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Citation: Hong-Ren RONG, Xian-Mei WANG, Yan-Wei MA, Ge-Xiang GAO, Hao-Qi SU, Li-Fang LAI, Qi LIU. Three-Dimensional Cobalt-Based MOF[KCo7(OH)3(ip)6(H2O)4]·12H2O as High-Capacity Electrode Materials for Supercapacitors[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(2): 206-212. doi: 10.11862/CJIC.2021.042 shu

Three-Dimensional Cobalt-Based MOF[KCo7(OH)3(ip)6(H2O)4]·12H2O as High-Capacity Electrode Materials for Supercapacitors

  • School of Petrochemical Engineering, Jiangsu Province Key Laboratory of Fine Petrochemical Engineering, Changzhou University, Changzhou, Jiangsu 213164, China

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  • In order to develop supercapacitors with higher energy density, a three-dimensional cobalt-based metalorganic framework (MOF) compound ([KCo7(OH)3(ip)6(H2O)4]·12H2O, Co ip; ip=isophthalate) was synthesized by simple solvothermal reaction. Its electrochemical performances as a supercapacitor electrode material were investigated. The Co-ip electrode exhibited high specific capacitance, good cycle stability, and superior rate performance. In 1 mol·L-1 KOH solution, the maximum specific capacitance was 1 660 F·g-1 at a current density of 1 A·g-1. At a current density of 2 A·g-1, the retention of specific capacitance was 82.7% after 3 000 cycles. The superior supercapacitive performance is attributed to the three-dimensional porous structure of Co-ip and nano-sized particles.
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