Citation: Yu LI, Ying-Fen ZHUANG, Yan-Lai ZHANG, An-Sheng FENG, Xun-Zhong ZOU. Syntheses, Crystal Structures, Luminescence and Catalytic Activity of Manganese(Ⅱ) and Cadmium(Ⅱ) Coordination Polymers Based on 2, 3-Dihydroxy-terephthalic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(6): 1135-1142. doi: 10.11862/CJIC.2021.132 shu

Syntheses, Crystal Structures, Luminescence and Catalytic Activity of Manganese(Ⅱ) and Cadmium(Ⅱ) Coordination Polymers Based on 2, 3-Dihydroxy-terephthalic Acid

Guangdong Research Center for Special Building Materials and Its Green Preparation Technology/Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China

Corresponding author: Xun-Zhong ZOU, 2017018009@gdip.edu.cn
Received Date: 2 February 2021
Revised Date: 25 March 2021

Figures(9)

Two 3D manganese(Ⅱ) and cadmium(Ⅱ) coordination polymers, namely[M(μ₄-H₂DTA)(bipy)]_n (M=Mn (1), Cd (2)), have been constructed hydrothermally using H₄DTA (H₄DTA=2, 3-dihydroxy-terephthalic acid), bipy (bipy=2, 2'-bipyridine), and manganese or cadmium chlorides. Single-crystal X-ray diffraction analyses reveal that two complexes are isostructural and crystallize in the orthorhombic system, space groups Pnna. Both complexes disclose a 3D metal-organic framework. The luminescent and catalytic properties of two complexes were investigated. Complex 1 exhibited good catalytic performance for the cyanosilylation reaction. CCDC: 2060258, 1; 2060259, 2.
- coordination polymer,
- 2, 3-dihydroxy-terephthalic acid,
- luminescence,
- catalytic
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