Citation: Jiao ZHAO, Zhi-Yuan WANG, Hai-Lang JIA, Rui-Xin CHEN, Rui LIU. Preparation and Performance of N and S Co-doped Graphene Loaded Cobalt Sulfide Nanoparticles Oxygen Evolution Electrocatalyst[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(10): 1793-1800. doi: 10.11862/CJIC.2021.216 shu

Preparation and Performance of N and S Co-doped Graphene Loaded Cobalt Sulfide Nanoparticles Oxygen Evolution Electrocatalyst

1.
School of Chemical and Environmental Engineering, Jiangsu University of Technology, Changzhou, Jiangsu 213001, China
2.
PLA Army Academy of Artillery and Air Defense, Hefei 230031, China

Corresponding author: Hai-Lang JIA, jiahailang85@126.com
Received Date: 30 April 2021
Revised Date: 7 August 2021

Figures(6)

The three-dimensional N and S co-doped graphene loaded cobalt sulfide nanoparticles oxygen evolution electrocatalyst (CoS/N/S/rGO) was prepared by using D-glucosamine as the Co dispersant and carbon source, thiourea as the nitrogen source and sulfur source, and NaCl as the template, achieving N and S co-doping and uniformly loading two kinds of nanoparticles Co₉S₈ and Co₄S₃. CoS/N/S/rGO had good oxygen reduction reaction (ORR) activity with initial potential of 960 mV and half-wave potential of 815 mV, respectively, which was similar to commercial Pt/C. In addition, CoS/N/S/rGO showed obvious four-electron transfer characteristics and ultra-low hydrogen peroxide production rate. Compared with Pt/C based zinc-air battery, CoS/N/S/rGO based zinc-air battery showed higher constant current discharge performance and better stability in 6 mol·L^-1 KOH and 0.2 mol·L^-1 Zn(CH₃COO)₂ alkaline electrolyte.
- oxygen reduction reaction,
- template method,
- electrocatalyst,
- zinc-air battery
1. [1]
  Xue Y J, Sun S S, Wang Q, Dong Z H, Liu Z P. J. Mater. Chem. A, 2018, 6: 10595-10626 doi: 10.1039/C7TA10569J
2. [2]
  Eissa A A, Kim N H, Lee J H. J. Mater. Chem. A, 2020, 8: 23436-23454 doi: 10.1039/D0TA06987F
3. [3]
  Nguyen T T, Balamurugan J, Lau K T, Kim N H, Lee J H. J. Mater. Chem. A, 2021, 9: 9092-9104 doi: 10.1039/D0TA12414A
4. [4]
  Zou H Z, Pei S P, Zhou Z S, Chen Z Y, Xiong X, Sun Y Y, Zhang Y M. RSC Adv. , 2020, 10: 779-783 doi: 10.1039/C9RA08951A
5. [5]
  Bera R K, Park H, Ryoo R. J. Mater. Chem. A, 2019, 7: 9988-9996 doi: 10.1039/C9TA01482A
6. [6]
  Ding J T, Ji S, Wang H, Gai H J, Liu F S, Pollet B G, Wang R F. Chem. Commun. , 2019, 55: 2924-2927 doi: 10.1039/C9CC00391F
7. [7]
  Wang C W, Zhao H F, Wang J, Zhao Z, Cheng M, Duan X Y, Zhang Q, Wang J Y, Wang J Z. J. Mater. Chem. A, 2019, 7: 1451-1458 doi: 10.1039/C8TA09722D
8. [8]
  Wu H H, Zeng M, Li Z Y, Zhu X, Tian C C, Xia C G, He L, Dai S. Sustainable Energy Fuels, 2019, 3: 136-141 doi: 10.1039/C8SE00362A
9. [9]
  Sanetuntikul J, Hyun S, Ganesan P, Shanmugam S. J. Mater. Chem. A, 2018, 6: 24078-24085 doi: 10.1039/C8TA08476A
10. [10]
  Lv M Y, Guo H C, Shen H J, Wang J, Wang J C, Shimakawa Y, Yang M H. Phys. Chem. Chem. Phys. , 2020, 22: 7218-7223 doi: 10.1039/D0CP00109K
11. [11]
  Zheng W W, Lv J Q, Zhang H B, Zhang H X, Zhang J. Sustainable Energy Fuels, 2020, 4: 1093-1098 doi: 10.1039/C9SE01130G
12. [12]
  He T Y, Xu L, Zhang Y, Huang H, Jiao H. New J. Chem. , 2019, 43: 1611-1616 doi: 10.1039/C8NJ05365K
13. [13]
  Lu X Y, Wang D, Ge L P, Xiao L H, Zhang H Y, Liu L L, Zhang J Q, An M Z, Yang P X. New J. Chem. , 2018, 42: 19665-19670 doi: 10.1039/C8NJ04857F
14. [14]
  Zhao J Y, Wang R, Wang S, Lv Y R, Xu H, Zang S Q. J. Mater. Chem. A, 2019, 7: 7389-7395 doi: 10.1039/C8TA12116H
15. [15]
  Feng C, Guo Y, Xie Y H, Cao X L, Li S, Zhang L G, Wang W, Wang J D. Nanoscale, 2020, 12: 5942-5952 doi: 10.1039/C9NR10943A
16. [16]
  Feng C, Xi Y, Shen C, Li X, Wang J M, Qin G W, Li S, Pang X Y, Li G Q. J. Mater. Chem. A, 2020, 8: 7245-7252 doi: 10.1039/D0TA00826E
17. [17]
  Ibraheem S, Chen S G, Li J, Wang Q M, Wei Z D. J. Mater. Chem. A, 2019, 7: 9497-9502 doi: 10.1039/C9TA01964B
18. [18]
  Joshi P, Yadav R, Hara M, Inoue T, Motoyama Y, Yoshimura M. J. Mater. Chem. A, 2021, 9: 9066-9080 doi: 10.1039/D1TA00158B
19. [19]
  Song R L, Cao X T, Xu J, Zhou X S, Wang X, Yuan N Y, Ding J N. Nanoscale, 2021, 13: 6174-6183 doi: 10.1039/D0NR09174J
20. [20]
  Liu W J, Wen Y Q, Wang J W, Zhong D C, Tan J B, Lu T B. J. Mater. Chem. A, 2019, 7: 9587-9592 doi: 10.1039/C8TA07994C
21. [21]
  Fan L L, Du X X, Zhang Y M, Li M F, Wen M L, Ge X Y, Kang Z X, Sun D F. Dalton Trans. , 2019, 48: 2352-2358 doi: 10.1039/C8DT04650F
22. [22]
  Li P, Jang H, Yuan B, Wu Z X, Liu X, Cho J. Inorg. Chem. Front. , 2019, 6: 417-422
23. [23]
  Wang H L, Liang Y Y, Li Y G, Dai H J. Angew. Chem. Int. Ed. , 2011, 50: 10969-10972 doi: 10.1002/anie.201104004
24. [24]
  Higgins D C, Hassan F M, Seo M H, Choi J Y, Hoque M A, Lee D U, Chen Z. J. Mater. Chem. A, 2015, 3: 6340-6350 doi: 10.1039/C4TA06667G
25. [25]
  Hu C C, Liu J, Wang J, She W X, Xiao J W, Xi J B, Bai Z W, Wang S. ACS Appl. Mater. Interfaces, 2018, 10: 33124-33134 doi: 10.1021/acsami.8b07343
26. [26]
  Chen S, Chen S, Zhang B H, Zhang J T. ACS Appl. Mater. Interfaces, 2019, 11: 16720-16728 doi: 10.1021/acsami.9b02819
27. [27]
  Ren J T, Yuan Z Y. ACS Sustainable Chem. Eng. , 2019, 7: 10121-10131 doi: 10.1021/acssuschemeng.9b01699
28. [28]
  Huang Z, Zhou H H, Yang W J, Fu C P, Chen L, Kuang Y F. ChemCatChem, 2017, 9: 987-996 doi: 10.1002/cctc.201601387
29. [29]
  Liu B, Qu S X, Kou Y, Liu Z, Chen X, Wu Y T, Han X P, Deng Y D, Hu W B, Zhong C. ACS Appl. Mater. Interfaces, 2018, 10: 30433-30440 doi: 10.1021/acsami.8b10645
30. [30]
  Zhu X J, Dai J L, Li L G, Wu Z X, Chen S W. Nanoscale, 2019, 11: 21302-21310 doi: 10.1039/C9NR07632H
31. [31]
  Zhang J, Chen J W, Luo Y, Chen Y H, Luo Y J, Zhang C Y, Xue Y L, Liu H G, Wang G, Wang R L. J. Mater. Chem. A, 2021, 9: 5556-5565 doi: 10.1039/D0TA11859A
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