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Citation: YAO Shou-Guang, DOU Fei, LIU Dun, CHENG Jie. Electrochemical Performance of Mn and Mg Co-doped Ni(OH)2[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(1): 95-102. doi: 10.11862/CJIC.2021.014 shu

Electrochemical Performance of Mn and Mg Co-doped Ni(OH)2

  • 1.

    School of Energy and Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China

  • 2.

    Chilwee Power Co., Ltd., Huzhou, Zhejiang 313100, China

  • Corresponding author: YAO Shou-Guang, zjyaosg@126.com
  • Received Date: 16 July 2020
    Revised Date: 12 November 2020

Figures(7)

  • To reduce costs and improve performance of the positive electrode materials, the buffer solution method was used to prepare manganese and magnesium doped nickel hydroxide, labeled as Ni0.82Mn0.18-xMgx(OH)2 (x=0.06, 0.09, 0.12). XRD, XPS and SEM tests were used to characterize the crystal structure, manganese valence state and morphology of the samples. Cyclic voltammetry and constant current charge-discharge tests were used to study the influence of Mn and Mg doping ratio on the electrochemical performance of Ni(OH)2. The results showed that the samples doped Mn and Mg were all β-phase and the crystal particles were smaller; Ni0.82Mn0.09Mg0.09(OH)2 showed excellent electrode reaction reversibility and charge-discharge performance. Specific discharge capacity (290.6 mAh·g-1) of Ni0.82Mn0.09Mg0.09(OH)2 was better than that of the commercial β-Ni(OH)2 (281.1 mAh·g-1) at 100 mA·g-1; moreover, after cycling for 30 cycles at a current density of 500 mA·g-1, the specific discharge capacity of Ni0.82Mn0.09Mg0.09(OH)2 was no decay, indicating its cycle stability is better than that of the commercial β-Ni(OH)2.
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