Citation: Xiang-Dong JI, Cai-Yun LIU, Shu-Fang ZHANG, Wen-Xia WANG, Guo-Ren YUE, Cheng CAO. High Selectivity of p-Tetradecyloxy Imine Derivative for "Double Response" Recognition of CN^-[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(2): 221-228. doi: 10.11862/CJIC.2021.036 shu

High Selectivity of p-Tetradecyloxy Imine Derivative for "Double Response" Recognition of CN^-

Xiang-Dong JI ¹ ,
Cai-Yun LIU ¹ ,
Shu-Fang ZHANG ¹ ,
Wen-Xia WANG ¹ ,
Guo-Ren YUE ^{1, 2} ,
Cheng CAO ^{1, 2,,}

1.
Key Laboratory of Hexi Corridor Resources Utilization of Gansu, College of Chemistry and Chemical Engineering, Hexi University, Zhangye, Gansu 734000, China
2.
Gansu Province Kaiyuan Bio-Tech Development Center, Hexi University, Zhangye, Gansu 734000, China

Corresponding author: Cheng CAO, caochxu@126.com
Received Date: 12 May 2020
Revised Date: 29 October 2020

Figures(16)

A new long-chain alkoxy imine derivative R was designed and synthesized. The recognition property of the receptor R for 10 kinds of anions was studied by UV-Vis analysis and naked-eye detection. The results showed that the receptor R had significant recognition ability for F^-, Ac^- and CN^- through UV-Vis analysis, which found single colorimetric recognition of CN^- by naked-eye recognition in H₂O/DMSO (1:1, V/V) solution. The LOD (limit of lowest detection) of receptor R for CN^- was 7.02 μmol·L^-1, and naked recognition paper of receptor R was prepared. The Job's plot indicated that the formation of complex between receptor R and CN^- was in 1:2 stoichiometric ratio. The recognition mechanism of receptor R was illustrated through UV titration, NMR titration, MS and theoretical calculation. The "reaction" and "hydrogen-bond" double response recognition phenomena and deprotonation were found in the CN^- and F^- titrations, respectively.
- imine base receptor,
- ion detection,
- chemosensor for CN^-,
- naked-eye detection
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

High Selectivity of p-Tetradecyloxy Imine Derivative for "Double Response" Recognition of CN-

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通讯作者: 陈斌, bchen63@163.com

High Selectivity of p-Tetradecyloxy Imine Derivative for "Double Response" Recognition of CN^-