Citation: Qing LIU, Jun-Ming GUO, Xiao-Fang LIU, Hong-Li BAI, Ming-Wu XIANG, Wei BAI, Kai-Jiao DUAN. Preparation and Long Cycle Electrochemical Properties of B-Doped Spinel LiMn₂O₄ Cathode Material[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(2): 276-284. doi: 10.11862/CJIC.2021.046 shu

Preparation and Long Cycle Electrochemical Properties of B-Doped Spinel LiMn₂O₄ Cathode Material

Qing LIU ^{1, 2} ,
Jun-Ming GUO ^{1, 2,,} ,
Xiao-Fang LIU ^{1, 2} ,
Hong-Li BAI ^{1, 2} ,
Ming-Wu XIANG ^{1, 2} ,
Wei BAI ^{1, 2} ,
Kai-Jiao DUAN ^{1, 2}

1.
National and Local Joint Engineering Research Center for Green Preparation Technology of Biobased Materials, Yunnan Minzu University, Kunming 650500, China
2.
Key Laboratory of Green-Chemical Materials in University of Yunnan Province, Yunnan Minzu University, Kunming 650500, China

Corresponding author: Jun-Ming GUO, guojunming@tsinghua.org.cn
Received Date: 26 August 2020
Revised Date: 8 December 2020

Figures(7)

A single crystal polyhedron LiMn_1.94B_0.06O₄ cathode material was prepared by a solid-state combustion synthesis, their structural and electrochemical properties were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and charge-discharge test. The results show that Bdoping did not change the crystal structure of spinel LiMn₂O₄, and it could promote the preferential growth of (440) and (400) crystal facets. Inducing the formation of the single crystal polyhedron LiMn_1.94B_0.06O₄ material with the highly exposed (111) facets and a small part of (110) and (100) facets, as well as a particle size of 160~350 nm, which enabled minimal Mn dissolution and provided more lithium ions channels. The LiMn_1.94B_0.06O₄ delivered the initial discharge capacity of 103 mAh·g^-1 with a good capacity retention rate of 57.7% after 2 000 cycles at 10C and 25℃. At high current rate of 15C, it showed the initial discharge capacity of 67.1 mAh·g^-1, and the capacity retention rates of 46.2% was obtained after 1 500 cycles. Moreover, at 1C and high temperature of 55℃, the initial discharge capacity of 125.2 mAh·g^-1 was also maintained, showing good high temperature performance. The B-doping can effectively improve the high rate performance and cycle life of spinel LiMn₂O₄, stabilize the crystal structure, inhibit the Jahn-Teller effect and relieve the Mn dissolution.
- spinel LiMn₂O₄,
- single crystal polyhedron,
- B-doping,
- Jahn-Teller effect,
- Mn dissolution,
- electrochemistry,
- kinetics,
- cathode material
1. [1]
  Li J W, Liu Y, Yao W L, Rao X F, Zhong S W, Qian L W. Solid State Ionics, 2020, 349:115292 doi: 10.1016/j.ssi.2020.115292
2. [2]
  Liu Y, Yao W L, Lei C, Zhang Q, Zhong S W, Yan Z Q. J. Electrochem. Soc., 2019, 166(8):A1300-A1309 doi: 10.1149/2.0151908jes
3. [3]
  BAN L Q, BAI X T, ZHUANG W D, Li W J, HUANG W, LU S G. Chinese J. Inorg. Chem., 2020, 36(1):79-86
4. [4]
  Qiu X Y, Zhuang Q C, Zhang Q Q, Cao R, Ying P Z, Qiang Y H, Sun S G. Phys. Chem. Chem. Phys., 2012, 14:2617-2630 doi: 10.1039/c2cp23626e
5. [5]
  Noh H J, Youn S J, Yoon C S, Sun Y K. J. Power Sources, 2013, 233:121-130 doi: 10.1016/j.jpowsour.2013.01.063
6. [6]
  Byeon P, Bae H B, Chung H S, Lee S G, Chung S Y. Adv. Funct. Mater., 2018, 28:1-10 doi: 10.1002/adfm.201870320
7. [7]
  Guo D L, Wei X G, Chang Z R, Tang H W, Li B, Shangguan E B, Chang K, Yuan X Z, Wang H J. J. Alloys Compd., 2015, 632:222-228 doi: 10.1016/j.jallcom.2015.01.182
8. [8]
  Fergus J W. J. Power Sources, 2010, 195(4):939-954 doi: 10.1016/j.jpowsour.2009.08.089
9. [9]
  Han C G, Zhu C Y, Saito G, Akiyama T. Electrochim. Acta, 2016, 209:225-234 doi: 10.1016/j.electacta.2016.05.075
10. [10]
  Lin B H, Yin Q, Hu H R, Lu F J, Xia H. J. Solid State Chem., 2014, 209:23-28 doi: 10.1016/j.jssc.2013.10.016
11. [11]
  Xu G J, Liu Z H, Zhang C J, Cui G L, Chen L Q. J. Mater. Chem. A, 2015, 3(8):4092-4123 doi: 10.1039/c4ta06264g
12. [12]
  Li W, Deng H J, Jiang J B. Sci. Adv. Mater., 2018, 10:1823-1829 doi: 10.1166/sam.2018.3425
13. [13]
  Tan X H, Liu H Q, Jiang Y, Liu G Y, Guo Y J, Wang H F, Sun L F, Chu W G. J. Power Sources, 2016, 328:345-354 doi: 10.1016/j.jpowsour.2016.08.038
14. [14]
  Fang D L, Li J C, Liu X, Huang P F, Xu T R, Qian M C, Zheng C H. J. Alloys Compd., 2015, 640:82-89 doi: 10.1016/j.jallcom.2015.03.243
15. [15]
  Feng X Y, Zhang J X, Yin L W. Mater. Res. Bull., 2016, 74:421-424
16. [16]
  Kebede M A, Kunjuzwa N, Jafta C J, Mathe M K, Ozoemena K I. Electrochim. Acta, 2014, 128:172-177 doi: 10.1016/j.electacta.2013.11.080
17. [17]
  Huang J J, Yang F L, Guo Y J, Peng C C, Bai H L, Peng J H, Guo J M. Ceram. Int., 2015, 41:9662-9667
18. [18]
  Feng Y, Li Y L, Hou F. J. Power Sources, 2009, 187:224-228
19. [19]
  Zheng C H, Wu Z F, Li J C, Liu X, Fang D L. Ceram. Int., 2014, 40:8455-8463
20. [20]
  Li X L, Zhou Q, Wang H L, Liu S. Ionics, 2014, 21:1517-1523 doi: 10.1007/s11581-014-1352-4
21. [21]
  Ebin B, Lindbergh G, Gürmen S. J. Alloys Compd., 2015, 620:399-406 doi: 10.1016/j.ceramint.2013.06.099
22. [22]
  Kim J, Kim K, Cho W, Shin W H, Kanno R, Choi J W. Nano Lett., 2012, 12:6358-6365 doi: 10.1021/nl303619s
23. [23]
  Duan Y Z, Guo J M, Xiang M W, Zhu J Y, Su C W, Bai H L, Liu X F, Bai W, Wang R. Solid State Ionics, 2018, 40:100-109
24. [24]
  Zhu J Y, Liu Q, Xiang M W, Guo J M, Bai H L, Liu X F, Su C W, Bai W. Ceram. Int., 2020, 46:14516-14522
25. [25]
  Yu Y, Xiang M W, Guo J M, Su C W, Liu X F, Bai H L, Bai W, Duan K J. J. Colloid Interface Sci., 2019, 555:64-71
26. [26]
  Pan L C, Xia Y G, Qiu B, Zhao H, Guo H C, Jia K, Gu Q W, Liu Z P. J. Power Sources, 2016, 327:273-280 doi: 10.1016/j.jpowsour.2016.07.064
27. [27]
  Yang C X, Deng Y F, Gao M, Yang X F, Qin X S, Chen G H. Electrochim. Acta, 2017, 225:198-206
28. [28]
  Liu J T, Li G, Bai H L, Shao M M, Su C W, Guo J M, Liu X F, Bai W. Solid State Ionics, 2017, 307(11):79-89
29. [29]
  Wang Y Z, Shao X, Xu H Y, Xie M, Deng S X, Wang H, Liu J B, Yan H. J. Power Sources, 2013, 226(6):140-148
30. [30]
  Yao W L, Liu Y, Li D, Zhang Q, Zhong S W, Cheng H W, Yan Z Q. J. Phys. Chem. C, 2020, 124(4):2346-2356
31. [31]
  Wang J L, Li Z H, Yang J, Tang J J, Yu J J, Nie W B, Lei G T, Xiao Q Z. Electrochim. Acta, 2012, 75(4):115-122 doi: 10.1016/j.electacta.2012.04.136
32. [32]
  Tang S B, Lai M O, Lu L. Mater Chem Phys., 2008, 111(1):149-153 doi: 10.1016/j.matchemphys.2008.03.041
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Preparation and Long Cycle Electrochemical Properties of B-Doped Spinel LiMn₂O₄ Cathode Material