Citation: Xue ZHANG, Hong-Ji SONG, Nan MA, Jie LIU, Xing-Xing ZHANG, Zhan-Chao WU. Spectral Control of Ba_5-2x-yTb_xNa_x(PO₄)₃Cl: yEu²⁺ Phosphor Achieved by Energy Transfer[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(7): 1251-1257. doi: 10.11862/CJIC.2021.152 shu

Spectral Control of Ba_5-2x-yTb_xNa_x(PO₄)₃Cl: yEu²⁺ Phosphor Achieved by Energy Transfer

College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China

Corresponding author: Zhan-Chao WU, wuzhan_chao@163.com
Received Date: 5 February 2021
Revised Date: 29 May 2021

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In this paper, a series of Ba_5-2x-yTb_xNa_x(PO₄)₃Cl: yEu²⁺ phosphor powder was prepared via [Na⁺, Tb³⁺] ion pairs substituting [Ba²⁺, Ba²⁺] ion pairs. The structure, morphology, composition and luminescence properties were studied through X-ray powder diffraction, scanning electron microscope, photoexcitation and emission spectroscopy. Under excitation at 354 nm, the emission spectra of Ba_3.97Tb_0.50Na_0.50(PO₄)₃Cl: 0.03Eu²⁺ sample was composed of the characteristic broad peak of Eu²⁺ at about 450 nm and the four characteristic sharp peaks of Tb³⁺ at 490, 545, 583 and 622 nm. Due to Eu²⁺→Tb³⁺ energy transfer, the luminescence intensity of Tb³⁺ in Ba_3.97Tb_0.50Na_0.50(PO₄)₃Cl: 0.03Eu²⁺ was significantly increased compared with that of Tb³⁺ in Ba_4.00Tb_0.50Na_0.50(PO₄)₃Cl sample. By changing the concentration of [Na⁺, Tb³⁺] ion pairs, the spectral control of Ba_5-2x-yTb_xNa_x(PO₄)₃Cl: yEu²⁺ phosphor was achieved. When x=0.50, the luminescence intensity of Tb³⁺ in Ba_4.97-2xTb_xNa_x(PO₄)₃Cl: 0.03Eu²⁺ reached the maximum.
- phosphor,
- chemical unit substitution,
- energy transfer,
- spectral control
1. [1]
  Hou J S, Pan C X, Chen X Y, Zhao G Y, Liu Y F, Li Y, Fang Y Z. Mater. Technol. , 2018, 34(3): 1753-5557
2. [2]
  Wu Z C, Cui L L, Zhang X, Zhang X X, Liu J, Ma L, Wang X J, Zhang J L. J. Alloys Compd. , 2020, 835: 155109-155115 doi: 10.1016/j.jallcom.2020.155109
3. [3]
  FAN B, LIU J, QI S M, ZHAO W Y. Spectroscopy and Spectral Analysis, 2020, 40(1): 65-70
4. [4]
  Liu J, Zhang Z M, Wu Z C, Wang F F, Li Z J, Kuang S P, Wu M M. Spectrochim. Acta A, 2017, 171: 126-131 doi: 10.1016/j.saa.2016.07.042
5. [5]
  Babu J K, Rao B S, Suresh K, Sridhar M, Murthy K. Mater. Today: Proceedings, 2019, 18: 2530-2539 doi: 10.1016/j.matpr.2019.07.110
6. [6]
  Lin L, Tang W J. J. Lumin. , 2018, 198: 405-409 doi: 10.1016/j.jlumin.2018.03.001
7. [7]
  Zhang Y Q, Zhang J, Li X W, Jiang X M, Shi J, Wen Y. J. Mater. Sci. : Mater. Electron. , 2018, 29: 3120-3126 doi: 10.1007/s10854-017-8244-0
8. [8]
  Li S D, Meng Q Y, Lv S Y, Sun W J. J. Lumin. , 2018, 200: 103-110 doi: 10.1016/j.jlumin.2018.04.009
9. [9]
  Dong Q, Cui J, Tian Y B, Yang F L, Ming H, Du F, Peng J Q, Ye X Y. J. Lumin. , 2019, 212: 146-153 doi: 10.1016/j.jlumin.2019.04.042
10. [10]
  WU Z C, JIAO Y M, ZHANG X, LIU J, XIANG G T, MA L, WANG X J. Chinese Journal of Lminescence, 2020, 41(10): 1041-1048
11. [11]
  Tang M, Fan Y T, Qiu Z X, Zhang J L, Yu L P, Li C Z, Lian S X, Zhou W L. J. Am. Ceram. Soc. , 2017, 100: 2991-2996 doi: 10.1111/jace.14837
12. [12]
  Jin Y H, Lv Y, Hu Y H, Chen L, Ju G F, Mu Z F. J. Lumin. , 2017, 185: 106-111 doi: 10.1016/j.jlumin.2017.01.004
13. [13]
  Feng Y M, Huang J P, Liu L L, Liu J, Yu X B. Dalton Trans. , 2015, 44: 15006-15013 doi: 10.1039/C5DT01794G
14. [14]
  Liu W R, Huang C H, Yeh C Y, Tsai J C, Chiu Y C, Yeh Y T, Liu R S. Inorg. Chem. , 2012, 51: 9636-9641 doi: 10.1021/ic3007102
15. [15]
  Kim D, Kim S C, Bae J S, Kim S Y, Kim S J, Park J C. Inorg. Chem. , 2016, 55: 8359-8370 doi: 10.1021/acs.inorgchem.6b00637
16. [16]
  Jiao M M, Guo N, Lv W, Jia Y C, Lv W Z, Zhao Q, Shao B Q, You H P. Inorg. Chem. , 2013, 52: 10340-10346 doi: 10.1021/ic401033u
17. [17]
  Chen Y, Wang J, Zhang X G, Zhang G G, Gong M L, Su Q. Sens. Actuators B, 2010, 148: 259-263 doi: 10.1016/j.snb.2010.04.030
18. [18]
  Liu H K, Zhang H Y, Liao L B, Xia Z G. J. Lumin. , 2014, 156: 49-54 doi: 10.1016/j.jlumin.2014.07.010
19. [19]
  Zeng C, Liu H K, Hu Y, Liao L B, Mei L F. Opt. Laser Technol. , 2015, 74: 6-10 doi: 10.1016/j.optlastec.2015.05.003
20. [20]
  Wu Z C, Wang P, Liu J, Li C, Zhou W H, Kuang S P. Mater. Res. Bull. , 2012, 47: 3413-3416 doi: 10.1016/j.materresbull.2012.07.013
21. [21]
  Li K, Zhang Y, Li X J, Shang M M, Lian H Z, Lin J. Dalton Trans. , 2015, 44: 4683-4692 doi: 10.1039/C4DT03720K
22. [22]
  Guan A X, Lu Z Z, Gao F F, Zhang X S, Wang H, Huang T J, Zhou L Y. J. Rare Earth, 2018, 36: 238-242 doi: 10.1016/j.jre.2017.06.013
23. [23]
  Liang C, You H P, Fu Y B, Teng X M, Liu K, He J H. Dalton Trans. , 2015, 44: 8100-8106 doi: 10.1039/C4DT03999H
24. [24]
  Zhang Y Y, Mei L F, Liu H K, Ma X X, Huang Z H, Liao L B. Ceram. Int. , 2015, 41: 14698-14702 doi: 10.1016/j.ceramint.2015.07.193
25. [25]
  Wu Z C, Wang F F, Zhang K, Xu S C, Liu J, Xia Z G, Wu M M. Dyes Pigm. , 2018, 150: 275-283 doi: 10.1016/j.dyepig.2017.12.026
26. [26]
  Shen Y L, Zhang Q, Cheng J M, Sheng Q C, Liu S, Li W T, Chewpradirkul W, Chen D P. Mater. Lett. , 2013, 97: 151-153 doi: 10.1016/j.matlet.2013.01.086
27. [27]
  Sun J Y, Zhu J C, Zhang X Y, Xia Z G, Du H Y. J. Lumin. , 2012, 132: 2937-2942 doi: 10.1016/j.jlumin.2012.05.036
28. [28]
  Zhang M F, Liang Y J, Xu S Y, Zhu Y G, Wu X Y, Liu S Q. CrystEngComm, 2016, 18: 68-76 doi: 10.1039/C5CE01814E
29. [29]
  Dong Q, Cui J, Tian Y B, Yang F L, Ming H, Du F, Peng J Q, Ye X Y. J. Lumin. , 2019, 6: 30254-30256
30. [30]
  Guo Q F, Liao L B, Molokeey M, Mei L F, Liu H K. Mater. Res. Bull. , 2015, 72: 245-251 doi: 10.1016/j.materresbull.2015.07.029
31. [31]
  Xu Q G, Han L, Di Q M, Sun J Y. Ceram. Int. , 2015, 41: 2699-2705 doi: 10.1016/j.ceramint.2014.10.084
32. [32]
  Mo F W, Zhang X G, Sun Z S, Zhu Z P, Guo Z Y, Wu Z C. Ceram. Int. , 2019, 45: 12319-12324 doi: 10.1016/j.ceramint.2019.03.147
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沈阳化工大学材料科学与工程学院沈阳 110142

Spectral Control of Ba5-2x-yTbxNax(PO4)3Cl: yEu2+ Phosphor Achieved by Energy Transfer

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通讯作者: 陈斌, bchen63@163.com

Spectral Control of Ba_5-2x-yTb_xNa_x(PO₄)₃Cl: yEu²⁺ Phosphor Achieved by Energy Transfer