Citation: Yi-Jie ZHANG, Le-Ran LIU, Yun WU, Fei ZHAO, Guang LIU, Jin-Ping LI. Two-Step Electrodeposition Construction of NiFe/Ni₃S₂/NF Hierarchical Heterogeneous Electrode for Enhanced Oxygen Evolution Reaction at Large Current Densities[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(3): 499-508. doi: 10.11862/CJIC.2021.057 shu

Two-Step Electrodeposition Construction of NiFe/Ni₃S₂/NF Hierarchical Heterogeneous Electrode for Enhanced Oxygen Evolution Reaction at Large Current Densities

College of Chemistry and Chemical Engineering, Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: Guang LIU, liuguang@tyut.edu.cn Jin-Ping LI, jpli211@hotmail.com
Received Date: 5 October 2020
Revised Date: 5 January 2021

Figures(6)

A simple two step electrodeposition method was applied to effectively integrate the amorphous Ni₃S₂ material and the defect-rich NiFe bimetallic oxyhydroxide on the surface of the nickel foam, thereby constructing a NiFe/Ni₃S₂/NF three-dimensional hierarchical heterogeneous electrode. Benefiting from the structural and catalytic advantages of amorphous Ni₃S₂ and defect-rich NiFe materials, as well as the strong electronic interaction at the heterogeneous interface, the NiFe/Ni₃S₂/NF catalytic electrode exhibited excellent oxygen evolution performance: only an overpotential of 273 mV was needed to attain a current density of 100 mA·cm^-2, which is far superior to most of the reported Ni/Fe-based composite materials. It can stably output a high current density of 1 000 mA·cm^-2 at the overpotential of 372 mV for more than 27 h in 1 mol·L^-1 KOH solution.
- water splitting,
- large current density,
- oxygen evolution reaction,
- hierarchical heterogeneous electrode,
- iron-group metals
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Two-Step Electrodeposition Construction of NiFe/Ni3S2/NF Hierarchical Heterogeneous Electrode for Enhanced Oxygen Evolution Reaction at Large Current Densities

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通讯作者: 陈斌, bchen63@163.com

Two-Step Electrodeposition Construction of NiFe/Ni₃S₂/NF Hierarchical Heterogeneous Electrode for Enhanced Oxygen Evolution Reaction at Large Current Densities