Citation: Yang ZHANG, Yan-Hong CUI, Shou-Tao MA, Wei ZHANG, Yuan-Yuan WEI, Yan-Hua SUO. Preparation of Rice Husk-Based High-Purity NaP1 Zeolite and Evaluation of Heptane Isomerization Performance[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(9): 1613-1624. doi: 10.11862/CJIC.2021.192 shu

Preparation of Rice Husk-Based High-Purity NaP1 Zeolite and Evaluation of Heptane Isomerization Performance

Yang ZHANG ¹ ,
Yan-Hong CUI ¹ ,
Shou-Tao MA ^{1, 2} ,
Wei ZHANG ¹ ,
Yuan-Yuan WEI ¹ ,
Yan-Hua SUO ^1,,

1.
College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing, Heilongjiang 163318, China
2.
Daqing PetroChenical Research Center of PetroChina, Daqing, Heilongjiang 163714, China

Corresponding author: Yan-Hua SUO, 33367123@qq.com
Received Date: 17 March 2021
Revised Date: 17 June 2021

Figures(13)

NaP1 zeolite were synthesized by calcination-hydrothermal method using rice husk as the silicon source. The effects of different silicon-to-aluminum molar ratio (n_SiO₂/n_Al₂O₃), water-to-sodium molar ratio (n_H₂O/n_Na₂O), crystallization temperature and crystallization time on the crystallinity of zeolite were investigated. The alkane isomerization catalyst of x%Ni/NaP1 (x% was the mass ratio of Ni to NaP1) was prepared with the NaP1 zeolite as the support. Xray powder diffraction, infrared spectroscopy, scanning electron microscope, transmission electron microscope-Xray energy spectrum, N₂ adsorption-desorption, X-ray photoelectron energy spectrum, NH₃ temperature programmed desorption and differential thermal analysis characterization methods were used to analyze the crystal structure, microscopic morphology and metal dispersion of the synthesized materials, and the effect of nickel loading on the acidity and thermal stability of NaP1 were studied. The results showed that the optimal synthesis conditions for NaP1 zeolite prepared from rice husk as silicon source were as follows: n_H₂O/n_Na₂O=35, n_SiO₂/n_Al₂O₃=10, crystallization temperature was 95℃, and the crystallization time was 12 h. Under these synthesizing conditions, the crystallinity of NaP1 crystal was 99.38%. In the experiment of n-heptane isomerization as a probe, 4%Ni/NaP1 had the best catalytic performance at a reduction temperature of 400℃, reduction time of 4 h, weight hourly space velocity of 3.52 h^-1, and reaction temperature of 320℃, and the maximum yield was 46.41%, with the conversion of n-heptane and selectivity of iso-heptane of 65.49% and 70.86%, respectively.
- rice husk,
- zeolites,
- hydrothermal synthesis,
- isomerization,
- porous materials
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