Citation: Yan-Ping DONG, Guang-Ming LI. Syntheses, Structures and Magnetic Properties of β-diketone Dy(Ⅲ) Complexes Tuned by Bond Length and Electronic Effect[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(2): 213-220. doi: 10.11862/CJIC.2021.041 shu

Syntheses, Structures and Magnetic Properties of β-diketone Dy(Ⅲ) Complexes Tuned by Bond Length and Electronic Effect

Yan-Ping DONG ^{1, 2} ,
Guang-Ming LI ^1,,

1.
Key Laboratory of Functional Inorganic Material Chemistry(MOE), Heilongjiang University, Harbin 150080, China
2.
Department of Food and Pharmaceutical Engineering, Suihua University, Suihua, Heilongjiang 152061, China

Corresponding author: Guang-Ming LI, gmli_2000@163.com
Received Date: 20 June 2020
Revised Date: 1 November 2020

Figures(11)

A series of 1-(1-ethyl-1H-indol-3-yl)-4, 4, 4-trifluorobutane-1, 3-dione (EIFD) dysprosium complexes, namely[Dy(EIFD)₃(EM)]·CH₂Cl₂ (1), [Dy(EIFD)₃(EDM)]·CH₂Cl₂ (2) and[Dy(EIFD)₃(TEG)] (3) (EM=CH₃OCH₂CH₂OH, EDM=CH₃OCH₂CH₂OCH₃, TEG=HOCH₂CH₂OCH₂CH₂OCH₂CH₂OH), have been isolated by reactions of EIFD, DyCl₃·6H₂O and corresponding oxygen-containing auxiliary ligands, respectively. X-ray crystallographic analysis reveals that complexes 1~3 are all eight coordinated mononuclear structures. The coordination geometry for Dy(Ⅲ) ion in complexes 1 and 3 are suggested closer to the biaugmented trigonal prismatic (8-BTP, C_2v), in contrast, it is closer to the triangular dodecahedron (8-TDH, D_2d) for complex 2. Magnetic studies indicate that all complexes 1~3 exhibit slowed magnetic relaxation with anisotropy energy barriers of 95.1 K for 1, 40.5 K for 2 as well as 53.8 and 13.4 K for 3, respectively. Complexes 1 and 3 showed butterfly-loop. In view of the β-diketone ligand of EIFD, Dy (Ⅲ) complexes with oxygen containing auxiliary ligands displayed higher energy barriers than those of complexes with nitrogen containing auxiliary ligands. The Dy-O bond length and electronic effect of oxygen containing auxiliary ligands in the complexes have been investigated in terms of their anisotropy energy barriers. CCDC: 1893554, 1; 1893555, 2; 1893556, 3.
- β-diketone,
- Dy(Ⅲ) complex,
- oxygen-containing auxiliary ligand,
- electronic effect,
- bond length
1. [1]
  Caneschi A, Gatteschi D, Sessoli R, Barra A L, Brunel L C, Guillot M. J. Am. Chem. Soc., 1991, 113(15):5873-5874 doi: 10.1021/ja00015a057
2. [2]
  Sessoli R, Powell A K. Coord. Chem. Rev., 2009, 253(19/20):2328-2341
3. [3]
  Woodruff D N, Winpenny R E, Layfield R A. Chem. Rev., 2013, 113(7):5110-5148 doi: 10.1021/cr400018q
4. [4]
  Ungur L, Lin S Y, Tang J K, Chibotaru L F. Chem. Soc. Rev., 2014, 43(20):6894-6905 doi: 10.1039/C4CS00095A
5. [5]
  ZOU X Y, MA H Y, PANG H J, ZHANG F M, LI G M. Chinese J. Inorg. Chem., 2016, 32(9):1647-1652
6. [6]
  Zou X Y, Du C Y, Dong Y P, Li G M. Inorg. Chim. Acta, 2020, 507:119455-119461 doi: 10.1016/j.ica.2020.119455
7. [7]
  Tian X Q, Dong Y P. ChemistrySelect, 2019, 4(43):12608-12611 doi: 10.1002/slct.201903131
8. [8]
  Habib F, Murugesu M. Chem. Soc. Rev., 2013, 42(8):3278-3288 doi: 10.1039/c2cs35361j
9. [9]
  HAO W H, ZOU X Y, FEI B W, YAN P F, DONG Y P, LI G M. Chinese J. Inorg. Chem., 2016, 32(11):2063-2068
10. [10]
  Zhang J W, Ren Y N, Li J X, Liu B Q, Dong Y P. Eur. J. Inorg. Chem., 2018, 2018(9):1099-1106 doi: 10.1002/ejic.201701394
11. [11]
  Jia J H, Li Q W, Chen Y C, Liu J L, Tong M L. Coord. Chem. Rev., 2019, 378:365-381 doi: 10.1016/j.ccr.2017.11.012
12. [12]
  Hewitt I J, Tang J K, Madhu N T, Anson C E, Lan Y H, Luzon J, Etienne M, Sessoli R, Powell A K. Angew. Chem. Int. Ed., 2010, 49(36):6352-6356 doi: 10.1002/anie.201002691
13. [13]
  Ishikawa N, Sugita M, Wernsdorfer W. J. Am. Chem. Soc., 2005, 127(11):3650-3651 doi: 10.1021/ja0428661
14. [14]
  Hussain B, Savard D, Burchell T J. Chem. Commun., 2009, 9(9):1100-1102
15. [15]
  Thielemann D T, Klinger M, Wolf T J A, Lan Y, Wernsdorfer W, Busse M, Roesky P W, Unterreiner A N, Powell A K, Junk P C, Deacon G B. Inorg. Chem., 2011, 50(23):11990-12000 doi: 10.1021/ic201157m
16. [16]
  Gregson M, Chilton N F, Ariciu A M, Tuna F, Crowe I F, Lewis W, Blake A J, Collison D, McInnes E J L, Winpenny R E P, Liddle S T. Chem. Sci., 2016, 7(1):155-165 doi: 10.1039/C5SC03111G
17. [17]
  Zou X Y, Dong Y P, Zhang F M, Li G M. Inorg. Chim. Acta, 2018, 473:37-43 doi: 10.1016/j.ica.2017.12.021
18. [18]
  Dong Y P, Yan P F, Zou X Y, Li G M. Inorg. Chem. Front., 2015, 2(9):827-836 doi: 10.1039/C5QI00079C
19. [19]
  Kang Q, Baldov J J, Jiang S D, Gaita-Arino A, Zhang Y Q, Overgaard J, Wang B W, Coronado E, Gao S. Chem. Sci., 2015, 6(8):4587-4593 doi: 10.1039/C5SC01245G
20. [20]
  Dong Y P, Li W Z, Zou X Y, Hou G F, Li G M. Inorg. Chim. Acta, 2017, 466:599-603 doi: 10.1016/j.ica.2017.06.019
21. [21]
  Dong Y P, Yan P F, Zou X Y, Liu T Q, Li G M. J. Mater. Chem. C, 2015, 3(17):4407-4415
22. [22]
  Sheldrick G M. Acta Crystallogr. Sect. C, 2015, C71:3-8
23. [23]
  Llunell M, Casanova D, Cirera J, Alemany P, Alvarez S. SHAPE, Ver. 2.1, University of Barcelona and the Hebrew University of Jerusalem, Spain, 2013.
24. [24]
  Kahn M L, Sutter J P, Golhen S, Guionneau P, Ouahab L, Kahn O, Chasseau D. J. Am. Chem. Soc., 2000, 122(14):3413-3421 doi: 10.1021/ja994175o
25. [25]
  Kahn M L, Ballou R, Porcher P, Kahn O, Sutter J P. Chem. Eur. J., 2002, 8(2):525-531 doi: 10.1002/1521-3765(20020118)8:2<525::AID-CHEM525>3.0.CO;2-L
26. [26]
  Nicholas F C, Stuart K L, Boujemaa M, Alessandro S, Stuart R B, Keith S M. Chem. Sci., 2013, 4(4):1719-1730 doi: 10.1039/c3sc22300k
27. [27]
  Abbas G, Lan Y, Kostakis G E, Wernsdorfer W, Anson C E, Powell A K. Inorg. Chem., 2010, 49(17):8067-8072 doi: 10.1021/ic1011605
28. [28]
  Car P E, Perfetti M, Mannini M, Favre A, Caneschi A, Sessoli R. Chem. Commun., 2011, 47(13):3751-3753 doi: 10.1039/c0cc05850e
29. [29]
  Jeletic M, Lin P H, Le Roy J J, Korobkov I, Gorelsky S I, Murugesu M. J. Am. Chem. Soc., 2011, 133(48):19286-19289 doi: 10.1021/ja207891y
30. [30]
  Ruiz J, Mota A J, Rodriguez-Dieguez A, Titos S, Herrera J M, Ruiz E, Cremades E, Costesc J P, Colacio E. Chem. Commun., 2012, 48(64):7916-7918 doi: 10.1039/c2cc32518g
31. [31]
  Liu S S, Lang K, Zhang Y Q, Yang Q, Wang B W, Gao S. Dalton Trans., 2016, 45(19):8149-8153
32. [32]
  Habib F, Brunet G, Vieru V, Korobkov I, Chibotaru L F, Murugesu M. J. Am. Chem. Soc., 2013, 135(36):13242-13245
33. [33]
  Chen G J, Guo Y N, Tian J L, Tang J K, Gu W, Liu X, Yan S P, Cheng P, Liao D Z. Chem. Eur. J., 2012, 18(9):2484-2487
34. [34]
  Chen G J, Zhou Y, Jin G X, Dong Y B. Dalton Trans., 2014, 43(44):16659-16665
35. [35]
  Chen G J, Gao C Y, Tian J L, Tang J K, Gu W, Liu X, Yan S P, Liao D Z, Cheng P. Dalton Trans., 2011, 40(20):5579-5583
36. [36]
  Zhu J, Wang C Z, Luan F, Liu T Q, Yan P F, Li G M. Inorg. Chem., 2014, 53(17):8895-8901
37. [37]
  Wang Y L, Ma Y, Yang X, Tang J K, Cheng P, Wang Q L, Li L C, Liao D Z. Inorg. Chem., 2013, 52(13):7380-7386
38. [38]
  Dong Y P, Yan P F, Zou X Y, Yao X, Hou G F, Li G M. Dalton Trans., 2016, 45(22):9148-9157
39. [39]
  Sun W B, Yan P F, Jiang S D, Wang B W, Zhang Y Q, Li H F, Chen P, Wang Z M, Gao S. Chem. Sci., 2016, 7(1):684-691
1. [1]
  Yaqin Zheng , Lian Zhuo , Meng Li , Chunying Rong . Enhancing Understanding of the Electronic Effect of Substituents on Benzene Rings Using Quantum Chemistry Calculations. University Chemistry, 2025, 40(3): 193-198. doi: 10.12461/PKU.DXHX202406119
2. [2]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
3. [3]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
4. [4]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
5. [5]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
6. [6]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
7. [7]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
8. [8]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
9. [9]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
10. [10]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
11. [11]
  Renqing Lü , Shutao Wang , Fang Wang , Guoping Shen . Computational Chemistry Aided Organic Chemistry Teaching: A Case of Comparison of Basicity and Stability of Diazine Isomers. University Chemistry, 2025, 40(3): 76-82. doi: 10.12461/PKU.DXHX202404119
12. [12]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
13. [13]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
14. [14]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
15. [15]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
16. [16]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
17. [17]
  Wei Li , Ze Chang , Meihui Yu , Ying Zhang . Curriculum Ideological and Political Design of Piezoelectricity Measurement Experiments of Coordination Compounds. University Chemistry, 2024, 39(2): 77-82. doi: 10.3866/PKU.DXHX202308004
18. [18]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
19. [19]
  Cunling Ye , Xitong Zhao , Hongfang Wang , Zhike Wang . A Formula for the Calculation of Complex Concentrations Arising from Side Reactions and Its Applications. University Chemistry, 2024, 39(4): 382-386. doi: 10.3866/PKU.DXHX202310043
20. [20]
  Keweiyang Zhang , Zihan Fan , Liyuan Xiao , Haitao Long , Jing Jing . Unveiling Crystal Field Theory: Preparation, Characterization, and Performance Assessment of Nickel Macrocyclic Complexes. University Chemistry, 2024, 39(5): 163-171. doi: 10.3866/PKU.DXHX202310084

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(1248)
HTML views(133)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142