Citation: Hong-Dao LI, Li-Jun ZHAI, Yong-Bo SONG, Yu-Lan NIU. Two Nitronyl Nitroxide Biradical-Bridged Lanthanide One-Dimensional Chains: Crystal Structure, Magnetic Properties and Luminescent Behavior[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(5): 914-920. doi: 10.11862/CJIC.2021.113 shu

Two Nitronyl Nitroxide Biradical-Bridged Lanthanide One-Dimensional Chains: Crystal Structure, Magnetic Properties and Luminescent Behavior

Department of Chemistry and Chemical Engineering, Taiyuan Institute of Technology, Taiyuan 030008, China

Corresponding author: Hong-Dao LI, lihong.dao@163.com Yu-Lan NIU, niuyulan@163.com
Received Date: 29 November 2020
Revised Date: 2 April 2021

Figures(8)

The rational design of 2p-4f chains, which are made of 4f ions and nitronyl nitroxide biradical, has been presented. The reaction of Ln(hfac)₃·2H₂O (hfac=hexafluoroacetylacetonate) and nitronyl nitroxide biradical BNPhOEt (BNPhOEt=1, 2-(bis-2, 2'-(4, 4, 5, 5-tetramethylimidazolyl-1-oxyl-3-oxide) phenoxy)ethane) afforded two isostructural chains of the formula[Ln(hfac)₃(BNPhOEt)]·C₆H₁₄ (Ln=Tb (1), Ho (2)). Direct-current magnetic susceptibility studies show ferromagnetic 4f-radical interaction in Tb complex while antiferromagnetic interaction in Ho derivative. In addition, the luminescence emission spectra of two complexes vary depending on lanthanide ion.
- biradical,
- lanthanide chains,
- magnetic properties,
- luminescent behavior
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