Citation: LUO Jing, LIU Jian-Xiong, HUANG Ling, XIAO Fang-Ming, LI Wen-Chao, TANG Ren-Heng, WANG Ying. Preparation and Characterization of LiNi_0.88Co_0.07Al_0.05O₂ as a High Nickel Cathode Material[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(1): 110-120. doi: 10.11862/CJIC.2021.010 shu

Preparation and Characterization of LiNi_0.88Co_0.07Al_0.05O₂ as a High Nickel Cathode Material

LUO Jing ^1,2,3 ,
LIU Jian-Xiong ¹ ,
HUANG Ling ^2,3 ,
XIAO Fang-Ming ^2,3 ,
LI Wen-Chao ^2,3 ,
TANG Ren-Heng ^2,3 ,
WANG Ying ^2,3,,

1.
School of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China
2.
Guangdong Provincial Key Laboratory of Rare Earth Development and Application, Guangzhou 510650, China
3.
Institute of Rare Metals, Guangdong Academy of Sciences, Guangzhou 510650, China

Corresponding author: WANG Ying, wy2228086@163.com
Received Date: 22 July 2020
Revised Date: 26 October 2020

Figures(12)

In this work, Ni_0.88Co_0.07Al_0.05(OH)₂ was synthesized by aluminum isopropoxide hydrolysis of nickel-cobalt hydroxide as raw material. The precursor was fully mixed with lithium source, and spherical LiNi_0.88Co_0.07Al_0.05O₂ cathode material was prepared through three sintering conditions. The crystalline structure, morphology and electrochemical performance were systematically characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscope (TEM), X-ray photoelectronic spectroscopy (XPS) and electrochemical tests. It is found that the synthesized LiNi_0.88Co_0.07Al_0.05O₂ after 500℃ for 3 h, and 700℃ for 14 h has a good comprehensive electrochemical performance. The discharge specific capacity at 0.2C was up to 192.2 mAh·g^-1, the first charge-discharge efficiency was 81.6%, and the discharge specific capacity at 1C was 190.7 mAh·g^-1, and still remain in 141.1 mAh·g^-1 after 100 weeks, which shows the capacity retention rate of 73.4%.
- lithium ion battery,
- cathode material,
- LiNi_0.88Co_0.07Al_0.05O₂,
- hydrolysis of aluminum isopropoxide,
- sintering method
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Characterization of LiNi0.88Co0.07Al0.05O2 as a High Nickel Cathode Material

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通讯作者: 陈斌, bchen63@163.com

Preparation and Characterization of LiNi_0.88Co_0.07Al_0.05O₂ as a High Nickel Cathode Material