Citation: LIU De-Zheng, YANG Gao-Yuan, XIANG Wen-Hao, WANG Song, LI Wang-Nan, ZHONG Jie, HUANG Fu-Zhi, CHEN Mei-Hua, LIANG Gui-Jie. Perovskite Solar Cells Based on 1D/0D Ordered Composite SnO₂ Nanocrystal[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(1): 85-94. doi: 10.11862/CJIC.2021.005 shu

Perovskite Solar Cells Based on 1D/0D Ordered Composite SnO₂ Nanocrystal

1.
Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices, Hubei University of Arts and Science, Xiangyang, Hubei 441053, China
2.
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China

Corresponding author: CHEN Mei-Hua, yunluo886@163.com LIANG Gui-Jie, guijie-liang@hotmail.com
Received Date: 12 July 2020
Revised Date: 16 September 2020

Figures(8)

Novel 1D/0D ordered composite SnO₂ nanocrystal electron transport layer (ETL) for pervoskite solar cells has been prepared by adjusting the density of one-dimensional (1D) nanorod arrays through adding functional additives in hydrothermal precursors, followed by depositing zero-dimensional (0D) nanoparticles between the nanorods. The effect of the NaCl additives in the precursor and the subsequent deposition of nanoparticles on the morphology, optical and interfacial charge transfer properties of the composite ETL was systematically studied, and the mechanism of the above effects on the photovoltaic performance of the device was discussed. The results show that the addition of NaCl in the precursor thins the rods' density, so that the following 0D nanoparticles penetrated smoothly into the gaps of 1D nanorods, inducing the obvious inhibitory effect on the perovskite/ETL and perovskite/FTO interface charge recombination, which is the direct reason for the increase in open circuit voltage and fill factor of the device. In summary, the excellent charge recombination inhibition (composite resistance was 2.9 times that of conventional 1D nanorod arrays ETL-2Cl) and efficient electron extraction performance (extraction rate and efficiency were 3.03×10⁷ s^-1 and 91.6%, respectively) of the novel 1D/0D ordered composite ETL-2P contributed to the better photoelectric performance of the device (with photoelectric efficiency of 12.15%).
- composite SnO₂ nanocrystals,
- morphology control,
- nanostructures,
- electron transport,
- perovskite solar cells
1. [1]
  Kojima A, Teshima K, Shirai Y, Miyasaka T. J. Am. Chem. Soc., 2009, 131(17):6050-6051 doi: 10.1021/ja809598r
2. [2]
  Im J H, Lee C R, Lee J W, Park S W, Park N G. Nanoscale, 2011, 3(10):4088-4093 doi: 10.1039/c1nr10867k
3. [3]
  Kim H S, Lee C R, Im J H, Lee K B, Moehl T, Marchioro A, Moon S J, Humphry-Baker R, Yum J H, Moser J E, Grätzel M, Park N G. Sci. Rep., 2012, 2(1):591-597
4. [4]
  Lee M M, Teuscher J, Miyasaka T, Murakami T N, Snaith H J. Science, 2012, 338(6107):643-647 doi: 10.1126/science.1228604
5. [5]
  Burschka J, Pellet N, Moon S J, Humphry-Baker R, Gao P, Nazeeruddin M K, Grätzel M. Nature, 2013, 499(7458):316-319 doi: 10.1038/nature12340
6. [6]
  Jeon N J, Nam N J, Kim Y C, Yang W S, Ryu S, Seok S I. Nat. Mater., 2014, 13(9):897-903 doi: 10.1038/nmat4014
7. [7]
  Jeon N J, Noh J H, Yang W S, Kim Y C, Ryu S, Seo J, Seok S I. Nature, 2015, 517(7535):476-480 doi: 10.1038/nature14133
8. [8]
  Yang W S, Park B W, Jung E H, Jeon N J, Kim Y C, Lee D U, Shin S S, Seo J, Kim E K, Noh J H, Seok S I. Science, 2017, 356(6345):1376-1379 doi: 10.1126/science.aan2301
9. [9]
  Jiang Q, Zhao Y, Zhang X W, Yang X L, Chen Y, Chu Z M, Ye Q F, Li X X, Yin Z G, You J B. Nat. Photonics, 2019, 13(7):460-466 doi: 10.1038/s41566-019-0398-2
10. [10]
  Liang J, Wang C X, Wang Y R, Xu Z R, Lu Z P, Ma Y, Zhu H F, Hu Y, Xiao C C, Yi X, Zhu G Y, Lv H L, Ma L B, Chen T, Tie Z X, Jin Z, Liu J. J. Am. Chem. Soc., 2016, 138(49):15829-15832 doi: 10.1021/jacs.6b10227
11. [11]
  Liang J, Zhao P Y, Wang G X, Wang Y R, Hu Y, Zhu G Y, Ma L B, Liu J, Jin Z. J. Am. Chem. Soc., 2017, 139(40):14009-14012 doi: 10.1021/jacs.7b07949
12. [12]
  Liang J, Wang J, Jin Z. Solar RRL, 2017, 1(10):1700086 doi: 10.1002/solr.201700086
13. [13]
  Liang J, Wang C X, Zhao P Y, Lu Z P, Ma Y, Xu Z R, Wang Y R, Zhu H F, Hu Y, Zhu G Y, Ma L B, Chen T, Tie Z X, Liu J, Jin Z. Nanoscale, 2017, 9(33):11841-11845 doi: 10.1039/C7NR03530F
14. [14]
  Ma L B, Zhang W J, Zhao P Y, Liang J, Hu Y, Chen R P, Tie Z X, Liu J, Jin Z. J. Mater. Chem. A, 2018, 6(41):20076-20082 doi: 10.1039/C8TA08116F
15. [15]
  Liang J, Zhu G Y, Wang G X, Zhao P Y, Wang Y R, Hu Y, Ma L B, Tie Z X, Liu J, Jin Z. Nano Energy, 2018, 52:239-245
16. [16]
  NREL, Best Research-Cell Efficiencies Chart, https://www.nrel.gov/pv/assets/pdfs/best-research-cell-efficiencies.20200218.pdf
17. [17]
  Sun C, Wu Z H, Yip H L, Zhang H, Jiang X F, Xue Q F, Hu Z C, Hu Z H, Shen Y, Wang M K, Huang F, Cao Y. Adv. Energy Mater., 2016, 6(5):1501534-1501543 doi: 10.1002/aenm.201501534
18. [18]
  Xu X B, Liu Z H, Zuo Z X, Zhang M, Zhao Z X, Shen Y, Zhou H P, Chen Q, Yang Y, Wang M K. Nano Lett., 2015, 15(4):2402-2408
19. [19]
  Zuo L J, Guo H X, deQuilettes D W, Jariwala S, Marco N D, Dong S Q, DeBlock R, Ginger D S, Dunn B, Wang M K, Yang Y. Sci. Adv., 2017, 3(8):e1700106-e1700116 doi: 10.1126/sciadv.1700106
20. [20]
  Son D Y, Im J H, Kim H S, Park N G. J. Phys. Chem. C, 2014, 118(30):16567-16573 doi: 10.1021/jp412407j
21. [21]
  Hu G F, Guo W X, Yu R M, Yang X N, Zhou R R, Pan C F, Wang Z L. Nano Energy, 2016, 23:27-33 doi: 10.1016/j.nanoen.2016.02.057
22. [22]
  Haque M A, Sheikh A, Guan X, Wu T. Adv. Energy Mater., 2017, 7(20):1602803-1602825 doi: 10.1002/aenm.201602803
23. [23]
  Leijtens T, Eperon G E, Pathak S, Abate A, Lee M M, Snaith H J. Nat. Commun., 2013, 4(1):2885-2891
24. [24]
  Li W Z, Zhang W, Reenen S V, Sutton R J, Fan J D, Haghighirad A A, Johnston M B, Wang L D, Snaith H J. Energy Environ. Sci., 2016, 9(2):490-498
25. [25]
  Yang J L, Siempelkamp B D, Mosconi E, Angelis F D, Kelly T L. Chem. Mater., 2015, 27(12):4229-4236 doi: 10.1021/acs.chemmater.5b01598
26. [26]
  KıLıÇ Ç, Zunger A. Phys. Rev. Lett., 2002, 88:095501-095504 doi: 10.1103/PhysRevLett.88.095501
27. [27]
  Zhang C X, Deng X S, Zheng J F, Zhou X, Shi J H, Chen X H, Sun Z, Huang S M. Electrochim. Acta, 2018, 283:1134-1145 doi: 10.1016/j.electacta.2018.07.028
28. [28]
  Liu C W, Zhu R X, Ng A, Ren Z W, Cheung S H, Du L L, So S K, Zapien J A, Djurišić A B, Phillips D L, Surya C. J. Mater. Chem. A, 2017, 5(30):15970-15980 doi: 10.1039/C7TA03710D
29. [29]
  Mahmood K, Swain B S, Amassian A. Adv. Energy Mater., 2015, 5(17):1500568-1500578 doi: 10.1002/aenm.201500568
30. [30]
  Bi D, Boschloo G, Schwarzmüller S, Yang L, Johansson E M J, Hag-feldt A. Nanoscale, 2013, 5(23):11686-11691 doi: 10.1039/c3nr01542d
31. [31]
  Zhao X Y, Shen H P, Sun R J, Luo Q, Li X, Zhou Y, Tai M Q, Li J B, Gao Y F, Li X, Lin H. Solar RRL, 2018, 2(5):1700194-1700202 doi: 10.1002/solr.201700194
32. [32]
  Yang L K, Wang X, Mai X M, Wang T, Wang C, Li X, Murugadoss V, Shao Q, Angaiah S, Guo Z H. J. Colloid Interface Sci., 2019, 534:459-468 doi: 10.1016/j.jcis.2018.09.045
33. [33]
  Chen M M, Wan L, Kong M Q, Hu H, Gan Y S, Wang J, Chen F X, Guo Z G, Eder D, Wang S M. J. Alloys Compd., 2017, 738:422-431
34. [34]
  Li S B, Zhang P, Wang Y F, Sarvari H, Liu D T, Wu J, Yang Y J, Wang Z M, Chen Z D. Nano Res., 2017, 10:1092-1103 doi: 10.1007/s12274-016-1407-0
35. [35]
  Zhang X K, Rui Y C, Wang Y Q, Xu J L, Wang H Z, Zhang Q H, Müller-Buschbaun P. J. Power Sources, 2018, 402:460-467 doi: 10.1016/j.jpowsour.2018.09.072
36. [36]
  Vayssieres L, Chanéac C, Tronc E, Jolivet J P J. J. Colloid Interface Sci., 1998, 205(2):205-212
37. [37]
  Liu B, Aydil E S. J. Am. Chem. Soc., 2009, 131(11):3985-3990 doi: 10.1021/ja8078972
38. [38]
  Hosono E, Fujihara S, Kakiuchi K, Imai H J. J. Am. Chem. Soc., 2004, 126(25):7790-7791 doi: 10.1021/ja048820p
39. [39]
  Feng X J, Zhai J, Jiang L. Angew. Chem., 2005, 44(32):5115-5118 doi: 10.1002/anie.200501337
40. [40]
  Baena J P C, Steier L, Tress W, Saliba M, Neutzner S, Matsui T, Giordano F, Jacobsson T J, Kandada A R S, Zakeeruddin S M, Petro-zza A, Abate A, Nazeeruddin M K, Grätzel M, Hagfeldt A. Energy Environ. Sci., 2015, 8(10):2928-2934
41. [41]
  Song J X, Zheng E Q, Bian J, Wang X F, Tian W J, Sanehira Y, Mi-yasaka T. J. Mater. Chem. A, 2015, 3(20):10837-10844 doi: 10.1039/C5TA01207D
42. [42]
  Xue J J, Wang R, Wang K L, Wang Z K, Yavuz I, Wang Y, Yang Y G, Gao X Y, Huang T Y, Nuryyeva S, Lee J W, Duan Y, Liao L S, Kaner R, Yang Y. J. Am. Chem. Soc., 2019, 141(35):13948-13953
43. [43]
  Li J C, Dong X F, Liu T, Liu H L, Wang S R, Li X G. ACS Appl. Mater. Interfaces, 2020, 12(17):19439-19446 doi: 10.1021/acsami.0c00762
44. [44]
  ZHANG D N, LIU J, LI W N, CHEN M H, WANG J Y, WU K F, LIANG G J. Science Sinica Chimica, 2018, 48(1):74-84
45. [45]
  Wang Q, Ito S, Grätzel M, Fabregat-Santiago F, Mora-SeróI, Bisquert J, Bessho T, Imai H J. J. Phys. Chem. B, 2006, 110(50):25210-25221 doi: 10.1021/jp064256o
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沈阳化工大学材料科学与工程学院沈阳 110142

Perovskite Solar Cells Based on 1D/0D Ordered Composite SnO2 Nanocrystal

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通讯作者: 陈斌, bchen63@163.com

Perovskite Solar Cells Based on 1D/0D Ordered Composite SnO₂ Nanocrystal