Citation: Lao-bang WANG, Ji-jiang WANG, Er-lin YUE, Long TANG, Xiao WANG, Xiang-yang HOU, Yu-qi ZHANG. Synthesis, Structure, Magnetic and Photocatalytic Properties of Nickel(Ⅱ) Coordination Polymer Based on 1-(3,5-Dicarboxybenzyl)-1H-pyrazole-3,5-dicarboxylic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(4): 744-750. doi: 10.11862/CJIC.2021.089 shu

Synthesis, Structure, Magnetic and Photocatalytic Properties of Nickel(Ⅱ) Coordination Polymer Based on 1-(3,5-Dicarboxybenzyl)-1H-pyrazole-3,5-dicarboxylic Acid Ligand

Yan′an City Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan′an University, Yan′an, Shannxi 716000, China

Corresponding author: Ji-jiang WANG, yadxwjj@126.com Er-lin YUE, yueerlin@yau.edu.com
Received Date: 17 September 2020
Revised Date: 30 January 2021

Figures(12)

A new coordination polymer {[Ni₂(L)(bib)_1.5(H₂O)₄]·3H₂O}_n (1)(H₄L=1-(3,5-dicarboxybenzyl)-1H-pyrazole-3,5-dicarboxylic acid, bib=1,4-bis(1-imidazolyl)benzene) was synthesized by hydrothermal method and characterized by single-crystal X-ray diffraction, elemental analyses and thermogravimetric analysis. Complex 1 features a 3D network structure. The variable temperature magnetic susceptibility measurements reveal that there are antiferromagnetic interactions between the Ni(Ⅱ) ions in complex 1. In addition, photocatalytic experiments indicated that complex 1 exhibited high photocatalytic activity up to 82.7% for the degradation of methylene blue pollutant.CCDC: 2030837.
- coordination polymer,
- Ni(Ⅱ),
- 1-(3,5-dicarboxybenzyl)-3,5-pyrazole dicarboxylic acid,
- magnetic property,
- photocatalytic properties
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