Citation: Dong-Xu JIA, Xiang-Xiang HUANG, Chun-Kui HU, Ling-Yan FEI, Lang-Lang YOU, Chun-Xin Lü, Wei ZHONG. Synthesis of Magnetic Fe₃O₄-Supported Schiff Base Materials and Adsorption Properties of Cu(Ⅱ), Pb(Ⅱ) and Cd(Ⅱ)[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(6): 1080-1088. doi: 10.11862/CJIC.2021.117 shu

Synthesis of Magnetic Fe₃O₄-Supported Schiff Base Materials and Adsorption Properties of Cu(Ⅱ), Pb(Ⅱ) and Cd(Ⅱ)

1.
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China
2.
CAS Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Beijing 100190, China

Corresponding author: Chun-Xin Lü, chunxin.lu@mail.zjxu.edu.cn Wei ZHONG, weizhong@mail.zjxu.edu.cn
Received Date: 27 January 2021
Revised Date: 6 April 2021

Figures(10)

The magnetic Fe₃O₄-supported Schiff base adsorption material was synthesized via the reaction with activated silica gel silane and salicylaldehyde or its derivatives by homogeneous method and heterogeneous method, respectively. The prepared materials were fully characterized by infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and so on. The adsorption performance of these materials on Cu(Ⅱ), Pb (Ⅱ) and Cd(Ⅱ) in water was studied at 30℃. The effects of synthesis method, pH value, ion concentration and material structures on the adsorption properties were examined. Finally, the regeneration property of the adsorbent was evaluated. The results showed that the obtained materials exhibited good adsorption performance for Cu (Ⅱ), Pb(Ⅱ) and Cd(Ⅱ) ions, and the adsorption capacity increased with the increase of pH value in the range of 1~6. The adsorption capacity of the adsorbents obtained by heterogeneous method was better than those of homogeneous method. In addition, the materials bearing electron-donating groups on the Schiff base showed better adsorption properties. This type of adsorbent exhibited good regeneration property with 89.4% regeneration rate after 4 cycles.
- magnetic material,
- Schiff base,
- regeneration,
- heavy metal ions,
- adsorption
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Synthesis of Magnetic Fe₃O₄-Supported Schiff Base Materials and Adsorption Properties of Cu(Ⅱ), Pb(Ⅱ) and Cd(Ⅱ)