Citation: Qing-Shan QIAO, Sheng ZHANG, Xiao-Ya ZHOU, Li-Bing HU, Hong-Bin LU, Shao-Chun TANG. Preparation of Nickel Foam Supported Fe₂O₃@Ni₃S₂ Nanowires Network Electrode and Electrocatalytic Oxygen Evolution Performance[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(8): 1421-1429. doi: 10.11862/CJIC.2021.162 shu

Preparation of Nickel Foam Supported Fe₂O₃@Ni₃S₂ Nanowires Network Electrode and Electrocatalytic Oxygen Evolution Performance

1.
National Laboratory of Solid State Microstructures, Jiangsu Key Laboratory of Artificial Functional Materials, College of Engineering and Applied Sciences, Nanjing University, Nanjing 210093, China
2.
College of Chemistry and Chemical Engineering, Nantong University, Nantong, Jiangsu 226019, China

Corresponding author: Hong-Bin LU, luhb@ntu.edu.cn Shao-Chun TANG, tangsc@nju.edu.cn
Received Date: 6 April 2021
Revised Date: 13 June 2021

Figures(7)

A two-step hydrothermal method was used to prepare nickel foam (NF) supported Fe₂O₃ nanoparticles@Ni₃S₂ nanowires 3D network electrode (Fe₂O₃@Ni₃S₂/NF). The crystal phase and microstructure features of the products were characterized in detail by using some characterization techniques including X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and N₂ adsorption-desorption measurement and so on. The in situ surface chemical etching process under hydrothermal conditions leads to the generation of Ni₃S₂ nanowires 3D network that binds to NF firmly with relatively low interfacial resistances. In an aqueous electrolyte of 1 mol·L^-1 KOH, the electrocatalytic oxygen evolution reaction (OER) performance of the obtained electrodes was tested by linear sweep voltammetry (LSV), chronopotentiometry, and electrochemical impedance test (EIS). At a ultrathigh current density of 100 mA·cm^-2, Fe₂O₃@Ni₃S₂/NF electrode showed a low OER overpotential of only 223 mV, which was 285 mV lower than that of Ni₃S₂/NF electrode (before growth of Fe₂O₃). These excellent properties are attributed to the faster reaction kinetics and smaller charge transfer impedance of Fe₂O₃@Ni₃S₂/NF electrode comparing with Ni₃S₂/NF.
- hydrothermal method,
- electrocatalysis,
- oxygen evolution reaction,
- Ni₃S₂ nanowire networks,
- Fe₂O₃ nanoparticles
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Preparation of Nickel Foam Supported Fe₂O₃@Ni₃S₂ Nanowires Network Electrode and Electrocatalytic Oxygen Evolution Performance