Citation: Jing ZHANG, Yu-feng WANG, Cheng-yan NIU, Jing-jing TAN, Xin-e DUAN, Xue-hong WEI. Lamellar-Smectic Polyoxometalate Liquid Crystal Encapsulated by Branched Bola-FormAmphiphiles[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(4): 758-766. doi: 10.11862/CJIC.2021.087 shu

Lamellar-Smectic Polyoxometalate Liquid Crystal Encapsulated by Branched Bola-FormAmphiphiles

Jing ZHANG ^1,, ,
Yu-feng WANG ^{1, 2} ,
Cheng-yan NIU ^{1, 2} ,
Jing-jing TAN ³ ,
Xin-e DUAN ² ,
Xue-hong WEI ^{1, 2,,}

1.
Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, China
2.
College of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, China
3.
Research Center for Fine Chemicals Engineering, Shanxi University, Taiyuan 030006, China

Corresponding author: Jing ZHANG, jingzhang@sxu.edu.cn Xue-hong WEI, xhwei@sxu.edu.cn
Received Date: 8 December 2020
Revised Date: 30 January 2021

Figures(6)

The quaternary ammonium amphiphile A6 with carboxylic acid group was employed to encapsulate the europium-containing inorganic polyoxometalate Na₉[EuW₁₀O₃₆] through ionic self-assembly strategy. The resultant surfactant-encapsulated polyoxometalate complex A6Eu was characterized by FT-IR spectra, thermogravimetric analysis and elemental analysis in detail. The dimerization of the carboxylic acid groups through intermolecular hydrogen bonding gives rise to a branched bola-form structure of the organic moieties, which leads to a lateral attachement of the peripheral mesogen to the inorganic cluster. The thermotropic liquid crystalline properties of polyoxometalate complex were characterized by differential scanning calorimetry, polarized optical microscopy, and temperature-dependent X-ray diffraction. A6Eu exhibited novel lamellar-smectic mesophase in which the mesogen is organized parallel to the layer planes, while the amphiphile A6 alone was found to form simple smectic structures.The lateral attachment of the mesogen was demonstrated to have an important influence on the thermotropic organized structures of the complex. The luminescence of polyoxometalate is well retained in the liquid crystalline mesophase.
- polyoxometalate,
- liquid crystal,
- luminescence,
- self-assembly,
- amphiphile
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