Citation: Xiao-qiang LI, Xin CHEN, Hong-bo LI, Ting-ting ZHAO, Ya-mei ZHANG, Jun XIANG, Kai-yin ZHANG. Carbon-Coated CaSnO₃ Nanofibers as High Performance Anode Materials for Lithium Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(4): 700-708. doi: 10.11862/CJIC.2021.085 shu

Carbon-Coated CaSnO₃ Nanofibers as High Performance Anode Materials for Lithium Ion Batteries

1.
School of Science, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China
2.
Wuyi University, Wuyishan, Fujian 354399, China

Corresponding author: Jun XIANG, jxiang@just.edu.cn
Received Date: 1 December 2020
Revised Date: 30 January 2021

Figures(9)

Carbon coated CaSnO₃ nanofibers(denoted as CaSnO₃@C NFs) were prepared via the electrospinning technique combined with in-situ polymerization and carbonization processes. The phase compositions, surface morphology and microstructures of the samples were characterized by means of X-ray diffraction, scanning electron microscope, transmitting electron microscope and X-ray photoelectron spectroscopy. The influences of carbon coating and carbonization temperature on the electrochemical properties of CaSnO₃ NFs-based anode materials were investigated using cyclic voltammetry, galvanostatic charge/discharge and AC impedance spectroscopy. The test results show that the electrochemical performance of CaSnO₃ NFs was greatly improved after carbon coating, and meanwhile the specific capacity of CaSnO₃@C NFs composites first increased and then decreased with increasing carbonization temperature, in which the CaSnO₃@C NFs-600 composite obtained by carbonization at 600 ℃ exhibited an optimal electrochemical performance. The CaSnO₃@C NFs-600 electrode had a high initial discharge specific capacity of 1 102.2 mAh·g^-1 at a current density of 100 mA·g^-1, and delivered a reversible specific capacity of 548.8 mAh·g^-1 after 100 charge/discharge cycles. Moreover, it also showed a superior rate performance and retained a specific capacity of 333.5 mAh·g^-1 even at 2 A·g^-1.
- CaSnO₃ nanofibers,
- carbon coating,
- electrospinning,
- anode material,
- lithium storage performance
1. [1]
  Xue H, Fang Y X, Zeng L X, He X T, Luo F Q, Liu R P, Liu J B, Chen Q H, Wei M D, Qian Q R. J. Colloid Interface Sci. , 2019, 533: 627-635 doi: 10.1016/j.jcis.2018.08.110
2. [2]
  Xiang P, Chen X F, Zhang W T, Zhang W T, Li J F, Xiao B B, Li L S, Deng K S. Phys. Chem. Chem. Phys. , 2017, 19: 24945-24954 doi: 10.1039/C7CP04989G
3. [3]
  Liu M Q, Hou J L, Xiang J, Shen X Q, Luan K J, Zhang Y J. J. Nanosci. Nanotechnol. , 2018, 18: 7824-7829 doi: 10.1166/jnn.2018.15543
4. [4]
  Lu J T, Wan H, Ju T, Ying Z R, Zhang W W, Li B, Zhang Y Z. J. Alloys Compd. , 2019, 774: 593-600 doi: 10.1016/j.jallcom.2018.09.383
5. [5]
  Dubal D P, Chodankar N R, Kim D H, Pedro G R. Chem. Soc. Rev. , 2018, 47: 2065-2129 doi: 10.1039/C7CS00505A
6. [6]
  Hu X Y, Tang Y W, Xiao T, Jiang J, Jia Z Y, Li D W, Li B H, Luo L J. J. Phys. Chem. C, 2010, 114: 947-952 doi: 10.1021/jp909903k
7. [7]
  Cha, Y L, Kim S H. J. Nanosci. Nanotechnol, 2020, 20: 5498-5510 doi: 10.1166/jnn.2020.17623
8. [8]
  Fang G Q, Shingo K, Liu W W, Xia B B, Sun H D, Zhang R X, Zheng J W, Li D C. Appl. Surf. Sci. , 2013, 283: 963-967 doi: 10.1016/j.apsusc.2013.07.053
9. [9]
  Liu P, Hao Q L, Xia X F, Lei W, Xia H, Chen Z Y, Wang X. Electrochim. Acta, 2016, 214: 1-10 doi: 10.1016/j.electacta.2016.08.022
10. [10]
  Wang L L, Zhang W Q, Wang C H, Wang D K, Liu Z P, Hao Q Y, Wang Y, Tang K B, Qian Y T. J. Mater. Chem. A, 2014, 2: 4970-4974 doi: 10.1039/c3ta14563h
11. [11]
  Liu W, Gu K H, Han J W, Ou Z Y, Qin W Q. Miner. Eng. , 2019, 143: 105945 doi: 10.1016/j.mineng.2019.105945
12. [12]
  Zhao S, Bai Y, Zhang W F. Electrochim. Acta, 2010, 55: 3891-3896 doi: 10.1016/j.electacta.2010.02.018
13. [13]
  Yuan Z Y, Huang F, Sun J T, Zhou Y H. J. Mater. Sci. Lett. , 2003, 22: 143-144 doi: 10.1023/A:1021875124445
14. [14]
  Jung H R, Cho S J, Kim K N, Lee W J. Electrochim. Acta, 2011, 56: 6722-6731 doi: 10.1016/j.electacta.2011.05.068
15. [15]
  Ji L W, Lin Z, Guo B, Andrew J M, Zhang X W. Chem. Eur. J. , 2010, 16: 11543-11548 doi: 10.1002/chem.201001564
16. [16]
  Li L L, Peng S J, Cheah Y L, Wang J, Madhavi S. Nanoscale, 2013, 5: 134-138 doi: 10.1039/C2NR32766J
17. [17]
  Wang Z Y, Wang Z C, Liu W T, Xiao W, Lou X W. Energy Environ. Sci. , 2012, 6: 87-91
18. [18]
  Li L L, Peng S J, Wang J, Cheah Y L, The P, Ko Y, Wong C, Srinivasan M. ACS Appl. Mater. Interfaces, 2012, 4: 6005-6012 doi: 10.1021/am301664e
19. [19]
  Fan F Q, Fang G Q, Zhang R X, Xu Y H, Zheng J W, Li D C. Appl. Surf. Sci. , 2014, 311: 484-489 doi: 10.1016/j.apsusc.2014.05.094
20. [20]
  Zhou S H, Huang Y, Liu X D, Yan J, Feng X S. Ind. Eng. Chem. Res. , 2018, 57: 5507-5516 doi: 10.1021/acs.iecr.8b00997
21. [21]
  ZHANG X K, XIANG J, WU Z P, LIU M, SHEN X Q. J. Inorg. Mater. , 2017, 32(12): 1299-1307
22. [22]
  Wang B, Cheng J L, Wu Y P, Wang D, He D N. J. Mater. Chem. A, 2013, 1: 1368-1373 doi: 10.1039/C2TA00487A
23. [23]
  Liang C Y, Wang Z J. ACS Appl. Mater. Interfaces, 2017, 9: 40690-40696 doi: 10.1021/acsami.7b13063
24. [24]
  Zhao X J, Wang G, Zhou Y X, Wang H. Energy, 2017, 118: 172-180 doi: 10.1016/j.energy.2016.12.018
25. [25]
  Zhang Y J, Li J, Wang C R. Phys. Chem. Chem. Phys. , 2015, 17: 20061-20065 doi: 10.1039/C5CP03305E
26. [26]
  Cao Y, Zhang L, Tao D, Huo D X, Su K P. Electrochim. Acta, 2014, 132: 483-489 doi: 10.1016/j.electacta.2014.03.048
27. [27]
  Wang R, Xu C, Sun J, Gao L, Yao H L. ACS Appl. Mater. Interfaces, 2014, 6: 3427-3436 doi: 10.1021/am405557c
28. [28]
  Sharma Y, Sharma N, Subba R G V, Chowdari B. Chem. Mater. , 2008, 20: 6829-6839 doi: 10.1021/cm8020098
29. [29]
  Chen C J, Peng L F, Li Y J, Zhang L, Xiang J W, Hu P, Cheng S J, Huang Y H, Xie J. ACS Appl. Mater. Interfaces, 2017, 9: 5470-15476
30. [30]
  Rudola A, Sharma N, Balaya P. Electrochem. Commun. , 2015, 61: 10-13 doi: 10.1016/j.elecom.2015.09.016
31. [31]
  Wang L L, Xue L H, Wang J S, Miao L, Zhang W X. J. Alloys Compd. , 2018, 768: 938-943 doi: 10.1016/j.jallcom.2018.07.322
32. [32]
  Wang L, Yu Y, Chen P C, Zhang D W, Chen C H. J. Power Sources, 2008, 183: 717-723 doi: 10.1016/j.jpowsour.2008.05.079
33. [33]
  Xia J, Liu L, Jamil S, Xie J J, Yan H X, Yuan Y T, Zhang Y, Nie S, Pan J, Wang X Y, Cao G Z. Energy Storage Mater. , 2019, 17: 1-11 doi: 10.1016/j.ensm.2018.08.005
34. [34]
  Li L, Zhong Q F, Kim N D, Ruan G D, Yang Y, Gao C T, Fei H L, Li Y L, Ji Y S, Tour J. Carbon, 2016, 105: 260-267 doi: 10.1016/j.carbon.2016.04.031
35. [35]
  Zhang Q, Huang Y T, Chen X X, Pan A Q, Cai Z Y, Liu S N. J. Alloys Compd. , 2019, 805: 539-544 doi: 10.1016/j.jallcom.2019.07.034
36. [36]
  Dong T, Wang G, Yang P. Diamond Relat. Mater. , 2016, 73: 210-217
37. [37]
  Zheng J L, Huang X M, Pan X, Teng C, Wang N. Appl. Surf. Sci. , 2019, 473: 699-705 doi: 10.1016/j.apsusc.2018.12.225
38. [38]
  Tai Z G, Shi M, Chen Y Z, Shu C Y, Dai X. J. Alloys Compd. , 2019, 800: 1-7 doi: 10.1016/j.jallcom.2019.06.037
39. [39]
  Liu J H, Zhang S, Chen Y L, Zhang J T, Guo P, Liu M, Lu X Q, Zhang J, Wang Z J. Appl. Surf. Sci. , 2018, 458: 1018-1052 doi: 10.1016/j.apsusc.2018.07.156
1. [1]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223
2. [2]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
3. [3]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
4. [4]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-. doi: 10.3866/PKU.WHXB202310024
5. [5]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
6. [6]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
7. [7]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
8. [8]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
9. [9]
  Zeyu XU , Tongzhou LU , Haibo SHAO , Jianming WANG . Preparation and electrochemical lithium storage performance of porous silicon microsphere composite with metal modification and carbon coating. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1995-2008. doi: 10.11862/CJIC.20240164
10. [10]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
11. [11]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
12. [12]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
13. [13]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
14. [14]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
15. [15]
  Zhiyuan TONG , Ziyuan LI , Ke ZHANG . Three-dimensional porous collector based on Cu-Li_6.4La₃Zr_1.4Ta_0.6O₁₂ composite layer for the construction of stable lithium metal anode. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 499-508. doi: 10.11862/CJIC.20240238
16. [16]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
17. [17]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
18. [18]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
19. [19]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
20. [20]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Corrosion inhibition of nickel-cobalt-phosphide in water by coating TiO₂ layer. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 365-384. doi: 10.11862/CJIC.20240063

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(1603)
HTML views(429)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Carbon-Coated CaSnO3 Nanofibers as High Performance Anode Materials for Lithium Ion Batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

Carbon-Coated CaSnO₃ Nanofibers as High Performance Anode Materials for Lithium Ion Batteries