Citation: YANG Xiao-Kun, CHEN A-Ling, YI Qing-Feng. Easy Preparation of N-Doped Graphene-like Nanosheets as Excellent Metal-Free Cathodic Electrocatalysts of Zn-Air Battery[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(1): 157-170. doi: 10.11862/CJIC.2021.001 shu

Easy Preparation of N-Doped Graphene-like Nanosheets as Excellent Metal-Free Cathodic Electrocatalysts of Zn-Air Battery

1.
School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan 411201, China
2.
Hunan Provincial Key Lab of Advanced Materials for New Energy Storage and Conversion, Xiangtan, Hunan 411201, China

Corresponding author: YI Qing-Feng, yqfyy2001@hnust.edu.cn
Received Date: 19 July 2020
Revised Date: 28 October 2020

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Carbon-based materials have been paid much attention due to their own good electroactivity and resources availability. Herein, we reported a simple and versatile synthesis strategy for the preparation of nitrogen-doped and metal-free carbon catalysts with excellent oxygen reduction reaction (ORR) electroactivity. Using dicyandiamide (DCD) as nitrogen source and sucrose, β-cyclodextrin and chitosan as different carbon sources, N-doped graphene-like nanosheet samples CN-nanosh(suc), CN-nanosh(cyc) and CN-nanosh(ch) were prepared by an easy pyrolysis of their mixture. The samples exhibited outstanding ORR electroactivity in alkaline media with a comparable performance to the benchmark Pt/C. Alkaline Zn-air battery with the prepared sample CN-nanosh(suc) as the cathodic catalyst displayed the maximum power density of 201.33 mW·cm^-2, and its discharge time can last for more than 50 h at a constant current density of 100 mA·cm^-2, which is close to the optimum values of the similar Zn-air battery with the metal-free cathodic electrocatalysts reported so far.
- oxygen reduction reaction,
- Zn-air battery,
- electrochemistry,
- energy conversion,
- nanoparticles
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