Citation: Xiao-Qing YANG, Chun-Yu HE, Yan-Hong ZHANG, Xian-Gui MU, Shuang JIANG. Synthesis, Crystal Structure and Properties of Mn(Ⅱ)/Co(Ⅱ) Coordination Polymers Based on 1, 4-Bis(imidazol-1-yl) benzene[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(8): 1364-1374. doi: 10.11862/CJIC.2021.165 shu

Synthesis, Crystal Structure and Properties of Mn(Ⅱ)/Co(Ⅱ) Coordination Polymers Based on 1, 4-Bis(imidazol-1-yl) benzene

1.
College of Chemistry and Environment Science, Key Laboratory of Excitonic Materials Chemistry & Devices, Inner Mongolia Normal University, Hohhot 010022, China
2.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China

Corresponding author: Yan-Hong ZHANG, zhangyh@imnu.edu.cn
Received Date: 29 December 2020
Revised Date: 21 May 2021

Figures(7)

Three new coordination polymers, namely, {[Mn₃(oba)₃(bib) (DMF) (H₂O)]·DMF}_n (1), [Co(Hoba)₂(bib)]_n (2), {[Co(aip) (bib)]·DMF}_n (3) (bib=1, 4-bis(imidazol-1-yl) benzene, H₂oba=4, 4'-oxybisbenzoic acid, H₂aip=5-aminoisophthalic acid, DMF=N, N-dimethylformamide) have been solvothermal synthesized and structurally characterized by elemental analysis, FT-IR spectroscopy, UV-Vis spectroscopy, thermogravimetric analysis, single crystal X-ray crystallography and powder X-ray diffraction. Compound 1 reveals a 3D porous metal-organic framework with the point symbol of {3¹⁸; 4³⁷; 5²⁴; 6¹²}{3⁹; 4¹²; 5²; 6³; 7²}{3⁹; 4¹²; 5³; 6⁴}. Compound 2 exhibits a 1D chain structure and the neigh-boring chains are further linked by hydrogen-bond O—H…O interactions to form a 3D supramolecular structure with the point symbol of {10}{8;10⁴; 14}{8³}₂. Compound 3 has a 2D layer structure, which are joined together by hydrogen-bond N—H…O interactions to form a 3D network with the point symbol of {3³; 4¹⁰; 5;6}. Compound 1 shows rapid and selective adsorption of Congo red (CR) from dye mixtures, while compounds 2 and 3 display weak antifer-romagnetic interaction between the Co(Ⅱ) centers.
- coordination polymer,
- crystal structure,
- selective adsorption,
- magnetic property
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