Citation: Qi-Long ZHANG, Le-Tao SUN, Xian-Jiong YANG, Hong XU, Li-Lang LI, Xiao-Sheng YANG. Synthesis and Crystal Structure of Cu(Ⅱ)/Zn(Ⅱ)/Mn(Ⅱ) Complexes Containing 3-((5-(Pyridin-3-yl)-1, 3, 4-oxadiazol-2-yl)thio)pentane-2, 4-dione Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(6): 989-994. doi: 10.11862/CJIC.2021.134 shu

Synthesis and Crystal Structure of Cu(Ⅱ)/Zn(Ⅱ)/Mn(Ⅱ) Complexes Containing 3-((5-(Pyridin-3-yl)-1, 3, 4-oxadiazol-2-yl)thio)pentane-2, 4-dione Ligand

1.
State Key Laboratory of Functions and Applications of Medicinal Plants, Guizhou Medical University, Guiyang 550014, China
2.
School of Basic Medical Sciences, Guizhou Medical University, Guiyang 550025, China

Corresponding author: Qi-Long ZHANG, gzuqlzhang@126.com
Received Date: 2 December 2020
Revised Date: 9 May 2021

Figures(9)

Three complexes {[Cu₂(L)₄]·CHCl₃}_n (1), {[Zn(L)₂]·4CHCl₃}_n (2) and {[Mn(L)₂]·4CHCl₃}_n (3) were synthesized from the reaction of 3-((5-(pyridin-3-yl)-1, 3, 4-oxadiazol-2-yl)thio)pentane-2, 4-dione (HL) with Cu(OAc)₂·H₂O, Zn(OAc)₂·2H₂O and Mn(OAc)₂·4H₂O, and characterized by elemental analysis, infrared spectroscopy, powder X-ray diffraction and single-crystal X-ray diffraction. In the solid state, coordination polymer 1 forms 1D helical chain structure, and coordination polymer 2 and 3 form 2D network structure.
- β-diketone,
- Cu(Ⅱ) coordination polymer,
- Zn(Ⅱ) coordination polymer,
- Mn(Ⅱ) coordination polymer,
- crystal structure
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Crystal Structure of Cu(Ⅱ)/Zn(Ⅱ)/Mn(Ⅱ) Complexes Containing 3-((5-(Pyridin-3-yl)-1, 3, 4-oxadiazol-2-yl)thio)pentane-2, 4-dione Ligand

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com