Citation: Geng GUO, Juan LI, Ya WU, Wen-Min DING, Shu-Zhen ZHANG, Yin-Xia SUN. Self-Assembled Zn²⁺, Co²⁺ and Ni²⁺ Complexes Based on Coumarin Schiff Base Ligands: Synthesis, Crystal Structure and Spectral Properties[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(6): 1113-1124. doi: 10.11862/CJIC.2021.124 shu

Self-Assembled Zn²⁺, Co²⁺ and Ni²⁺ Complexes Based on Coumarin Schiff Base Ligands: Synthesis, Crystal Structure and Spectral Properties

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China

Corresponding author: Yin-Xia SUN, sun_yinxia@163.com
Received Date: 30 September 2020
Revised Date: 19 March 2021

Figures(7)

Mononuclear Zn²⁺, Co²⁺ complexes and binuclear Ni²⁺ complex based on coumarin Schiff base ligands, [Zn(L¹)₂] (1) (HL¹=6-((4-diethylamino-2-hydroxy-benzylidene)-amino)-benzopyran-2-one), [Co(L²)₂] (2) (HL²=6-((4-methoxy-2-hydroxy-benzylidene)-amino)-benzopyran-2-one) and[Ni₂(L³)₂(CH₃OH)₄] (3) (H₂L³=4-hydroxy-3-((4-methoxy-2-hydroxy-benzylidene)-amino)-benzopyran-2-one), were synthesized and characterized by elemental analysis, IR, UV-Vis, fluorescence spectra and X-ray single crystal diffraction analysis. The crystal structure analysis represents that the complexes 1 and 2 possess mononuclear structure composed of one metal ion (Zn²⁺ or Co²⁺) and two ligand units ((L¹)^- or (L²)^-). Whereas complex 3 had binuclear structure, containing two Ni²⁺ ions, two ligand units (L³)^2- and four coordination methanol molecules. The crystals of complexes 1, 2 and 3 are solved as monoclinic space group C2/c, triclinic space group P1 and triclinic space group P2₁/n, respectively. The spatial configurations of the central metal Zn²⁺ and Co²⁺ ions are four-coordinated tetrahedrons, and the Ni²⁺ ion is six-coordinated twisted octahedrons. In addition, UV-Vis studies demonstrate that the free ligands HL¹ in DMF/H₂O (4:1, V/V) solution and HL² in DMSO/H₂O (4:1, V/V) solution could selectively recognize Hg²⁺ and Zn²⁺, respectively. The detection limits were calculated to be 7.45 and 6.10 μmol·L^-1, respectively. Fluorescence studies indicate that HL² exhibits ability of selective recognition Zn²⁺ against other common cationic including Ag⁺, Ba²⁺, Ca²⁺, Cd²⁺, Cr³⁺, Cu²⁺, Fe³⁺, Mg²⁺, Mn²⁺ and Hg²⁺ in DMSO/H₂O (4:1, V/V), and the detection limit was calculated to be 2.91 μmol·L^-1.
- coumarin Schiff-base,
- transition metal complex,
- crystal structure,
- spectral property
1. [1]
  Zhao Q, An X X, Liu L Z, Dong W K. Inorg. Chim. Acta, 2019, 490: 6-15 doi: 10.1016/j.ica.2019.02.040
2. [2]
  Georgieva I, Zahariev T, Aquino A J A, Trendafilova N, Lischka H. Spectrochim. Acta Part A, 2020, 240: 118591 doi: 10.1016/j.saa.2020.118591
3. [3]
  ZHANG S Z, CHANG J, ZHANG H J, WU Y, SUN Y X, WANG Y B. Chinese J. Inorg. Chem. , 2020, 36(3): 503-514
4. [4]
  Sourbh S G, Jeena G, Shikha S, Debasis S. Eur. J. Pharm. Sci. , 2020, 152: 105424 doi: 10.1016/j.ejps.2020.105424
5. [5]
  Sun Y X, Pan Y Q, Xu X, Zhang Y. Crystals, 2019, 9: 607 doi: 10.3390/cryst9120607
6. [6]
  Yang Y S, Liang C, Yang C, Zhang Y P, Wang B X, Liu J. Spectrochim. Acta Part A, 2020, 237: 118391 doi: 10.1016/j.saa.2020.118391
7. [7]
  Zhang Y, Liu L Z, Peng Y D, Li N, Dong W K. Transition Met. Chem. , 2019, 44: 627-639 doi: 10.1007/s11243-019-00325-3
8. [8]
  Liu L Z, Wang L, Yu M, Zhao Q, Zhang Y, Sun Y X, Dong W K. Spectrochim. Acta Part A, 2019, 222: 117209 doi: 10.1016/j.saa.2019.117209
9. [9]
  Yu B, Li C Y, Sun Y X, Jia H R, Guo J Q, Li J. Spectrochim. Acta Part A, 2017, 184: 249-254 doi: 10.1016/j.saa.2017.05.012
10. [10]
  Mu H R, An X X, Liu C, Zhang Y, Dong W K. J. Struct. Chem. , 2020, 61: 1155-1166 doi: 10.1134/S0022476620070203
11. [11]
  Wei Z L, Wang L, Guo S Z, Zhang Y, Dong W K. RSC Adv. , 2019, 9: 41298 doi: 10.1039/C9RA09017G
12. [12]
  Kang Q P, Li X Y, Wang L, Zhang Y, Dong W K. Appl. Organomet. Chem. , 2019, 33: e5013
13. [13]
  YU M, MU H R, LIU L Z, LI N, BAI Y, DONG X Y. Chinese J. Inorg. Chem. , 2019, 35(6): 1109-1121
14. [14]
  Jia H R, Chang J, Zhang H J, Li J, Sun Y X. Crystals, 2018, 8: 272 doi: 10.3390/cryst8070272
15. [15]
  Deilami A B, Salehi M, Arab A, Amiri A. Spectrochim. Acta Part A, 2018, 476: 93-100
16. [16]
  Wang L, Wei Z L, Liu C, Dong W K, Ru J X. Spectrochim. Acta A, 2020, 239: 118496 doi: 10.1016/j.saa.2020.118496
17. [17]
  Pan Y Q, Zhang Y, Yu M, Zhang Y, Wang L. Appl. Organomet. Chem. , 2020, 34: e5441
18. [18]
  Mu H R, Yu M, Wang L, Zhang Y, Ding Y J. Phosphorus Sulfur Silicon Relat. Elem. , 2020, 195: 730-739 doi: 10.1080/10426507.2020.1756807
19. [19]
  Jia H R, Li J, Sun Y X, Guo J Q, Yu B, Wen N, Xu L. Crystals, 2017, 7: 247 doi: 10.3390/cryst7080247
20. [20]
  Sanjoy K S, Sen B, Thounaojam R, Aguan K, Khatua S. J. Photochem. Photobiol. A, 2017, 332: 101-111 doi: 10.1016/j.jphotochem.2016.08.019
21. [21]
  MacLean L, Karcz D, Jenkins H, McClean S, Devereux M, Howe O, Pereiraet M D, May N V, Enyedy E A, Creaven B S. J. Inorg. Biochem. , 2019, 197: 110702 doi: 10.1016/j.jinorgbio.2019.110702
22. [22]
  Li J, Zhang H J, Chang J, Jia H R, Sun Y X, Huang Y Q. Crystals, 2018, 8: 176 doi: 10.3390/cryst8040176
23. [23]
  Kang Q P, Li X Y, Wei Z L, Zhang Y, Dong W K. Polyhedron, 2019, 165: 38-50 doi: 10.1016/j.poly.2019.03.008
24. [24]
  Yu M, Zhang Y, Pan Y Q, Wang L. Inorg. Chim. Acta, 2020, 509: 119701 doi: 10.1016/j.ica.2020.119701
25. [25]
  Ghosh S, Roy N, Singh T S, Chattopadhyay N. Spectrochim. Acta Part A, 2018, 188: 252-257 doi: 10.1016/j.saa.2017.07.006
26. [26]
  An X X, Zhao Q, Mu H R, Dong W K. Crystals, 2019, 9: 101 doi: 10.3390/cryst9020101
27. [27]
  Datta P, Mukhopadhyay A P, Manna P, Tiekink E R T, Sil P C, Sinha C. J. Inorg. Biochem. , 2011, 105: 577-588 doi: 10.1016/j.jinorgbio.2010.04.013
28. [28]
  Danış Ö, Basak Y D, Cihan G, Ayşe O. Arzneim. -Forsch. , 2010, 60: 617-620
29. [29]
  SAINT, Version 6.02, Bruker AXS Inc., Madison, WI, USA, 2002.
30. [30]
  SADABS, Version 2.03, Bruker AXS Inc., Madison, WI, USA, 2002.
31. [31]
  Sheldrick G M. SHELXL-2014/7, University of Göttingen, Germany, 2014.
32. [32]
  Zhang L W, Zhang Y, Cui Y F, Yu M, Dong W K. Inorg. Chim. Acta, 2020, 506: 119534 doi: 10.1016/j.ica.2020.119534
33. [33]
  Zhang S Z, Guo G, Ding W M, Li J, Wu Y, Zhang H J, Guo J Q, Sun Y X. J. Mol. Struct. , 2021, 1230: 129627 doi: 10.1016/j.molstruc.2020.129627
34. [34]
  Chang J, Zhang S Z, Wu Y, Zhang H J, Sun Y X. Transition Met. Chem. , 2020, 45: 279-293 doi: 10.1007/s11243-020-00379-8
35. [35]
  Zhang Y, Pan Y Q, Yu M, Xu X, Dong W K. Appl. Organomet. Chem. , 2019, 33: e5240
36. [36]
  ZHANG H J, CHANG J, JIA H R, SUN Y X. Chinese J. Inorg. Chem. , 2018, 34(12): 2261-2270 doi: 10.11862/CJIC.2018.261
37. [37]
  Cui Y F, Zhang Y, Xie K F, Dong W K. Crystals, 2019, 9: 596 doi: 10.3390/cryst9110596
38. [38]
  Liu C, Wei Z L, Mu H R, Dong W K, Ding Y J. J. Photochem. Photobiol. A, 2020, 397: 112569 doi: 10.1016/j.jphotochem.2020.112569
39. [39]
  Xu L, Yu M, Li L H, Ma J C, Dong W K. J. Struct. Chem. , 2019, 60: 1358
40. [40]
  An X X, Chen Z Z, Mu H R, Zhao L. Inorg. Chim. Acta, 2020, 511: 119823 doi: 10.1016/j.ica.2020.119823
41. [41]
  CHANG J, ZHANG H J, JIA H R, SUN Y X. Chinese J. Inorg. Chem. , 2018, 34(11): 2097-2107 doi: 10.11862/CJIC.2018.256
42. [42]
  Zhang Y, Yu M, Pan Y Q, Zhang Y, Xu L, Dong W K. Appl. Organomet. Chem. , 2020, 34: e5442
43. [43]
  Wang L, Wei Z L, Chen Z Z, Liu C, Dong W K, Ding Y J. Microchem. J. , 2020, 155: 104801 doi: 10.1016/j.microc.2020.104801
44. [44]
  LIU L Z, YU M, Li X Y, KANG Q P, DONG W K. Chinese J. Inorg. Chem. , 2019, 35(7): 1283-1294
45. [45]
  Wu Y, Ding W M, Li J, Guo G, Zhang S Z, Jia H R, Sun Y X. J. Fluoresc. , 2021, 31: 437-446 doi: 10.1007/s10895-020-02677-x
46. [46]
  Bian R N, Wang J F, Li Y J, Zhang Y, Dong W K. J. Photochem. Photobiol. A, 2020, 403: 112829 doi: 10.1016/j.jphotochem.2020.112829
47. [47]
  Xu X, Bian R N, Guo S Z, Dong W K, Ding Y J. Inorg. Chim. Acta, 2020, 513: 119945 doi: 10.1016/j.ica.2020.119945
48. [48]
  Wang Y, Wu H, Wu W N, Li S J, Xu Z H, Xu Z Q, FanY C, Zhao X L, Liu B Z. Sens. Actuators B, 2018, 260: 106-115 doi: 10.1016/j.snb.2017.12.201
49. [49]
  Liu C, An X X, Cui Y F, Xie K F, Dong W K. Appl. Organomet. Chem. , 2020, 34: e5272
50. [50]
  Xu X, Li Y J, Feng T, Dong W K, Ding Y J. J. Lumin. , 2021, 36: 169-179 doi: 10.1002/bio.3932
51. [51]
  He W Y, Liu R Q, Liao Y H, Ding G H, Li J L, Liu W, Wu L Y, Feng H J, Shi Z F, He M X. Anal. Biochem. , 2020, 598: 113690 doi: 10.1016/j.ab.2020.113690
52. [52]
  Kaur B, Gupta A, Kaur N. Microchem. J. , 2020, 153: 104508 doi: 10.1016/j.microc.2019.104508
53. [53]
  Wang Y G, Hou X F, Yan Q M, Liu X L, Xia G M, Shao Q Q, Liang K L, Hong L M, Chi B Z, Wang H M. Dyes Pigm. , 2020, 173: 107951 doi: 10.1016/j.dyepig.2019.107951
54. [54]
  Fan L, Qin J C, Li C R, Yang Z Y. Spectrochim. Acta Part A, 2020, 236: 118347 doi: 10.1016/j.saa.2020.118347
55. [55]
  Wang L, Pan Y Q, Wang J F, Zhang Y, Ding Y J. J. Photochem. Photobiol. A, 2020, 400: 112719 doi: 10.1016/j.jphotochem.2020.112719
56. [56]
  World Health Organization. Zinc in Drinking-water: WHO/SDE/WSH/03.04/17. Geneva: World Health Organization, 1996.
57. [57]
  Yuan C X, Li S Y, Wu Y B, Lu L P, Zhu M L. Sens. Actuators B, 2017, 242: 1035-1042 doi: 10.1016/j.snb.2016.09.149
58. [58]
  Abbasi Z, Mehdi S, Khaleghian A, Kubicki M. J. Mol. Struct. , 2018, 1173: 213-220 doi: 10.1016/j.molstruc.2018.06.104
59. [59]
  Wei Z L, Wang L, Wang J F, Zhang Y, Guo W T, Dong W K. Spectrochim. Acta Part A, 2020, 228: 117775 doi: 10.1016/j.saa.2019.117775
60. [60]
  Pan Y Q, Xu X, Zhang Y, Zhang Y, Dong W K. Spectrochim. Acta Part A, 2020, 229: 117927 doi: 10.1016/j.saa.2019.117927
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Self-Assembled Zn2+, Co2+ and Ni2+ Complexes Based on Coumarin Schiff Base Ligands: Synthesis, Crystal Structure and Spectral Properties

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通讯作者: 陈斌, bchen63@163.com

Self-Assembled Zn²⁺, Co²⁺ and Ni²⁺ Complexes Based on Coumarin Schiff Base Ligands: Synthesis, Crystal Structure and Spectral Properties