Citation: Su-qin ZHAO, Jin-zhong GU. Synthesis, Structure and Catalytic Properties of Mn(Ⅱ) Coordination Polymer through in Situ Ligand Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(4): 751-757. doi: 10.11862/CJIC.2021.080 shu

Synthesis, Structure and Catalytic Properties of Mn(Ⅱ) Coordination Polymer through in Situ Ligand Reaction

Su-qin ZHAO ^1,, ,
Jin-zhong GU ^2,,

1.
College of Physics and Electronic Information Engineering, Qinghai University for Nationalities, Xining 810007, China
2.
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: Su-qin ZHAO, qhzhsq@sina.com Jin-zhong GU, gujzh@lzu.edu.cn
Received Date: 16 November 2020
Revised Date: 21 December 2020

Figures(9)

One 2D coordination polymer, namely[Mn(μ₃-Hdpna)(2, 2'-bipy)]_n (1), has been constructed hydrothermally using Hdbna (Hdbna=5-(2, 3-dicyanobenzoxy)nicotic acid), 2, 2'-bipy (2, 2'-bipy=2, 2'-bipyridine), and manganese chloride at 160 ℃. Interestingly, the H₃dpna (H₃dpna=5-(2, 3-dicarboxylphenoxy)nicotic acid) ligand was generated by in situ hydrolysis of cyano groups in Hdbna. The product was isolated as stable crystalline solid and was characterized by IR spectrum, elemental analysis, thermogravimetric analysis (TGA), and single-crystal X-ray diffraction analysis. Single-crystal X-ray diffraction analysis reveals that compound 1 crystallizes in the triclinic system, space group P1. Compound 1 discloses a 2D sheet with an hcb topology. Compound 1 was applied as an efficient heterogeneous catalyst for the cyanosilylation.
- coordination polymer,
- ether-bridged tricarboxylic acid,
- catalytic properties,
- in situ reaction
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沈阳化工大学材料科学与工程学院沈阳 110142