Citation: Zhong-Xuan XU, Li-Feng LI, Xu-Ling BAI, Shi-Fei XU. Enantiomeric Helical Frameworks with dia Net Based on Rigid Ligands from Spontaneous Resolution[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(7): 1191-1196. doi: 10.11862/CJIC.2021.143 shu

Enantiomeric Helical Frameworks with dia Net Based on Rigid Ligands from Spontaneous Resolution

School of Chemistry and Chemical Engineering, Zunyi Normal College, Zunyi, Guizhou 563002, China

Corresponding author: Zhong-Xuan XU, xuzhongxuan4201@163.com
Received Date: 13 December 2020
Revised Date: 18 April 2020

Figures(6)

The enantiomers of complex 1 (1Δ and 1Λ), [Zn(MPA)(2, 5-DIP)]·1.4H₂O (H₂MPA=2-methoxyterephthalic acid, 2, 5-DIP=2, 5-di(1H-imidazol-1-yl)pyridine) were obtained by spontaneous resolution upon crystallization in the absence of any enantiopure reagents under hydrothermal condition. X-ray crystallography reveals that complexes 1Δ and 1Λ crystallize in chiral space groups P4₁ and P4₃ with near-zero Flack parameters, respectively. In complexes 1Δ and 1Λ, three types of helical chains are constructed by Zn²⁺ ions, MPA^2- and/or 2, 5-DIP ligands along c axis. Although these helical chains contain different components and show different structures, they still have same righthanded helical configuration in 1Δ and left-handed helical configuration in 1Λ, respectively. For the width of channels based on helical chains are up to 1.1 nm×1.1 nm, 1.1 nm×0.8 nm and 0.8 nm×0.8 nm, respectively, and such empty structures result in 5-fold-interpenetrating 3D frameworks with 4-connected dia net in complexes 1Δ and 1Λ. Furthermore, UV-Vis spectra measurement for 1 showed a strong absorption band in ultraviolet region, while solid fluorescence curve revealed blue fluorescence property with emission peak at about 435 nm in complex 1. CCDC: 2049948, 1Δ; 2049947, 1Λ.
- chiral coordination polymers,
- spontaneous resolution,
- helical chain,
- 5-fold-interpenetrating structure,
- dia net
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Enantiomeric Helical Frameworks with dia Net Based on Rigid Ligands from Spontaneous Resolution

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com