Citation: Yu-Ting MAO, Si-Da OUYANG, Zhi-Sheng KE, Yan HU, Shu-Qi YU, Ming-Xue XIANG, Zhong-Bang ZHU, Ping ZHANG. Magnesium-Doped Tricalcium Aluminate: Preparation and Simultaneous Removal Performance of Nitrogen and Phosphorus[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(10): 1745-1752. doi: 10.11862/CJIC.2021.202 shu

Magnesium-Doped Tricalcium Aluminate: Preparation and Simultaneous Removal Performance of Nitrogen and Phosphorus

Yu-Ting MAO ^{1, 2} ,
Si-Da OUYANG ¹ ,
Zhi-Sheng KE ¹ ,
Yan HU ³ ,
Shu-Qi YU ¹ ,
Ming-Xue XIANG ¹ ,
Zhong-Bang ZHU ¹ ,
Ping ZHANG ^1,,

1.
Key Laboratory of Poyang Lake Environment and Resource Utilization, Ministry of Education, School of Environmental and Chemical Engineering, Nanchang University, Nanchang 330031, China
2.
Office of MRL Development Committee of Jiangxi Province, Nanchang 330046, China
3.
Ganzhou Institute of Animal Science, Ganzhou, Jiangxi 341401, China

Corresponding author: Ping ZHANG, zhangping@ncu.edu.cn
Received Date: 9 February 2021
Revised Date: 22 July 2021

Figures(7)

Magnesium-doped tricalcium aluminate (Mg-C₃A) was successfully prepared through solid reaction method. The crystal structure and morphology of Mg-C₃A with various Mg contents were analyzed via X-ray diffraction, Raman spectra, scanning electron microscope and high-resolution transmission electron microscope to explore the preparation mechanism. The results showed that Mg-C₃A was composed of C₃A isomorphism formed by the replacement of Ca with Mg and the surface MgO, in which the Mg doping did not change the cubic symmetric structure and morphology of C₃A. The simultaneous removal behavior of nitrogen (NH₄⁺) and phosphorus (PO₄^3-) by Mg-C₃A were investigated by batch experiments (e. g., Mg-C₃A dosage, reaction time and real wastewater treatment), which revealed the maximum capacity was 65.2 and 20.2 mg·g^-1 at 12 h, respectively, conforming to the pseudo-secondorder kinetic model. Besides, the removal mechanisms were comprehensively explored by microscopic characterizations. The released ions (i.e., Mg²⁺ and Al³⁺) of Mg-C₃A play a major role in the removal of NH₄⁺ and PO₄^3- via the formation of struvite and AlPO₄; the OH^- benefits for the removal of excessive NH₄⁺ via neutralization.
- magnesium-doped tricalcium aluminate,
- preparation,
- ammonium,
- phosphate,
- simultaneous removal
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