Citation: Man LI, Ju-Feng GENG, Hao-Yu WANG, Chen-Yue YANG, Shang-Ke PAN, Jian-Guo PAN. Growth and Luminescence Properties of Eu²⁺ Doped KCaCl₃ Crystal[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(3): 443-447. doi: 10.11862/CJIC.2021.049 shu

Growth and Luminescence Properties of Eu²⁺ Doped KCaCl₃ Crystal

Key Laboratory of Photoelectric Detection Materials and Devices of Zhejiang Province, School of Materials Science & Chemical Engineering, Ningbo University, Ningbo, Zhejiang 315211, China

Corresponding author: Jian-Guo PAN, panjianguo@nbu.edu.cn
Received Date: 8 August 2020
Revised Date: 20 November 2020

Figures(8)

Single crystals of KCa_1-xEu_xCl₃ (x=0.005, 0.01, 0.02, 0.03, 0.05) doped with different Eu²⁺ ion molar fractions have been grown successfully by Bridgman-Stockbarger technique. The crystals were characterized by powder X-ray diffraction, thermogravimetry, transmittance, photoluminescence spectrum, decay time and X-ray excitation emission spectrum. Through phase diagram and structure analysis, the crystal is regarded as a congruent compound and belongs to orthorhombic system. The unit cell parameters are determined as: a=0.756 04 nm, b=1.048 23 nm, c=0.726 57 nm, space group: Pnma(62). Under the excitation of ultraviolet light, the crystal exhibited a broad emission around 434 nm, which can be attributed to the 4f⁶5d¹→4f⁷ transition of Eu²⁺. The result exhibited that the emission spectra with the maximum which position was shifted from 427 to 436 nm with the increase of Eu²⁺ doped concentration. The photolumimnescence decay time was 1.473 μs, moreover, the intensity of X-ray luminescence spectra continued to increase with the Eu²⁺ ion concentration.
- KCaCl₃: Eu,
- Bridgman technique,
- photoluminescence,
- X-ray luminescence
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Growth and Luminescence Properties of Eu²⁺ Doped KCaCl₃ Crystal