Citation: Xue ZHANG, Yuan-Yuan SUN, Si-Si FENG, Cai-Xia YUAN. Synthesis, Structures, Luminescence and Magnetic Properties of Co(Ⅱ) and Ni(Ⅱ) Coordination Compounds Based on Dibenzoyl-Tartaric Acid[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(12): 2279-2288. doi: 10.11862/CJIC.2021.253 shu

Synthesis, Structures, Luminescence and Magnetic Properties of Co(Ⅱ) and Ni(Ⅱ) Coordination Compounds Based on Dibenzoyl-Tartaric Acid

1.
Institute of Molecular Science, Key Laboratory of Chemical Biology and Molecular Engineering of Ministry of Education, Shanxi University, Taiyuan 030006, China
2.
Xi'an Manareco New Material Co., Ltd., Xi'an 710000, China

Corresponding author: Si-Si FENG, ssfeng@sxu.edu.cn Cai-Xia YUAN, cxyuan@sxu.edu.cn
Received Date: 25 March 2021
Revised Date: 24 September 2021

Figures(9)

Two coordination compounds[Ni(DBTA)(DMF)(H₂O)₄] (1) and[Co(DBTA)(DMF)(H₂O)₄] (2) (D-H₂DBTA=(+)-2, 3-dibenzoyl-D-tartaric acid, DMF=N, N-dimethylformamide) have been synthesized at room temperature, and characterized by elemental analyses (EA), FT-IR, X-ray single-crystal and powder diffraction analyses. The structural analysis shows that complexes 1 and 2 are isomorphic. They belong to the monoclinic system with P2₁ space group and display a zero-dimensional structure constructed from coordination bonds, which is further interlinked to form a three-dimensional network via hydrogen-bonding interactions. Fluorescence measurements indicate that 1 and 2 can exhibit strong fluorescence using 280 nm as the excitation wavelength. Though 1 and 2 are isomorphic, they displayed different magnetic properties. Complex 1 dominates weak antiferromagnetic couplings between Ni²⁺ cations, while complex 2 exhibits the magnetic anisotropy of the Co²⁺ center and antiferromagnetic interactions between the Co²⁺ cations.
- coordination compounds,
- dibenzoyl-tartaric acid,
- crystal structure,
- luminescence,
- magnetism
1. [1]
  Wang J H, Tang G M, Wang Y T, Qian T X, Ng S W. Metal-Directed Assembly of Coordination Polymers with the Versatile Ligand 2-(1H-Benzotriazol-1-yl) Acetic Acid: from Discrete Structures to Two-Dimensional Networks[J]. CrystEngComm, 2014,16:2660-2683. doi: 10.1039/c3ce42099j
2. [2]
  Zhang Z Z, Jin J C, Gong L K, Lin Y P, Du K Z, Huang X Y. Columinescence in a Zero-Dimensional Organic-Inorganic Hybrid Antimony Halide with Multiple Coordination Units[J]. Dalton Trans., 2021,50:3586-3592. doi: 10.1039/D0DT04388E
3. [3]
  Zhang M, Ling Y, Zheng J, Xu J L, Tasawar H, Alharbi N S. Formation of Uniform Magnetic C@CoNi Alloy Hollow Hybrid Composites with Excellent Performance for Catalysis and Protein Adsorption[J]. Dalton Trans., 2018,47:7839-7847. doi: 10.1039/C8DT01480A
4. [4]
  Dong J P, Shi Z Z, Li B, Wang L Y. Synthesis of a Novel 2D Zinc(Ⅱ) Metal-Organic Framework for Photocatalytic Degradation of Organic Dyes in Water[J]. Dalton Trans., 2019,48:17626-17632. doi: 10.1039/C9DT03727F
5. [5]
  Chen J L, Zhang H, Li B, Yang J Z, Li X W, Zhang T X, He C, Duan C Y, Wang L Y. Bioinspired Carboxylate-Water Coordination Polymers with Hydrogen-Bond Clusters and Local Coordination Flexibility for Electrochemical Water Splitting[J]. ACS Appl. Energy Mater., 2020,3:10515-10524. doi: 10.1021/acsaem.0c01552
6. [6]
  Fan W D, Wang Y T, Zhang Q, Kirchon A, Xiao Z Y, Zhang L L, Dai F N, Wang R M, Sun D F. An Amino-Functionalized Metal-Organic Framework, Based on a Rare Ba₁₂(COO)₁₈(NO₃)₂ Cluster, for Efficient C₃/C₂/C₁ Separation and Preferential Catalytic Performance[J]. Chem. Eur. J., 2018,24:2137-2143. doi: 10.1002/chem.201704629
7. [7]
  Yang X C, Xu Q. Bimetallic Metal-Organic Frameworks for Gas Storage and Separation[J]. Cryst. Growth Des., 2017,17:1450-1455. doi: 10.1021/acs.cgd.7b00166
8. [8]
  He Y B, Chen F L, Li B, Qian G D, Zhou W, Chen B L. Porous MetalOrganic Frameworks for Fuel Storage[J]. Coord. Chem. Rev., 2018,373:167-198. doi: 10.1016/j.ccr.2017.10.002
9. [9]
  Shi W J, Du L Y, Yang H Y, Zhang K, Hou L, Wang Y Y. Ligand Configuration-Induced Manganese(Ⅱ) Coordination Polymers: Syntheses, Crystal Structures, Sorption, and Magnetic Properties[J]. Inorg. Chem., 2017,56:10090-10098. doi: 10.1021/acs.inorgchem.7b01657
10. [10]
  Liu J W, Chen L F, Cui H, Zhang J Y, Zhang L, Su C Y. Applications of Metal-Organic Frameworks in Heterogeneous Supramolecular Catalysis[J]. Chem. Soc. Rev., 2014,43:6011-6061. doi: 10.1039/C4CS00094C
11. [11]
  Lustig W P, Mukherjee S, Rudd N D, Desai A V, Li J, Ghosh S K. Metal-Organic Frameworks: Functional Luminescent and Photonic Materials for Sensing Applications[J]. Chem. Soc. Rev., 2017,46:3242-3285. doi: 10.1039/C6CS00930A
12. [12]
  Yang X G, Ma L F, Yan D P. Facile Synthesis of 1D Organic-Inorganic Perovskite Micro-belts with High Water Stability for Sensing and Photonic Applications[J]. Chem. Sci., 2019,10:4567-4572. doi: 10.1039/C9SC00162J
13. [13]
  Wang Y N, Wang S D, Yang L L, Zhao Y F, Yang Q F. A Luminescent Cadmium Coordination Polymer for Highly Sensitive Detection of Ascorbic Acid[J]. J. Solid State Chem., 2020,289:121519-121524. doi: 10.1016/j.jssc.2020.121519
14. [14]
  Ma X L, Wang Z X, He X, Shao M, Li M X. 2D Double-Layered Dibenzoyl-Tartrate Chiral Coordination Polymer Containing[Mn₄L₂(bpp)₄] Tetrahedral Cage[J]. Inorg. Chem. Commun., 2018,92:131-135. doi: 10.1016/j.inoche.2018.04.015
15. [15]
  Liu X Y, Li F F, Ma X H, Cen P P, Luo S C, Shi Q, Ma S R, Wu Y W, Zhang C C, Xu Z, Song W M, Xie G, Chen S P. Coligand Modifications Fine-Tuned the Structure and Magnetic Properties of Two Triple-Bridged Azido-Cu(Ⅱ) Chain Compounds Exhibiting Ferromagnetic Ordering and Slow Relaxation[J]. Dalton Trans., 2017,46:1207-1217. doi: 10.1039/C6DT04108F
16. [16]
  Gai Y L, Guo Q, Xiong K C, Jiang F L, Li C Y, Xi L, Chen Y, Zhu C Y, Huang Q, Yao R, Hong M C. Mixed-Lanthanide Metal-Organic Frameworks with Tunable Color and White Light Emission[J]. Cryst. Growth Des., 2017,17:940-940. doi: 10.1021/acs.cgd.6b01541
17. [17]
  Feng X, Guo N, Chen H P, Wang H L, Yue L Y, Chen X, Ng S W, Liu X F, Ma L F, Wang L Y. A Series of Anionic Host Coordination Polymers Based on Azoxybenzene Carboxylate: Structures, Luminescence and Magnetic Properties[J]. Dalton Trans., 2017,46:14192-14200. doi: 10.1039/C7DT02974H
18. [18]
  Wei N, Zhang M Y, Zhang X N, Li G M, Zhang X D, Han Z B. Two Series of Solvent-Dependent Lanthanide Coordination Polymers Demonstrating Tunable Luminescence and Catalysis Properties[J]. Cryst. Growth Des., 2014,14:3002-3009. doi: 10.1021/cg500286v
19. [19]
  Qin L, Chen H Z, Lei J, Wang Y Q, Ye T Q, Zheng H G. Photodegradation of Some Organic Dyes over Two Metal-Organic Frameworks with Especially High Efficiency for Safranine T[J]. Cryst. Growth Des., 2017,17:1293-1298. doi: 10.1021/acs.cgd.6b01690
20. [20]
  Zhu M, Li M T, Zhao L, Shao K Z, Su Z M. Metal-Organic Fameworks Based on Multi-carboxylate Ligands with Threefold Symmetries and Luminescence Properties[J]. Inorg. Chem. Commun., 2017,79:69-73. doi: 10.1016/j.inoche.2017.03.020
21. [21]
  Cui Y J, Y F F, Y ue, Qian G D, Chen B L. Luminescent Functional Metal-Organic Frameworks[J]. Chem. Rev., 2012,112:1126-1162. doi: 10.1021/cr200101d
22. [22]
  Yu S, Hu H C, Chen Y K, Chen Z L, Zhang Z Y, Ding M M, Zhang Y Q, Liu D C, Liang F P. Acid and Alkali-Resistant Dy₄ Coordination Clusters: Synthesis, Structure and Slow Magnetic Relaxation Behaviors[J]. J. Mater. Chem. C, 2021,9:3854-3862. doi: 10.1039/D0TC03250F
23. [23]
  Zhang S, Mo W J, Yin B, Zhang G N, Yang D S, Lu X Q, Chen S P. The Slow Magnetic Relaxation Regulated by the Coordination, Configuration and Intermolecular Dipolar Field in Two Mononuclear Dy^Ⅲ Single Molecule Magnets (SMMs)[J]. Dalton Trans., 2018,47:12393-12405. doi: 10.1039/C8DT02361A
24. [24]
  Tupolova Y P, Shcherbakov I N, Popov L D, Morgunov R B, Korchagin D V, Lebedev V E, Palii A V, Aldoshin S M. Field-Induced SIM Behaviour of a Co(Ⅱ) Complex with a 1, 1'-Diacetylferrocene-Derived Ligand[J]. Dalton Trans., 2020,49:15592-15596. doi: 10.1039/D0DT02747B
25. [25]
  Mattei C A, Montigaud V, Dorcet V, Riobe F, Argouarch G, Maury O, Guennic B L, Cador O, Lalli C, Pointillart F. Luminescent Dysprosium Single-Molecule Magnets Made from Designed Chiral BINOL-Derived Bisphosphate Ligands[J]. Inorg. Chem. Front., 2021,8:963-976. doi: 10.1039/D0QI01193B
26. [26]
  Pramanik S, Zheng C, Zhang X, Emge T J, Li J. New Microporous Metal-Organic Framework Demonstrating Unique Selectivity for Detection of High Explosives and Aromatic Compounds[J]. J. Am. Chem. Soc., 2011,133:4153-4155. doi: 10.1021/ja106851d
27. [27]
  Banerjee D, Hu Z C, Li J. Luminescent Metal-Organic Frameworks as Explosive Sensors[J]. Dalton Trans., 2014,43:10668-10685. doi: 10.1039/C4DT01196A
28. [28]
  GAO X L, HAN M R, REN H F, FENG S S. Synthesis, Structures, Luminescence and Photocatalytic Properties of Three Lanthanide Complexes Based on Ditoluoyl-Tartrate[J]. Chinese J. Inorg. Chem., 2021,37(2):375-384.
29. [29]
  Yang X F, Zhu H B, Liu M. Transition-Metal-Based (Co²⁺, Ni²⁺ and Cd²⁺) Coordination Polymers Constructed by a Polytopic Ligand Integrating Both Flexible Aliphatic and Rigid Aromatic Carboxylate Groups: Aqueous Detection of Nitroaromatics[J]. Polyhedron, 2017,128:18-29. doi: 10.1016/j.poly.2017.02.041
30. [30]
  Hong M M, Liu A F, Xu Y, Xu D M. Synthesis and Properties of Three Novel Rhodamine-Based Fluorescent Sensors for Hg²⁺[J]. Chin. Chem. Lett., 2016,27:989-992. doi: 10.1016/j.cclet.2016.03.027
31. [31]
  Guo X, Zhu G, Fang Q. Synthesis, Structure and Luminescent Properties of Rare Earth Coordination Polymers Constructed from Paddle-Wheel Building Blocks[J]. Inorg. Chem., 2005,44:3850-3855. doi: 10.1021/ic0500457
32. [32]
  Zheng S L, Yang J H, Yu X L, Chen X M, Wong W T. Syntheses, Structures, Photoluminescence, and Theoretical Studies of d¹⁰ Metal Complexes of 2, 2'-Dihydroxy-[J]. Inorg. Chem., 2004,43:830-838. doi: 10.1021/ic034847i
33. [33]
  Liu Q Y, Xiong W L, Xu W Y, Wang Y L, Peng X W, Xiong L H. Synthesis, Crystal Structures and Magnetism of Two Coordination Compounds Constructed from 2, 5-Disulfonylterephthalate Ligand[J]. Inorg. Chim. Acta, 2013,405:222-227. doi: 10.1016/j.ica.2013.05.037
34. [34]
  Mahmoudi G, Chowdhury H, Ghosh B K, Lofland S E, Maniukiweicz W. Syntheses, Crystal Structures and Hirshfeld Surface Analysis of a Coordination Polymer of Cu(Ⅱ) Chlorido and a Tris-octahedral Complex of Ni (Ⅱ) Containing Isonicotinoylhydrazone Blockers[J]. J. Mol. Struct., 2018,1160:368-374. doi: 10.1016/j.molstruc.2018.02.015
35. [35]
  Torres R D, Menelaou M, Roubeau O, Sorrenti A, Pedro B D, Sanudo E C, Teat S J, Fraxedas J, Ruiz E, Alcalde N A. Multiscale Study of Mononuclear Co^Ⅱ SMMs Based on Curcuminoid ligands[J]. Chem. Sci., 2016,7:2793-2803. doi: 10.1039/C5SC03298A
36. [36]
  Tu D S, Shao D, Yan H, Lu C S. A Carborane-Incorporated Mononuclear Co(Ⅱ) Complex Showing Zero-Field Slow Magnetic Relaxation[J]. Chem. Commun., 2016,52:14326-14329. doi: 10.1039/C6CC07728E
37. [37]
  Muddassir M, Song Y. Synthesis, Crystal Structures and Magnetic Properties of Mononuclear High-Spin Cobalt (Ⅱ) Complex[J]. Crystals, 2020,10:87-97. doi: 10.3390/cryst10020087
38. [38]
  Zhang X M, Liu F, Gao W, Huang H, Liu J P. Six Novel Coordination Polymers Based on the 5-(1H-Tetrazol-5-yl)isophthalic Acid Ligand: Structures, Luminescence, and Magnetic Properties[J]. CrystEngComm, 2018,20:1985-1996. doi: 10.1039/C8CE00030A
39. [39]
  Su F, Lu L P, Feng S S, Zhu M L, Gao Z Q, Dong Y H. Synthesis, Structures and Magnetic Properties in 3d-Electron-Rich Isostructural Complexes Based on Chains with Sole syn-anti Carboxylate Bridges[J]. Dalton Trans., 2015,44:7213-7222. doi: 10.1039/C5DT00412H
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