Citation: Yu-ting YANG, Zhang-zheng TU, Fan WANG, Yue ZHANG, Jian-ling WANG, Hong-ju YIN, Fei-xiang CHENG. Flexible Bis(imidazole)-Based Ligands Oriented Co(Ⅱ) -Glutarate Metal-Organic Frameworks: Syntheses, Structures and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(4): 735-743. doi: 10.11862/CJIC.2021.086 shu

Flexible Bis(imidazole)-Based Ligands Oriented Co(Ⅱ) -Glutarate Metal-Organic Frameworks: Syntheses, Structures and Properties

College of Chemistry and Environmental Science, Qujing Normal University, Qujing, Yunnan 655011, China

Corresponding author: Zhang-zheng TU, tuchangzheng@163.com Fei-xiang CHENG, chengfx2019@163.com
Received Date: 11 July 2020
Revised Date: 28 December 2020

Figures(12)

Two new Co(Ⅱ) -MOFs based on flexible ligands, namely {[Co(glu)(bimb)]·4H₂O}_n(1) and [Co(glu)(bix)_0.5]_n(2)(H₂glu=glutaric acid; bimb=1, 4-bis(imidazol-1-yl)-butane; bix=1, 4-bis(imidazol-1-yl-methylene)-benzene), have been hydrothermally synthesized and structurally characterized. Compound 1 displays non-interpenetrated(4, 4)-rhomboid grid layers. A 3D supramolecular framework is invoked through interlayer hydrogen bonding and π…π interactions. Upon dehydration the structure of 1 degraded irreversibly. Compound 2 exhibits a typical pillar-layered 3D framework with 4¹²6³ topology, in which the Co(Ⅱ) ion adopts a square pyramidal coordination geometry. Moreover, Compound 1 exhibited significant adsorption activity towards methyl orange in aqueous solution, and 2 showed weak antiferromagnetic behavior. CCDC: 2012753, 1; 2012754, 2.
- crystal structure,
- glutaric acid,
- bis(imidazole) ligands,
- adsorption,
- magnetism
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