Citation: Xue-lan MEI, Jian-ni GUO, Min-jie DU, Pei-pei YANG, Qian LI, Zong-qun LI, An-rong JU. Three Binuclear Lanthanide Complexes Constructed from Nitronyl Nitroxide Radical Ligands Containing Phenol Groups: Structure and Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(4): 592-600. doi: 10.11862/CJIC.2021.073 shu

Three Binuclear Lanthanide Complexes Constructed from Nitronyl Nitroxide Radical Ligands Containing Phenol Groups: Structure and Magnetic Properties

Xue-lan MEI ^1,, ,
Jian-ni GUO ² ,
Min-jie DU ³ ,
Pei-pei YANG ^4,, ,
Qian LI ¹ ,
Zong-qun LI ¹ ,
An-rong JU ¹

1.
College of Materials Science and Chemical Engineering, Bengbu University, Anhui 233030, China
2.
Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China
3.
Military Representative Bureau of Nanjing of the PLA Army, Bengbu, Anhui 233030, China
4.
College of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, China

Corresponding author: Xue-lan MEI, daluhuashu@qq.com Pei-pei YANG, 394117773@qq.com
Received Date: 15 August 2020
Revised Date: 30 December 2020

Figures(10)

The nitronyl nitroxide radicals NIT-5Br-2PhOH(2-(2′-hydroxy-5′-bromophenyl)-4, 4, 5, 5-tetramethylimidazoline-1-oxyl-3-oxide) and NIT-5NO₂-2 PhOH(2-(2′-hydroxy-5′-nitrophenyl)-4, 4, 5, 5-tetramethylimidazoline-1-oxyl-3-oxide) were selected as ligands to react with Ln(tfac)₃·2H₂O(tfac=trifluoroacetylacetonate) to produce three new lanthanide-radical complexes [Ln(tfac)₂(NIT-5Br-2PhO)]₂(Ln=Gd(1), Dy(2)) and [Dy(tfac)₂(NIT-5NO₂-2 PhO)]₂(3).Single crystal X-ray crystallographic analysis reveals that all three complexes possess binuclear structure in which two lanthanide ions are connected through the hydroxy groups of the radicals. DC magnetic susceptibilities of Gd complex reveal that the antiferromagnetic coupling between the Gd(Ⅲ) centers plays a major role for the magnetic behavior. CCDC: 1981623, 1; 1981622, 2; 2021836, 3.
- lanthanide complexes,
- nitronyl nitroxide radical,
- binuclear structure,
- magnetic behavior
1. [1]
  Poneti G, Bernot K, Bogani L, Caneschi A, Sessoli R, Wernsdorfer W, Gatteschi D. Chem. Commun. , 2007, 18: 1807-1809
2. [2]
  Gatteschi D, Sessoli R. Angew. Chem. Int. Ed. , 2003, 42: 268-297 doi: 10.1002/anie.200390099
3. [3]
  Sessoli R, Powell A K. Coord. Chem. Rev. , 2009, 253: 2328-2341 doi: 10.1016/j.ccr.2008.12.014
4. [4]
  Luzon J, Sessoli R. Dalton. Trans. , 2012, 41: 13556-13567 doi: 10.1039/c2dt31388j
5. [5]
  Chen Y C, Liu J L, Ungur L, Liu J, Li Q W, Wang L F, Ni Z P, Chibotaru L F, Chen X M, Tong M L. J. Am. Chem. Soc. , 2016, 138: 2829-2837 doi: 10.1021/jacs.5b13584
6. [6]
  Woodruff D N, Winpenny R E P, Layfield R A. Chem. Rev. , 2013, 113: 5110-5148 doi: 10.1021/cr400018q
7. [7]
  Habib F, Murugesu M. Chem. Soc. Rev. , 2013, 42: 3278-3288 doi: 10.1039/c2cs35361j
8. [8]
  HU P, WU Y N, HUANG Q X, LIAN S M, FU X H, HE G P, CHEN X M. Chinese J. Inorg. Chem. , 2016, 32(2): 297-304
9. [9]
  HU P, GAO Y Y, XIAO F Y, DENG X J, HUANG G H, ZHANG M, SU F, WANG L N. Chinese J. Inorg. Chem. , 2017, 33(1): 33-40
10. [10]
  Booth C H, Walter M D, Kazhdan D, Hu Y J, Lukens W W, Bauer E D, Maron L, Eisenstein O, Andersen R A. J. Am. Chem. Soc. , 2009, 131: 6480-6491 doi: 10.1021/ja809624w
11. [11]
  Caneschi A, Dei A, Gatteschi D, Sorace L, Vostrikova K. Angew. Chem. Int. Ed. , 2000, 39: 246-248 doi: 10.1002/(SICI)1521-3773(20000103)39:1<246::AID-ANIE246>3.0.CO;2-B
12. [12]
  Gurek A G, Basova T, Luneau D, Lebrun C, Kol'tsov E, Hassan A K, Ahsen V. Inorg. Chem. , 2006, 45(4): 1667-1676 doi: 10.1021/ic051754n
13. [13]
  Kanetomo T, Ishida T. Chem. Commun. , 2014, 50(19): 2529-2531 doi: 10.1039/c3cc48326f
14. [14]
  Trifonov A A, Gudilenkov I D, Larionova J, Luna C, Fukin G K, Cherkasov A V, Poddel'sky A I, Druzhkov N O. Organometallics, 2009, 28(23): 6707-6713 doi: 10.1021/om9004143
15. [15]
  Ganivet C R, Ballesteros B, de la Torre G, Clemente Juan J M, Coronado E, Torres T. Chem. Eur. J. , 2013, 19(4): 1457-1465 doi: 10.1002/chem.201202600
16. [16]
  Bernot K, Pointillart F, Rosa P, EtienneM, Sessoli R, Gatteschi D. Chem. Commun. , 2010, 46(35): 6458-6460 doi: 10.1039/c0cc00966k
17. [17]
  Tian L, Sun Y Q, Na B, Cheng P. Eur. J. Inorg. Chem. , 2013(24): 4329-4335
18. [18]
  Li X, Li T, Tian L, Liu Z Y, Wang X G. RSC Adv. , 2015, 5(91): 74864-74873 doi: 10.1039/C5RA13386F
19. [19]
  Li H D, Xie J, Xi L, Zhai L J, Niu Y L. Inorg. Chim. Acta, 2020, 499: 119188 doi: 10.1016/j.ica.2019.119188
20. [20]
  Demir S, Gonzalez M I, Darago L E, Evans W J, Long J R. Nat. Commun. , 2017, 8: 2144 doi: 10.1038/s41467-017-01553-w
21. [21]
  Liu R N, Liu L, Fang D, Xu J, Zhao S P, Xu W L. Z. Anorg. Allg. Chem. , 2015, 641(3/4): 728-731
22. [22]
  Reis S G, Briganti M, Soriano S, Guedes G P, Calancea S, Tiseanu C, Novak M A, del Aguila Sanchez M A, Totti F, Lopez Ortiz F, Andruh M, Vaz M G F. Inorg. Chem. , 2016, 55(22): 11676-11684 doi: 10.1021/acs.inorgchem.6b01616
23. [23]
  Demir S, Nippe M, Gonzalez M I, Long J R. Chem. Sci. , 2014, 5(12): 4701-4711 doi: 10.1039/C4SC02154A
24. [24]
  Demir S, Zadrozny J M, Nippe M, Long J R. J. Am. Chem. Soc. , 2012, 134(45): 18546-18549 doi: 10.1021/ja308945d
25. [25]
  Rinehart J D, Fang M, Evans W J, Long J R. Nat. Chem. , 2011, 3(7): 538-542 doi: 10.1038/nchem.1063
26. [26]
  Meihaus K R, Corbey J F, Fang M, Ziller J W, Long J R, Evans W J. Inorg. Chem. , 2014, 53(6): 3099-3107 doi: 10.1021/ic4030102
27. [27]
  Pointillart F, Le Gal Y, Golhen S, Cador O, Ouahab L. Chem. Commun. , 2009(25): 3777-3779 doi: 10.1039/b901932d
28. [28]
  Dei A, Gatteschi D, Massa C A, Pardi L A, Poussereau S, Sorace L. Chem. Eur. J. , 2000, 6: 4580-4586 doi: 10.1002/1521-3765(20001215)6:24<4580::AID-CHEM4580>3.0.CO;2-B
29. [29]
  Pointillart F, Le Guennic B, Golhen S, Cador O, Ouahab L. Chem. Commun. , 2013, 49: 11632-11634 doi: 10.1039/c3cc47087c
30. [30]
  Reis S G, Briganti M, Martins D O T A, Akpinar H, Calancea S, Guedes G P, Soriano S, Andruh M, Cassaro R A A, Lahti P M, Totti F, Vaz M G F. Dalton Trans. , 2016, 45(7): 2936-2944 doi: 10.1039/C5DT04469C
31. [31]
  Li H D, Sun Z, Sun J, Xi L, Guo J N, Sun G F, Xie J, Ma Y, Li L C. J. Mater. Chem. C, 2018, 6(8): 2060-2068 doi: 10.1039/C7TC05377K
32. [32]
  Chen P Y, Wu M Z, Li T, Shi X J, Tian L, Liu Z Y. Inorg. Chem. , 2018, 57(20): 12466-12470 doi: 10.1021/acs.inorgchem.8b01923
33. [33]
  Xi L, Sun J, Li H D, Han J, Huang X H, Li L C. Cryst. Growth Des. , 2020, 20(6): 3785-3794 doi: 10.1021/acs.cgd.0c00060
34. [34]
  Raebiger J W, Miller J S. Inorg. Chem. , 2002, 41(12): 3308-3312 doi: 10.1021/ic0201093
35. [35]
  Romanov V E, Bagryanskaya I Y, Gorbunov D E, Gritsan N P, Zaytseva E V, Luneau D, Tretyakov E V. Crystals, 2018, 8(9): 334 doi: 10.3390/cryst8090334
36. [36]
  Tian H X, Liu R N, Wang X L, Yang P P, Li Z X, Li L C, Liao D Z. Eur. J. Inorg. Chem. , 2009: 4498-4502
37. [37]
  Pointillart F, Bernot K, Poneti G, Sessoli R. Inorg. Chem. , 2012, 51(22): 12218-12229 doi: 10.1021/ic301394x
38. [38]
  Katagiri S, Tsukahara Y, Hasegawa Y, Wada Y. Bull. Chem. Soc. Jpn. , 2007, 80: 1492-1503 doi: 10.1246/bcsj.80.1492
39. [39]
  Das B, Venkateswarlu K, Majhi A, Siddaiah V, Reddy K R. J. Mol. Catal. A, 2007, 267: 30-33 doi: 10.1016/j.molcata.2006.11.002
40. [40]
  Ullman E F, Call L, Osiecki J H. J. Org. Chem. , 1970, 35: 3623 doi: 10.1021/jo00836a008
41. [41]
  Davis M S, Morokuma K, Kreilick R W. J. Am. Chem. Soc. , 1972, 94: 5588 doi: 10.1021/ja00771a010
42. [42]
  Sheldrick G M. SHELXLS-97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1997.
43. [43]
  Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
44. [44]
  Zhang J, Ma X F, Xuan X P. Chin. J. Struct. Chem. , 2020, 39(4): 698-708
45. [45]
  Mei X L, Wang X F, Wang J J, Ma Y, Liao D Z. New J. Chem. , 2013, 37: 3620-3626 doi: 10.1039/c3nj00739a
46. [46]
  Liu R N, Zhang C M, Li L C, Liao D Z, Sutter J P. Dalton Trans. , 2012, 41(39): 12139-12144 doi: 10.1039/c2dt31310c
47. [47]
  SHAPE Ver. 2.1, University of Barcelona and The Hebrew University of Jerusalem, Barcelona, 2005.
48. [48]
  Benelli C, Caneschi A, Gatteschi D, Guillou O, Pardi L. Inorg. Chem. , 1990, 29: 1750-1755 doi: 10.1021/ic00334a031
49. [49]
  Andruh M, Ramade I, Godjovi E, Guillou O, Kahn O, Trombe J C. J. Am. Chem. Soc. , 1993, 115: 1822-1829 doi: 10.1021/ja00058a029
50. [50]
  Datcu A, Roques N, Jubera V, Maspoch D, Fontrodona X, Wurst K, Imaz I, Mouchaham G, Sutter J P, Rovira C, Veciana J. Chem. Eur. J. , 2012, 18(1): 152-162 doi: 10.1002/chem.201102278
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