Citation: Wen-Juan JI, Dan WANG, Guo-Jiao WANG, Xiu-Ling SUN, Yun-Long FU. High Performance Supercapacitors Constructed with Isomorphic MOFs Doped Graphene Oxide Electrode Materials[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(11): 1931-1942. doi: 10.11862/CJIC.2021.241 shu

High Performance Supercapacitors Constructed with Isomorphic MOFs Doped Graphene Oxide Electrode Materials

Key Laboratory of Magnetic Molecules & Magnetic Information Materials Ministry of Education, School of Chemical and Material Science, Shanxi Normal University, Taiyuan 030006, China

Corresponding author: Wen-Juan JI, jiwj@sxnu.edu.cn Yun-Long FU, yunlongfu@sxnu.edu.cn
Received Date: 14 January 2021
Revised Date: 27 September 2021

Figures(15)

A series of X-MOF@GO composited with X-MOF (X₆O(TATB)₄(H⁺)₂·(H₂O)₈·(DMF)₂, X=Zn, Co, Ni; H₃TATB=4, 4', 4″-s-triazine-2, 4, 6-triyl-tribenzoic acid; DMF=N, N-dimethylformamide) and graphene oxide (GO) as supercapacitor electrode materials were synthesized by one-step self-assembly under hydrothermal conditions. X-ray powder diffraction, X-ray photoelectron spectroscopy and scanning electron microscopy showed that X-MOF@GO composites were successfully synthesized. Ni-MOF@1.5GO electrode with the best performance delivered a specific capacitance of 694.8 F·g^-1 at 0.5 A·g^-1. Moreover, the specific capacitance of Ni-MOF@1.5GO electrode was nearly twice of Ni-MOF, while the capacitance of Ni-MOFs@1.0GO retained about 81.2% after 1 000 cycles indicating that GO doped Ni-MOF can boost the performance of MOFs materials effectively. A symmetrical capacitor based on Ni-MOF@1.5GO//AC (AC=activated carbon) electrode exhibited a high energy density of 754.3 W·kg^-1 at power density of 15.4 Wh·kg^-1, while the capacitance retention reached about 70.0% after 3 000 cycles.
- metal-organic framework,
- graphene oxide,
- composite materials,
- supercapacitors
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