Citation: Xiao-Min HU, Hui CHEN, Xuan-Yi JIA, Qiao WANG, Li-Hong HUANG. Y-Mn-O Supported Ni-Based Catalyst for Hydrogen Production via Auto-thermal Reforming of Acetic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(3): 555-560. doi: 10.11862/CJIC.2021.032 shu

Y-Mn-O Supported Ni-Based Catalyst for Hydrogen Production via Auto-thermal Reforming of Acetic Acid

College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610059, China

Corresponding author: Li-Hong HUANG, huanglihong06@cdut.cn
Received Date: 16 September 2020
Revised Date: 4 December 2020

Figures(7)

To effectively achieve high hydrogen yield from biomass-derived acetic acid (HAc), a series of NiMnY catalysts were prepared by hydrothermal method and tested in auto-thermal reforming (ATR) of HAc. X-ray diffraction (XRD), N₂ adsorption-desorption test and H₂-temperature-programmed reduction (H₂-TPR) were carried out to explore the internal relationship within these NiMnY catalysts. Over the Ni_0.39Mn_0.61YO_3.11±δ catalyst, perovskite-like (Ni, Mn)YO₃ phase was formed after calcination, and converted into thermostable Ni-Mn-Y-O species after reduction in H 2, along with the highly dispersed nickel nanoparticles. As a result, over the promoted Ni_0.39Mn_0.61YO_3.11±δ catalyst, a stable catalytic performance with high HAc conversion (100%) and hydrogen yield (2.68 mol_H₂ ·mol_HAc^-1) was recorded, showing potential for hydrogen production.
- biomass,
- heterogeneous catalysis,
- hydrogen energy,
- nickel,
- perovskite phases
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沈阳化工大学材料科学与工程学院沈阳 110142