Citation: LI Li. Preparation, Structures and Thermal Stabilities of Four Transition Metal Complexes Constructed by 3, 7-Di(3-pyridyl)-1, 5-dioxa-3, 7-diazacyclooctane Bipyridine Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(1): 121-130. doi: 10.11862/CJIC.2021.009 shu

Preparation, Structures and Thermal Stabilities of Four Transition Metal Complexes Constructed by 3, 7-Di(3-pyridyl)-1, 5-dioxa-3, 7-diazacyclooctane Bipyridine Ligand

LI Li ^,

School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou, Jiangsu 215009, China

Corresponding author: LI Li, leeleaa@163.com
Received Date: 11 February 2020
Revised Date: 27 October 2020

Figures(7)

Four transition metal complexes, [Co(NO₃) (H₂O)₂(L)₂]NO₃ (1), [Co₂Cl₄(L)₂] ·CH₂Cl₂ (2), [Cd₂(AcO)₄(L)₂] ·4CH₃OH (3) and[Cd₂(NO₃)₂(CH₃OH)₂(H2O)₂(L)2](NO₃)₂·2H₂O (4), were synthesized by employing a clamplike bipyridine ligand 3, 7-di(3-pyridyl)-1, 5-dioxa-3, 7-diazacyclooctane (L). Single-crystal X-ray analysis reveals that complex 1 is mononuclear structure; 2 is macrocyclic dimer; wheras 3 and 4 are rectangular dinuclear structures. The ligand molecules in these complexes has shown three types of coordination mode including mono-dentate, trans-bridge and cis-bridge. All of the complexes were also characterized by elemental analysis, IR, thermal stabilities and singlecrystal structure analysis.CCDC: 940778, 1; 915840, 2; 1446573, 3; 1446574, 4.
- cobalt,
- cadmium,
- 3, 7-di(3-pyridyl)-1, 5-dioxa-3, 7-diazacyclooctane,
- bipyridine,
- crystal structure
1. [1]
  Kumar S, Mandon D. Inorg. Chem., 2015, 54(15):7481-7491 doi: 10.1021/acs.inorgchem.5b01096
2. [2]
  Geyer F L, Rominger F, Vogtland M, Bunz U H F. Cryst. Growth Des., 2015, 15(7):3539-3544 doi: 10.1021/acs.cgd.5b00719
3. [3]
  Wang Z J, Qin L, Zhang X, Chen J X, Zheng H G. Cryst. Growth Des., 2015, 15(3):1303-1310 doi: 10.1021/cg501708b
4. [4]
  Jones C D, Tan J C, Lloyd G O. Chem. Commun., 2012, 48(15):2110-2112 doi: 10.1039/c2cc16691g
5. [5]
  Zhao Q, Liu X M, Song W C, Bu X H. Dalton Trans., 2012, 41(22):6683-6688 doi: 10.1039/c2dt00002d
6. [6]
  Li N, Jiang F L, Chen L, Li X J, Chen Q H, Hong M C. Chem. Commun., 2011, 47(8):2327-2329 doi: 10.1039/C0CC04601A
7. [7]
  Carlucci L, Ciani G, Proserpio D M, Rizzato S. CrystEngComm, 2002, 4(22):121-129 doi: 10.1039/b201288j
8. [8]
  Fiscus J E, Shotwell S, Layland R C, Hipp R E, Goforth A M, Chap-man C T, Smith M D, Bunz U H, Loye H C. J. Chem. Crystallogr., 2005, 35(11):903-912 doi: 10.1007/s10870-005-5136-6
9. [9]
  Mukherjee P S, Min K S, Arif A M, Stang P J. Inorg. Chem., 2004, 43(20):6345-6350 doi: 10.1021/ic0493088
10. [10]
  Li J C, Li H X, Li H Y, Gong W J, Lang J P. Cryst. Growth Des., 2016, 16(3):1617-1625 doi: 10.1021/acs.cgd.5b01721
11. [11]
  Caradoc-Davies P L, Hanton L R. Dalton Trans., 2003, 9:1754-1758
12. [12]
  Grosshans P, Jouaiti A, Bulach V, Planeix J M, Hosseini M W, Kyrit-sakas N. Eur. J. Inorg. Chem., 2004(3):453-458
13. [13]
  Braga D, Polito M, D' Addari D, Tagliavini E, Proserpio D M, Grepi-oni F, Steed J W. Organometallics, 2003, 22(22):4532-4538 doi: 10.1021/om030432t
14. [14]
  Li G B, Liu J M, Cai Y P, Sun C Y. Cryst. Growth Des., 2011, 11(7): Fig.7 PXRD patterns of complex 12763-2772
15. [15]
  SHI W D, ZHENG D H, WANG M. Chinese J. Inorg. Chem., 2015, 31(11):2205-2512
16. [16]
  ZHOU J, DONG S F, QIAO Y F, DU L, YAN T, XIE M J, ZHAO Q H. Chinese J. Inorg. Chem., 2015, 31(11):2095-2102
17. [17]
  Li L, Li H Y, Ren Z G, Lang J P. Eur. J. Inorg. Chem., 2014(5):824-830
18. [18]
  CrystalStructure, Single Crystal Structure Analysis Software, Ver. 3.00, Rigaku/MSC, 9009 New Trails Drive, The Woodlands, TX, USA.
19. [19]
  Sheldrick G M. Acta Crystallogr. Sect. A, 2008, A64(1):112-122
20. [20]
  Schönleber A, Smaalen S, Larsen F K. Acta Crystallogr. Sect. C, 2010, C66(4):m107-m109
21. [21]
  Rogan J, Poleti D, Karanović L, Bogdanović G, Biré A S, Petrović D M. Polyhedron, 2000, 19(11):1415-1421 doi: 10.1016/S0277-5387(00)00435-6
22. [22]
  Liu D, Zi Y Q, Ng S W. Acta Crystallogr. Sect. E, 2011, E67(11):m1621
23. [23]
  Biradha K, Fujita M. Chem. Commun., 2002, 17:1866-1867
24. [24]
  Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordi-nation Compounds, Part B: Applications in Coordination, Organome-tallic, and Bioinorganic Chemistry. 6th ed. Hoboken: John Wiley & Sons, Inc., 2009.
25. [25]
  Palma B F E, Piotrowski E A, Sundaram S, Cleveland F F. J. Mol. Spectrosc., 1964, 13(1/2/3/4):119-131
1. [1]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
2. [2]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
3. [3]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
4. [4]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
5. [5]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
6. [6]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
7. [7]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
8. [8]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
9. [9]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
10. [10]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
11. [11]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
12. [12]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
13. [13]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
14. [14]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
15. [15]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
16. [16]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
17. [17]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
18. [18]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
19. [19]
  Zhaodong WANG . In situ synthesis, crystal structure, and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 597-604. doi: 10.11862/CJIC.20240268
20. [20]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(1187)
HTML views(142)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142