Citation: Lan WANG, Hang SHI, Huan ZHANG, Qi-Xin CHEN, Bao-Dan JIN, Hong-Zhong ZHANG. ZnIn₂S₄/TiO₂/Ag Composite Photocatalyst: Preparation and Performance for Hydrogen Production from Water Splitting[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(9): 1571-1578. doi: 10.11862/CJIC.2021.187 shu

ZnIn₂S₄/TiO₂/Ag Composite Photocatalyst: Preparation and Performance for Hydrogen Production from Water Splitting

Henan Collaborative Innovation Centre of Environmental Pollution Control and Ecological Restoration, College of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China

Corresponding author: Hong-Zhong ZHANG, zhz@zzuli.edu.cn
Received Date: 24 February 2021
Revised Date: 16 July 2021

Figures(8)

Firstly, 1D TiO₂ nanobelts were uniformly interspersed into 3D ZnIn₂S₄ microspheres assembled by lamellar structure by solvothermal method. The heterostructure photocatalyst can effectively suppress the re-combination of photoinduced electron-hole pairs. Secondly, 0D Ag nanoparticles were loaded onto 3D ZnIn₂S₄/1D TiO₂ hetero-structure by photodeposition method. Owing to the plasma effect of 0D Ag nanoparticles and the action of electron co -catalyst, ternary 3D ZnIn₂S₄/1D TiO₂/0D Ag composite photocatalyst showed excellent performance in photocatalytic hydrogen evolution. Under simulated sunlight irradiation, the hydrogen production rate of ZnIn₂S₄/TiO₂/Ag composite photocatalyst reached 715 μmol·g^-1·h^-1, which was 2.7 times, 3.3 times, 3.8 times, 184 times and 518 times higher than those of ZnIn₂S₄/TiO₂, ZnIn₂S₄/P25, TiO₂ and P25, respectively. At the same time, by means of X-ray diffraction, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy and UV-Vis diffuse reflection spectroscopy, the excellent performance of the composite catalyst was further demonstrated.
- ZnIn₂S₄/TiO₂/Ag,
- electron cocatalyst,
- heterostructure,
- photocatalytic hydrogen production
1. [1]
  Fujishima A. Nature, 1972, 238: 37-38
2. [2]
  Chen X B, Shen S H, Guo L J, Mao S S. Chem. Rev., 2010, 110(11): 6503-6570
3. [3]
  Guang Y, Daimei C, Hao D, Feng J, Zhang J Z, Zhu Y F, Hamid S, Bahnemann D W. Appl. Catal. B, 2017, 219: 611-618 doi: 10.1016/j.apcatb.2017.08.016
4. [4]
  Wei N, Cui H Z, Song Q, Zhang L Q, Song X J, Wang K, Zhang Y F, Li J, Wen J, Tian J. Appl. Catal. B, 2016, 198: 83-90 doi: 10.1016/j.apcatb.2016.05.040
5. [5]
  WU S N, JIANG Y, CHEN Q H, XIN Y J. Environ. Sci. Technol., 2018, 41(9): 12-16
6. [6]
  Yamashita H, Harada M, Misaka J, Takeuchi M, Ikeue K, Anpo M. J. Photochem. Photobiol. A, 2002, 148: 257-261 doi: 10.1016/S1010-6030(02)00051-5
7. [7]
  Li J, Ma W H, Huang Y P, Tao X, Zhao J C, Xu Y M. Appl. Catal. B, 2003, 48(1): 17-24
8. [8]
  Zhao J C, Chen C C, Ma W H. Top. Catal., 2005, 35(3/4): 269-278
9. [9]
  Kim T W, Hwang S J, Jhung S H, Chang J S, Park H, Choi W, Choy J H. Adv. Mater., 2008, 20(3): 539-542 doi: 10.1002/adma.200701677
10. [10]
  Ikeda S, Sugiyama N, Pal B, Marci G, Palmisano L, Noguchi H, Uosaki K, Ohtani B. Phys. Chem. Chem. Phys., 2001, 3(2): 267-273 doi: 10.1039/b008028o
11. [11]
  Fujishima A, Zhang X T, Tryk D A. Surf. Sci. Rep., 2008, 63(12): 515-582 doi: 10.1016/j.surfrep.2008.10.001
12. [12]
  Wei L F, Yu C L, Zhang Q H, Liu H, Wang Y. J. Mater. Chem., 2018, 6(45): 22411-22436 doi: 10.1039/C8TA08879A
13. [13]
  WANG Y N, LI J H, DU Q J, LIU X J, XU W J, FANG T. Industrial Water Treatment, 2018, 38(8): 17-20
14. [14]
  Xu J Q, Li X D, Liu W, Sun Y F, Ju Z Y, Yao T, Wang C M, Ju H X, Zhu J F, Wei S Q, Xie Y. Angew. Chem. Int. Ed., 2017, 56(31): 9121-9125 doi: 10.1002/anie.201704928
15. [15]
  Pan Y, Yuan X Z, Jiang L B, Yu H B, Zhang J, Wang H, Guan R P, Zeng J M. Chem. Eng. J., 2018, 354: 407-431 doi: 10.1016/j.cej.2018.08.028
16. [16]
  Huang K L, Li C H, Meng X C. J. Colloid Interface Sci., 2020, 580: 669-680 doi: 10.1016/j.jcis.2020.07.044
17. [17]
  Zhang Q, Wang X H, Zhang J H, Li L F, Gu H J, Dai W L. J. Colloid Interface Sci., 2021, 590: 632-640 doi: 10.1016/j.jcis.2021.01.083
18. [18]
  Yan W, Hou W G, Tu W G, Wu S Y, Chew J W. Appl. Catal. B, 2019, 256: 117810 doi: 10.1016/j.apcatb.2019.117810
19. [19]
  Gou X L, Cheng F Y, Shi Y H. J. Am. Chem. Soc., 2006, 128: 7222-7229 doi: 10.1021/ja0580845
20. [20]
  Wang L, Zhou H H, Zhang H Z, Song Y L, Zhang H, Qian X H. Inorg. Chem., 2020, 59: 2278-2287 doi: 10.1021/acs.inorgchem.9b03007
21. [21]
  Wang L, Zhou H H, Zhang H Z, Song Y L, Zhang H, Luo L K, Yang Y F, Bai S Q, Wang Y, Liu S X. Nanoscale, 2020, 12: 13791 doi: 10.1039/D0NR03196H
22. [22]
  Zhang Z Y, Li A R, Cao S W, Bosman M, Li S Z, Xue C. Nanoscale, 2014, 6(10): 5217-5222 doi: 10.1039/C3NR06562F
23. [23]
  GU L H. China Dyeing & Finishing, 2019, 45(21): 42-46
24. [24]
  DU X H, LI Y, YIN H, XIANG Q J. Acta Phys. -Chim. Sin., 2018, 34(4): 414-423
25. [25]
  Yuan W, Zhang Z, Cui X L, Liu H R, Tai C, Song Y R. ACS Sustainable Chem. Eng., 2018, 6: 13766-13777 doi: 10.1021/acssuschemeng.8b01787
26. [26]
  WANG P, LI X Y, SHI Z L, LI H T. J. Inorg. Mater., 2020, 35(7): 781-788
27. [27]
  Wang X F, Sun K, Gu S, Zhang Y, Wu D, Zhou X Y, Gao K Y, Ding Y. Appl. Surf. Sci., 2021, 549: 149341 doi: 10.1016/j.apsusc.2021.149341
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ZnIn₂S₄/TiO₂/Ag Composite Photocatalyst: Preparation and Performance for Hydrogen Production from Water Splitting