Citation: Ya-Bo SHI, Guo-Qiang ZHANG, Yu-Chen SUN, Hua-Yan ZHENG, Zhong LI, Ju SHANGGUAN, Jie MI, Shou-Jun LIU, Peng-Zheng SHI. KIT-6 Supported CeO₂ for Catalytic Synthesis of Dimethyl Carbonate from CO₂ and Methanol[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(6): 1004-1016. doi: 10.11862/CJIC.2021.129 shu

KIT-6 Supported CeO₂ for Catalytic Synthesis of Dimethyl Carbonate from CO₂ and Methanol

1.
Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, China
2.
College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China
3.
Taiyuan Green Coke Energy Co., Ltd., Taiyuan 030006, China

Corresponding author: Guo-Qiang ZHANG, zgq198615@163.com Zhong LI, lizhong@tyut.edu.cn
Received Date: 19 December 2020
Revised Date: 10 March 2021

Figures(12)

A series of KIT-6 were synthesized by hydrothermal method at varied aging temperatures (80, 100, 120 and 150℃), which were used as supports to fabricate CeO₂/KIT-6 catalysts. Combined with X-ray diffraction, N₂-physisorption, temperature-programmed desorption of NH₃ and CO₂, transmission electron microscopy, Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy results, the effect of aging temperatures on the structure of KIT-6 and the catalytic activity of CeO₂/KIT-6 for direct synthesis of dimethyl carbonate (DMC) from CO₂ and methanol were investigated in detail. The results indicated that the KIT-6 synthesized at different aging temperatures maintained their unique three-dimensional pore structure. With the increasing aging temperature, the surface areas of KIT-6 firstly increased and then decreased, which attained the maximum (683 m²·g^-1) as the aging temperature was 100℃. High surface areas of KIT-6 favor for the dispersion of CeO₂ and thus improve the number of exposed active sites. The catalytic activity increases with the improved number of the medium base/acid adsorption sites and content of Ce³⁺. Herein, the particle size of CeO₂ for CeO₂/100-KIT-6 was the smallest (5.9 nm) and therefore the number of exposed active sites reached the maximum, which contributed to the optimal catalytic activity. Moreover, the effect of reaction temperature and pressure on the catalytic activity of CeO₂/100-KIT-6 were studied. The results showed that the catalytic activity firstly increased and then decreased with the increasing reaction temperature, and attained the highest as the reaction temperature was 140℃. In addition, the catalytic activity increased with the increase of reaction pressure. Furthermore, the recycle stability of CeO₂/100-KIT-6 was also studied under 140℃ and 6.8 MPa. The results showed that the DMC yield decreased from 15 mmol·g_CeO₂^-1 to 2.8 mmol·g_CeO₂^-1 after recycle six times, which is due to the decrease of active sites resulting from the agglomeration of CeO₂ nanoparticles.
- CO₂,
- CeO₂/KIT-6,
- dimethyl carbonate,
- particle size,
- active sites
1. [1]
  SUN Y C, ZHANG G Q, LIU B, LI Z, SHANGGUAN J, LIU S J, SHI P Z. Chem. Ind. Eng. Prog., 2019, 38(11): 5127-5135
2. [2]
  Zhong J W, Yang X F, Wu Z L, Liang B L, Huang Y Q, Zhang T. Chem. Soc. Rev., 2020, 49(5): 1385-1413 doi: 10.1039/C9CS00614A
3. [3]
  Ronda-Lloret M, Rothenberg G, Shiju N. R. ChemSusChem, 2019, 12(17): 3896-3914 doi: 10.1002/cssc.201900915
4. [4]
  Zhou W, Cheng K, Kang J C, Zhou C, Subramanian V, Zhang Q H, Wang Y. Chem. Soc. Rev., 2019, 48(12): 3193-3228 doi: 10.1039/C8CS00502H
5. [5]
  Liu M S, Wang X, Jiang Y C, Sun J M, Arai M. Catal. Rev., 2018, 61(2): 214-269
6. [6]
  Kumar P, Srivastava V C, Štangar U L, Mušič B, Mishra I M, Meng Y Z. Catal. Rev.-Sci. Eng., 2019, DOI:10.1080/01614940.2019.1696609 doi: 10.1080/01614940.2019.1696609
7. [7]
  Huang S Y, Yan B, Wang S P, Ma X B. Chem. Soc. Rev., 2015, 44(10): 3079-3116 doi: 10.1039/C4CS00374H
8. [8]
  Jung K T, Bell A T. J. Catal., 2001, 204(2): 339-347 doi: 10.1006/jcat.2001.3411
9. [9]
  Liu B, Li C M, Zhang G Q, Yao X S, Chuang S S. C, Li Z. ACS Catal., 2018, 8(11): 10446-10456 doi: 10.1021/acscatal.8b00415
10. [10]
  Wang S P, Zhao L F, Wang W, Zhao Y J, Zhang G L, Ma X B, Gong J L. Nanoscale, 2013, 5(12): 5582-5588 doi: 10.1039/c3nr00831b
11. [11]
  Marciniak A A, Alves O C, Appel L G, Mota C J. A. J. Catal., 2019, 371: 88-95 doi: 10.1016/j.jcat.2019.01.035
12. [12]
  Liu B, Li C M, Zhang G Q, Yan L F, Li Z. New J. Chem., 2017, 41(20): 12231-12240 doi: 10.1039/C7NJ02606D
13. [13]
  ZHANG G Q, SUN Y C, SHI Y B, ZHENG H Y, LI Z, SHANGGUAN J, LIU S J, SHI P Z. Chem. J. Chinese Universities, 2020, 9(41): 2061-2069
14. [14]
  Liu H, Zou W J, Xu X L, Zhang X L, Yang Y Q, Yue H J, Yu Y, Tian G, Feng S H. J. CO₂ Util., 2017, 17: 43-49 doi: 10.1016/j.jcou.2016.11.006
15. [15]
  Fu Z W, Zhong Y Y, Yu Y H, Long L Z, Xiao M, Han D M, Wang S J, Meng Y Z. ACS Omega, 2018, 3(1): 198-207 doi: 10.1021/acsomega.7b01475
16. [16]
  Soni K, Rana B S, Sinha A K, Bhaumik A, Nandi M, Kumar M, Dhar G. M. Appl. Catal. B, 2009, 90(1/2): 55-63
17. [17]
  Cao H X, Zhang J, Guo C L, Chen J G, Ren X K. Chin. J. Catal., 2017, 38(7): 1127-1137 doi: 10.1016/S1872-2067(17)62862-6
18. [18]
  Subhan F, Aslam S, Yan Z F, Ikram M, Rehman S. Microporous Mesoporous Mater., 2014, 199: 108-116 doi: 10.1016/j.micromeso.2014.08.018
19. [19]
  Cao H X, Wang W Y, Cui T L, Wang H Y, Zhu G, Ren X K. Energies, 2020, 13(9): 2235 doi: 10.3390/en13092235
20. [20]
  Zhou X F, Wan J W, Liu Y F, Liu D, Wang H, Lai X Y, Zou Y Z, Lin G, Chen J. Nano, 2017, 12(9): 1750104 doi: 10.1142/S1793292017501041
21. [21]
  Taghizadeh M, Akhoundzadeh H, Rezayan A, Sadeghian M. Int. J. Hydrogen Energy, 2018, 43(24): 10926-10937 doi: 10.1016/j.ijhydene.2018.05.034
22. [22]
  Bai B Y, Qiao Q, Li Y P, Peng Y, Li J H. Chin. J. Catal., 2018, 39(4): 630-638 doi: 10.1016/S1872-2067(18)63036-0
23. [23]
  Kleitz F, Choi S, Ryoo R. Chem. Commun., 2003, 9: 2136-2137
24. [24]
  Harun T S, Christian W. L, Hans B, Bernd T, Roland S, Ferdi S. J. Am. Chem. Soc., 2008, 130(34): 11510-11517 doi: 10.1021/ja803362s
25. [25]
  Hu B, Liu H, Tao K, Xiong C R, Zhou S H. J. Phys. Chem. C, 2013, 117(49): 26385-26395 doi: 10.1021/jp4098028
26. [26]
  Shao Y F, Wang L Z, Zhang J L, Anpo M. J. Phys. Chem. B, 2005, 109: 20835-20841 doi: 10.1021/jp054024+
27. [27]
  Zhang J Y, Zhao S Y, Zhao Y J, Ma X B, Wang S P. Asia-Pac. J. Chem. Eng., 2021, 16(1): e2517
28. [28]
  Chen Y D, Tang Q, Ye Z B, Li Y, Yang Y, Pu H Y, Li G. New J. Chem., 2020, 44(29): 12522-12530 doi: 10.1039/D0NJ02650F
29. [29]
  CHU S L, LI X, Robertson A W, SUN Z Y. Acta Phys.-Chim. Sin., 2021, 37(5): 2009023
30. [30]
  Chu S L, Yan X P, Choi C H, Hong S, Robertson A W, Masa J, Han B X, Jung Y S, Sun Z Y. Green Chem., 2020, 22(19): 6540-6546 doi: 10.1039/D0GC02279A
31. [31]
  Kumar P, Srivastava V C, Gläser R, With P, Mishra I M. Powder Technol., 2017, 309: 13-21 doi: 10.1016/j.powtec.2016.12.016
32. [32]
  Zhao S Y, Wang S P, Zhao Y J, Ma X B. Chin. Chem. Lett., 2017, 28(1): 65-69 doi: 10.1016/j.cclet.2016.06.003
33. [33]
  Hu W K, He F, Chen X, Liu S T. J. Nanopart. Res., 2018, 21(1): 6
34. [34]
  Kumar P, With P, Srivastava V C, Shukla K, Gläser R, Mishra I M. RSC Adv., 2016, 6(111): 110235-110246 doi: 10.1039/C6RA22643D
35. [35]
  Zhang M, Xiao M, Wang S J, Han D M, Lu Y X, Meng Y Z. J. Cleaner Prod., 2015, 103: 847-853 doi: 10.1016/j.jclepro.2014.09.024
36. [36]
  Li A X, Pu Y F, Li F, Luo J, Zhao N, Xiao F K. J. CO₂ Util., 2017, 19: 33-39 doi: 10.1016/j.jcou.2017.02.016
37. [37]
  Zhang R, Guo L, Chen C, Chen J Z, Chen A J, Zhao X G, Liu X R, Xiu Y H, Hou Z S. Catal. Sci. Technol., 2015, 5(5): 2959-2972 doi: 10.1039/C5CY00166H
38. [38]
  Chen S C, Wang H, Kang Z X, Jin S, Zhang X D, Zheng X S, Qi Z M, Zhu J F, Pan B C, Xie Y. Nat. Commun., 2019, 10(1): 788 doi: 10.1038/s41467-019-08697-x
39. [39]
  Fu Y, Zhu H, Shen J. Thermochim. Acta, 2005, 434(1/2): 88-92
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

KIT-6 Supported CeO2 for Catalytic Synthesis of Dimethyl Carbonate from CO2 and Methanol

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通讯作者: 陈斌, bchen63@163.com

KIT-6 Supported CeO₂ for Catalytic Synthesis of Dimethyl Carbonate from CO₂ and Methanol