Citation: Jian-Jun CHEN, Yong-Yu LI, Ya-Ping WANG, Tian-Lu CUI, Ai-Ling JIN, Xiao-Lin SHANG, Yan QIAO. Preparation and Photocatalytic Activity of C/g-C₃N₄/MoS₂ Composites[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(5): 791-797. doi: 10.11862/CJIC.2021.104 shu

Preparation and Photocatalytic Activity of C/g-C₃N₄/MoS₂ Composites

1.
School of Chemistry and Chemical Engineering, Zhengzhou Normal University, Zhengzhou 450044, China
2.
Department of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, China

Corresponding author: Jian-Jun CHEN, jianjunch82612@163.com Tian-Lu CUI, luluroom@163.com
Received Date: 26 October 2020
Revised Date: 28 January 2021

Figures(12)

C/g-C₃N₄ was firstly prepared by thermal condensation method with urea and glucose as precursors, and then C/g-C₃N₄/MoS₂ ternary composites were synthesized by solvothermal method. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), N₂ adsorption-desorption, ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS), photoluminescence spectroscopy (PL) and transient photocurrent analytical tests were used to characterize the crystal structure, morphology, specific surface area and optical properties of photocatalysts. In comparison with the C/g-C₃N₄, the ternary composites not only present a larger specific surface area, stronger light absorption capacity, but also were more favorable for electron transfer. At the same time, the performance of visible light catalytic degradation of methyl orange was studied. It was found that C/g-C₃N₄/MoS₂-2.0% (Mass fraction of MoS₂: 2.0%) showed the highest reaction rate constant (0.008 6 min^-1), which was 5.7 times and 2.3 times of g-C₃N₄/MoS₂ 2.0% (0.001 5 min^-1) and C/g-C₃N₄ (0.003 6 min^-1), respectively.
- g-C₃N₄,
- amorphous carbon,
- MoS₂,
- visible light catalysis
1. [1]
  Wang X C, Maeda K, Thomas A, Takanabe K, Xin G, Carlsson J M, Domen K, Antonietti M. Nat. Mater. , 2009, 8: 76-80 doi: 10.1038/nmat2317
2. [2]
  Ishida Y, Chabane L, Antonietti M, Shalom M. Langmuir, 2014, 30(2): 447-451 doi: 10.1021/la404101h
3. [3]
  Zhang J S, Chen X F, Takanabe K, Maeda K, Domen K, Epping J D, Fu X Z, Antonietti M, Wang X C. Angew. Chem. Int. Ed. , 2010, 49(1): 441-444
4. [4]
  Liu G, Niu P, Sun C H, Smith S C, Chen Z G, Cheng H M. J. Am. Chem. Soc. , 2010, 132(33): 11642-11648 doi: 10.1021/ja103798k
5. [5]
  Jiao Y Y, Huang Q Z, Wang J S, He Z H, Li Z J. Appl. Catal. B, 2019, 247: 124-132 doi: 10.1016/j.apcatb.2019.01.073
6. [6]
  Patnaik S, Martha S. Inorg. Chem. Front. , 2016, 3: 336-347 doi: 10.1039/C5QI00255A
7. [7]
  Shi L, Liang L, Ma J, Wang F X, Sun J M. Dalton. Trans. , 2014, 43(19): 7236-7244 doi: 10.1039/C4DT00087K
8. [8]
  Chen Y L, Li J H, Hong Z H, Shen B, Lin B Z, Gao B F. Phys. Chem. Chem. Phys. , 2014, 16(17): 8106-8113 doi: 10.1039/c3cp55191a
9. [9]
  Bai X J, Wang L, Wang Y, Yao W Q, Zhu Y F. Appl. Catal. B, 2014, 152: 262-270
10. [10]
  Low J X, Yu J G, Ho W K. J. Phys. Chem. Lett. , 2015, 6(21): 4244-4251 doi: 10.1021/acs.jpclett.5b01610
11. [11]
  Xu Q L, Cheng B, Yu J G, Liu G. Carbon, 2017, 118: 241-249 doi: 10.1016/j.carbon.2017.03.052
12. [12]
  Zhao H, Dong Y M, Jiang P P, Miao H Y, Wang G L, Zhang J L. J. Mater. Chem. A, 2015, 3(14): 7375-7381 doi: 10.1039/C5TA00402K
13. [13]
  Hou Y, Wen Z H, Cui S M, Guo X, Chen J H. Adv. Mater. , 2013, 25(43): 6291-6297 doi: 10.1002/adma.201303116
14. [14]
  Jiang Y B, Lin Z G, Zhang Y Y, Lai Y C, Liang D, Yang C Z. New J. Chem. , 2020, 44: 17891-17898 doi: 10.1039/D0NJ04169F
15. [15]
  Cui Y J, Zhang J S, Zhang G G, Huang J H, Liu P, Antoniettib M, Wang X C. J. Mater. Chem. , 2011, 21: 13032-13039 doi: 10.1039/c1jm11961c
16. [16]
  Du X R, Zou G J, Wang Z G, Wang X L. Nanoscale, 2015, 7: 8701-8706 doi: 10.1039/C5NR00665A
17. [17]
  She X, Liu L, Ji H, Mo Z, Li Y, Huang L, Du D L, Xu H, Li H M. Appl. Catal. B, 2016, 187: 144-153 doi: 10.1016/j.apcatb.2015.12.046
18. [18]
  Yang X, Qian F, Zou G, Li M, Lu J R, Li Y M, Bao M. Appl. Catal. B, 2016, 193: 22-35 doi: 10.1016/j.apcatb.2016.03.060
19. [19]
  Li X L, Li Y D. J. Phys. Chem. B, 2004, 108(37): 13893-13900 doi: 10.1021/jp0367575
20. [20]
  Cheng A, Zhang H Y, Zhong W H, Li Z P, Cheng D J, Lin Y G, Tang Y D, Shao H Y, Li Z H. Carbon, 2020, 168: 691-700 doi: 10.1016/j.carbon.2020.07.008
21. [21]
  Ye S, Wang R, Wu M Z, Yuan Y P. Appl. Surf. Sci. , 2015, 358: 15-27 doi: 10.1016/j.apsusc.2015.08.173
1. [1]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
2. [2]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
3. [3]
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4. [4]
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5. [5]
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6. [6]
  Hui Wang , Abdelkader Labidi , Menghan Ren , Feroz Shaik , Chuanyi Wang . 微观结构调控的g-C₃N₄在光催化NO转化中的最新进展：吸附/活化位点的关键作用. Acta Physico-Chimica Sinica, 2025, 41(5): 100039-. doi: 10.1016/j.actphy.2024.100039
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9. [9]
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11. [11]
  Xinyu Guo , Chang Li , Wenjun Deng , Yi Zhou , Yan Chen , Yushuang Xu , Rui Li . Phase engineering and heteroatom incorporation enable defect-rich MoS₂ for long life aqueous iron-ion batteries. Chinese Chemical Letters, 2025, 36(3): 109715-. doi: 10.1016/j.cclet.2024.109715
12. [12]
  Guixu Pan , Zhiling Xia , Ning Wang , Hejia Sun , Zhaoqi Guo , Yunfeng Li , Xin Li . Preparation of high-efficient donor-π-acceptor system with crystalline g-C3N4 as charge transfer module for enhanced photocatalytic hydrogen evolution. Chinese Journal of Structural Chemistry, 2024, 43(12): 100463-100463. doi: 10.1016/j.cjsc.2024.100463
13. [13]
  Wenda WANG , Jinku MA , Yuzhu WEI , Shuaishuai MA . Waste biomass-derived carbon modified porous graphite carbon nitride heterojunction for efficient photodegradation of oxytetracycline in seawater. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 809-822. doi: 10.11862/CJIC.20230353
14. [14]
  Yanghanbin Zhang , Dongxiao Wen , Wei Sun , Jiahe Peng , Dezhong Yu , Xin Li , Yang Qu , Jizhou Jiang . State-of-the-art evolution of g-C3N4-based photocatalytic applications: A critical review. Chinese Journal of Structural Chemistry, 2024, 43(12): 100469-100469. doi: 10.1016/j.cjsc.2024.100469
15. [15]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-. doi: 10.3866/PKU.WHXB202402016
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  Ping Wang , Ting Wang , Ming Xu , Ze Gao , Hongyu Li , Bowen Li , Yuqi Wang , Chaoqun Qu , Ming Feng . Keplerate polyoxomolybdate nanoball mediated controllable preparation of metal-doped molybdenum disulfide for electrocatalytic hydrogen evolution in acidic and alkaline media. Chinese Chemical Letters, 2024, 35(7): 108930-. doi: 10.1016/j.cclet.2023.108930
17. [17]
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18. [18]
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19. [19]
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20. [20]
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Preparation and Photocatalytic Activity of C/g-C₃N₄/MoS₂ Composites