Citation: Jian-Yin ZHANG, Hao-Hao LIU, Xiao-Xiao SHI. Preparation of Li₂Ni₂(MoO₄)₃@C Composite as High-Performance Anode Material for Lithium-Ion Batteries with High Initial Coulombic Efficiency[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(10): 1862-1870. doi: 10.11862/CJIC.2021.205 shu

Preparation of Li₂Ni₂(MoO₄)₃@C Composite as High-Performance Anode Material for Lithium-Ion Batteries with High Initial Coulombic Efficiency

Jian-Yin ZHANG ^{1, 2,,} ,
Hao-Hao LIU ^{1, 2} ,
Xiao-Xiao SHI ^{1, 2}

1.
Modern College of Humanities and Sciences, Shanxi Normal University, Linfen, Shanxi 041000, China
2.
School of Chemical and Material Science, Shanxi Normal University, Linfen, Shanxi 041004, China

Corresponding author: Jian-Yin ZHANG, jyzhang@sxnu.edu.cn
Received Date: 12 March 2021
Revised Date: 8 August 2021

Figures(7)

Herein, Li₂Ni₂(MoO₄)₃@C composite with mass ratio of 23.7% of carbon was prepared using conventional solid-state method combined with mechanical ball milling and first investigated as the new anode of lithium-ion batteries. Compared with pure Li₂Ni₂(MoO₄)₃, Li₂Ni₂(MoO₄)₃@C presented an outstanding electrochemical performance, where a high reversible capacity of 845 mAh·g^-1 can be acquired at a current density of 200 mA·g^-1 after 50 cycles. It's worth noting that Li₂Ni₂(MoO₄)₃@C delivered high initial coulombic efficiency of 85%. Moreover, the lithium intercalation/de-intercalation behavior of Li₂Ni₂(MoO₄)₃@C was preliminarily investigated by cyclic voltammetry.
- Li₂Ni₂(MoO₄)₃,
- solid state synthesis,
- anode material,
- lithium-ion batteries,
- high initial coulombic efficiency
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通讯作者: 陈斌, bchen63@163.com

Preparation of Li₂Ni₂(MoO₄)₃@C Composite as High-Performance Anode Material for Lithium-Ion Batteries with High Initial Coulombic Efficiency