Citation: Zhong YU, Na YE, Hao CHEN, Ting GUO, Jing HAN. Multi-colored Photochromism of Ag(Ⅰ) Complex Constructed by Two Diarylethene Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(10): 1727-1737. doi: 10.11862/CJIC.2021.217 shu

Multi-colored Photochromism of Ag(Ⅰ) Complex Constructed by Two Diarylethene Ligands

Zhong YU ¹ ,
Na YE ² ,
Hao CHEN ² ,
Ting GUO ² ,
Jing HAN ^2,,

1.
Department of Applied Chemistry, Xi'an University of Technology, Xi'an 710054, China
2.
Department of Materials Physics and Chemistry, Xi'an University of Technology, Xi'an 710048, China

Corresponding author: Jing HAN, hanj@xaut.edu.cn
Received Date: 12 May 2021
Revised Date: 24 August 2021

Figures(14)

A new two-component photochromic Ag (Ⅰ) complex 1 was synthesized by employing two diarylethenes bearing separated absorption wavelengths as ligands, i.e. 1, 2-bis(2'-methyl-5'-(4″-cyanopheny)-3'-thienyl) perfluorocyclopentene (L1) and cis-1, 2-dicyano-1, 2-bis(2', 4', 5'-trimethyl-3'-thienyl) ethylene (L2), Ag(Ⅰ) as metal ions as well as strong coordinating CF₃COO^- as anions. The complex was characterized structurally by IR, ¹H NMR and MS. The multi-colored photochromism of complex 1 was investigated in thtrahydrofuran (THF) and polymethylmethacrylate (PMMA) films by UV-Vis spectra with the mixture of two ligands as control. The results show the coordination of silver ions doesn't inhibit the photochromism but regulates the photo-isomerizations of the two ligands. The four color transformations of yellow, blue, red and purple in complex 1 were realized successfully by the selective stepwise photo-isomerization of the distinct ligands upon irradiation with combination of different wavelengths lights (254 nm, 405 nm, > 550 nm).
- photochromism,
- diarylethylene,
- complex,
- two-component,
- multi-color
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