Citation: Hao CHEN, Shi-Biao REN, Ping ZHANG, Zhi-Cai WANG, Zhi-Ping LEI, Shi-Gang KANG, Chun-Xiu PANG, Jing-Chong YAN, Zhan-Ku LI, Heng-Fu SHUI. Highly Dispersed Ni/MCM-41 Catalyst: Solvent-Free Preparation and Performance for Hydrogenation of Naphthalene[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(5): 817-823. doi: 10.11862/CJIC.2021.097 shu

Highly Dispersed Ni/MCM-41 Catalyst: Solvent-Free Preparation and Performance for Hydrogenation of Naphthalene

Anhui Province Key Laboratory of Coal Clean Conversion and High Valued Utilization, School of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan, Anhui 243002, China

Corresponding author: Shi-Biao REN, rensb@ahut.edu.cn Heng-Fu SHUI, shhf@ahut.edu.cn
Received Date: 5 November 2020
Revised Date: 9 January 2021

Figures(6)

Ni/MCM-41 catalysts were prepared with a solvent-free method of mechanical grinding. Furtherly, Ni/MCM-41(CA) catalyst was also prepared by adding citric acid during preparation of Ni/MCM-41. Compared with Ni/MCM-41(IM) catalyst prepared with the conventional impregnation method, the physical properties of the catalyst with the solvent-free method were almost unchanged. And the dispersion of metallic nickel and the performance of naphthalene hydrogenation were slightly improved. After adding citric acid during preparation of Ni/MCM-41, the dispersion of metallic nickel in Ni/MCM-41(CA) catalyst was greatly increased from 6.9% to 67.9%, and the performance of naphthalene hydrogenation was nearly enhanced 100%. Through infrared spectroscopy, UV spectra and thermogravimetric analysis, the promotion mechanism for adding citric acid in the solvent-free method was attributed to forming a kind of nickel citrate by adding citric acid during preparation of Ni/MCM-41.
- Ni/MCM-41,
- solvent free,
- catalyst preparation,
- dispersion,
- hydrogenation of naphthalene,
- citric acid
1. [1]
  Dillen A J V, Robert J A M, Lensveld D J. J. Catal. , 2003, 216(1/2): 257-264
2. [2]
  Ren S B, Zhang P, Shui H F, Lei Z P, Kang S G. Catal. Commun. , 2010, 12(2): 132-136 doi: 10.1016/j.catcom.2010.08.022
3. [3]
  Ren S B, Zhao R, Zhang P, Lei Z P, Wang Z C, Kang S G, Pan C X, Shui H F. React. Kinet. Mech. Catal. , 2014, 111(1): 247-257 doi: 10.1007/s11144-013-0629-3
4. [4]
  Ren S B, Shen Z, Zhang P, Lei Z P, Wang Z C, Kang S G, Pan C X, Shui H F. J. Fuel Chem. Technol. , 2014, 42(5): 591-596 doi: 10.1016/S1872-5813(14)60029-3
5. [5]
  Li X, Quek X Y, Ligthart D A J M, Guo M, Zhang Y, Li C, Yang Q, Hensen E J M. Appl Catal. B, 2012, 123-124: 424-432 doi: 10.1016/j.apcatb.2012.05.009
6. [6]
  Wang Y M, Wu Z Y, Shi L Y, Zhu J H. Adv. Mater. , 2005, 17(3): 323-327 doi: 10.1002/adma.200400860
7. [7]
  Wang Y M, Wu Z Y, Zhu J H. J. Solid State Chem. , 2004, 177(10): 3815-3823 doi: 10.1016/j.jssc.2004.07.013
8. [8]
  SUN J F, GE C Y, YAO X J, CAO Y, ZHANG L, TANG C J, DONG L. Acta Phys. -Chim. Sin. , 2013, 29(11): 505-532
9. [9]
  Yue W B, Zhou W Z. Chem. Mater. , 2007, 19(9): 2359-2363 doi: 10.1021/cm070124b
10. [10]
  Eggenhuisen T M, Steenbergen M J V, Talsma H, Jongh P E D, Jong K P D. J. Phys. Chem. C, 2009, 113(38): 16785-16791 doi: 10.1021/jp905410d
11. [11]
  Anedda R, Cannas C, Musinu A, Pinna G, Piccaluga G, Casu M. J. Nanopart. Res. , 2008, 10(1): 107-120 doi: 10.1007/s11051-007-9235-5
12. [12]
  Kim D W, Oh S G. Mater. Lett. , 2005, 59(8/9): 976-980
13. [13]
  Takahashi R, Sato S, Sodesawa T, Suzuki M, Ichikuni N. Microporous Mesoporous Mater. , 2003, 66(2/3): 197-208
14. [14]
  Takahashi R, Sato S, Sodesawa T, Kato M, Takenaka S, Yoshida S. J. Catal. , 2001, 204(2): 259-271 doi: 10.1006/jcat.2001.3400
15. [15]
  Chen F C, Zhao X S, Liu S L, Zhang J T, Xie S J, Xun L Y, Wang Q X. Ind. Catal. , 2006, 14(7): 14-17
16. [16]
  Valencia D, García-Cruz I, Klimova T. Stud. Surf. Sci. Catal. , 2010, 175: 529-532
17. [17]
  Marban G, Fuertes A B. Appl Catal. B, 2005, 57(1): 43-53 doi: 10.1016/j.apcatb.2004.10.011
18. [18]
  Sun M, Ma X X, Lv B, Dai X M, Yao Y, Liu Y Y, He M, Zhao X L. Fuel, 2015, 160: 16-23 doi: 10.1016/j.fuel.2015.07.029
19. [19]
  Lin S D, Vannice M A. J. Catal. , 1993, 143(2): 563-572 doi: 10.1006/jcat.1993.1299
20. [20]
  XUE Y B, LING K C, ZOU G M. Coal Conversion, 1999, 22(4): 1-4 doi: 10.3969/j.issn.1004-4248.1999.04.001
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