordered Layered N - Doped KTiNbO5/g - C3N4 Heterojunction with Enhanced Visible Light Photocatalytic Activity[J]. Appl. Catal. B, 2018,228:54-63. doi: 10.1016/j.apcatb.2018.01.074
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