Citation: CHEN Wei-Miao, SONG Xian-Gen, DING Yun-Jie. Construction of Metal-Promoter (Support) Interfaces within Rh based Catalyst for Direct Synthesis of C₂ Oxygenates from Syngas[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(11): 2005-2013. doi: 10.11862/CJIC.2020.234 shu

Construction of Metal-Promoter (Support) Interfaces within Rh based Catalyst for Direct Synthesis of C₂ Oxygenates from Syngas

1.
Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning 116023, China
2.
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning 116023, China

Corresponding author: DING Yun-Jie, dyj@dicp.ac.cn
Received Date: 6 July 2020
Revised Date: 3 September 2020

Figures(9)

It is of great significance to produce C₂ oxygenated compounds such as ethanol directly from CO hydrogenation via coal, natural gas or biomass that can replace the traditional oil and food routes. The supported promoted-Rh is the most effective catalyst to realize this transformation. The Rh-promoter (support) contact interfaces are the active sites for the formation of C₂ oxygenates from syngas, thus the contact interface areas directly determines the performance of the catalyst. Therefore, recently many researchers have been working on various physical or chemical methods to improve the preparation process of Rh-based catalysts to maximize the metal-promoter interfaces. In this paper, the principle, process, advantages and disadvantages of these methods (coating, formation of composite oxide or alloy, strong electrostatic adsorption, controlled surface reaction method and atomic layer deposition) are briefly introduced and reviewed. Through the combination of the above synthesis methods, it is possible to prepare the catalysts with uniform distribution of well-defined active sites at the interface.
- CO hydrogenation,
- C₂-oxygenates,
- Rh,
- metal-promoter interface,
- construction strategy
1. [1]
  Farrell A E, Plevin R J, Turner B T, et al. Science, 2006, 311:506-508 doi: 10.1126/science.1121416
2. [2]
  Zhou W, Kang J C, Cheng K, et al. Angew. Chem. Int. Ed., 2018, 57:12012-12016 doi: 10.1002/anie.201807113
3. [3]
  Jiao F, Li J J, Pan X L, et al. Science, 2016, 351:1065-1068 doi: 10.1126/science.aaf1835
4. [4]
  Wang C T, Zhang J, Qin G Q, et al. Chem, 2020, 6:646-657 doi: 10.1016/j.chempr.2019.12.007
5. [5]
  Subramani Ⅴ, Gangwal S K. Energy Fuels, 2008, 22:814-839 doi: 10.1021/ef700411x
6. [6]
  Luk H T, Mondelli C, Ferre D C, et al. Chem. Soc. Rev., 2017, 46:1358-1426 doi: 10.1039/C6CS00324A
7. [7]
  Zhang Y K, Ding C M, Wang J W, et al. Catal. Sci. Technol., 2019, 9:1581-1594 doi: 10.1039/C8CY02593B
8. [8]
  Kang J C, He S, Zhou W, et al. Nat. Commun., 2020, 11:827 doi: 10.1038/s41467-020-14672-8
9. [9]
  Gorodetskii Ⅴ Ⅴ, Nieuwenhuys B E, Sachtler W M H. Appl. Surf. Sci., 1981, 1:355-371
10. [10]
  CHEN Wei-Miao, DING Yun-Jie, XUE Fei, et al. Chem. Ind. Eng. Prog., 2014, 33:1753-1762
11. [11]
  CHEN Wei-Miao, DING Yun-Jie, XUE Fei, et al. Acta Phys.-Chim. Sin., 2015, 31:1-10
12. [12]
  XUE Fei, CHEN Wei-Miao, SONG Xian-Gen, et al. Acta Phys.-Chim. Sin., 2015, 32:2769-2775
13. [13]
  Chen W M, Ding Y J, Xue F, et al. Catal. Commun., 2016, 85:44-47 doi: 10.1016/j.catcom.2016.07.016
14. [14]
  Pan X L, Fan Z L, Chen W, et al. Nat. Mater., 2007, 6:507-511 doi: 10.1038/nmat1916
15. [15]
  Liu J, J Guo Z, Childers D, et al. J. Catal., 2014, 313:149-158 doi: 10.1016/j.jcat.2014.03.002
16. [16]
  Liu Y F, Goeltl F, Ro Ⅰ, et al. ACS Catal., 2017, 7:4550-4563 doi: 10.1021/acscatal.7b01381
17. [17]
  Yang N Y, Yoo J S, Schumann J, et al. ACS Catal., 2017, 7:5746-5757 doi: 10.1021/acscatal.7b01851
18. [18]
  Liu Y F, Zhang L F, Goltl F, et al. ACS Catal., 2018, 8:10707-10720 doi: 10.1021/acscatal.8b02461
19. [19]
  Huang X, Teschner D, Dimitrakopoulou M, et al. Angew. Chem. Int. Ed., 2019, 58:8709-8713 doi: 10.1002/anie.201902750
20. [20]
  Mei D, Rousseau R, Kathmann S M, et al. J. Catal., 2010, 271:325-342 doi: 10.1016/j.jcat.2010.02.020
21. [21]
  Liu J J, Tao R Z, Guo Z, et al. ChemCatChem, 2013, 5:3665-3672 doi: 10.1002/cctc.201300479
22. [22]
  Mo X H, Gao J, Umnajkaseam N, et al. J. Catal., 2009, 267:167-176 doi: 10.1016/j.jcat.2009.08.007
23. [23]
  Kip B J, Smeets P A T, van Grondelle J, et al. Appl. Catal., 1987, 33:181-208 doi: 10.1016/S0166-9834(00)80592-8
24. [24]
  Ishiguro S, Ito S, Kunimori K. Catal. Today, 1998, 45:197-201 doi: 10.1016/S0920-5861(98)00215-6
25. [25]
  Yamagishi T, Furikado Ⅰ, Ito S, et al. J. Mol. Catal. A, 2006, 244:201-212 doi: 10.1016/j.molcata.2005.09.011
26. [26]
  Ⅰto S, Chibana C, Nagashima K, et al. Appl. Catal. A, 2002, 236:113-120 doi: 10.1016/S0926-860X(02)00283-1
27. [27]
  Burch R, Hayes M J. J. Catal., 1997, 165:249-261 doi: 10.1006/jcat.1997.1482
28. [28]
  Chen W M, Ding Y J, Song X G, et al. Appl. Catal. A, 2011, 407:231-237 doi: 10.1016/j.apcata.2011.08.044
29. [29]
  Schuenemann Ⅴ, Trevino H, Sachtler W M H, et al. J. Phys. Chem., 1995, 99:1317-1321 doi: 10.1021/j100004a036
30. [30]
  Schunemann Ⅴ, Trevino H, Lei G D, et al. J. Catal., 1995, 153:144-157 doi: 10.1006/jcat.1995.1116
31. [31]
  Palomino R M, Magee J W, Llorca J, et al. J. Catal., 2015, 329:87-94 doi: 10.1016/j.jcat.2015.04.033
32. [32]
  Carrillo P, Shi R, Teeluck K, et al. ACS Catal., 2018, 8:7279-7286 doi: 10.1021/acscatal.8b02235
33. [33]
  Ⅰchikawa M, Fukushima T, Yokoyama T, et al. J. Phys. Chem., 1986, 90:1222-1224 doi: 10.1021/j100398a003
34. [34]
  Gogate M R, Davis R J. ChemCatChem, 2009, 1:295-303 doi: 10.1002/cctc.200900104
35. [35]
  Wang Y, Luo H Y, Liang D B, et al. J. Catal., 2000, 196:46-55 doi: 10.1006/jcat.2000.3026
36. [36]
  Underwood R P, Bell A T. Appl. Catal., 1987, 34:289-310 doi: 10.1016/S0166-9834(00)82463-X
37. [37]
  ZHANG Wei, LUO Hong-Yuan, ZHOU Huan-Wen, et al. Nat. Gas Chem. Ind., 1998, 23(6):1-4
38. [38]
  Gallaher G R, Goodwin J G, Huang C S, et al. J. Catal., 1993, 140:453-463 doi: 10.1006/jcat.1993.1098
39. [39]
  Yang N Y, Liu X Y, Asundi A S, et al. Catal. Lett., 2018, 148:289-297 doi: 10.1007/s10562-017-2223-1
40. [40]
  Ro Ⅰ, Resasco J, Christopher P. ACS Catal., 2018, 8:7368-7387 doi: 10.1021/acscatal.8b02071
41. [41]
  Ichikawa M, Fukushima T. J. Chem. Soc. Chem. Commun., 1985:321-323
42. [42]
  van Deelen T W, Mejia C H, de Jong K P. Nat. Catal., 2019, 2:955-970 doi: 10.1038/s41929-019-0364-x
43. [43]
  Tauster S J, Fung S C. J. Catal., 1978, 55:29-35 doi: 10.1016/0021-9517(78)90182-3
44. [44]
  Tauster S J, Fung S C, Baker R T K, et al. Science, 1981, 211:1121-1125 doi: 10.1126/science.211.4487.1121
45. [45]
  Tauster S J. Acc. Chem. Res., 1987, 20:389-394 doi: 10.1021/ar00143a001
46. [46]
  Zhang S Y, Plessow P N, Willis J J, et al. Nano Lett., 2016, 16:4528-4534 doi: 10.1021/acs.nanolett.6b01769
47. [47]
  Barcaro G, Agnoli S, Sedona F, et al. J. Phys. Chem. C, 2009, 113:5721-5729 doi: 10.1021/jp811020s
48. [48]
  Matsubu J C, Zhang S Y, DeRita L, et al. Nat. Chem., 2017, 9:120-127 doi: 10.1038/nchem.2607
49. [49]
  Pham T, Gibb A L, Li Z L, et al. Nano Lett., 2016, 16:7142-7147 doi: 10.1021/acs.nanolett.6b03442
50. [50]
  Krasheninnikov A Ⅴ, Nordlund K. J. Appl. Phys., 2010, 107:071301 doi: 10.1063/1.3318261
51. [51]
  Resasco J, Dai S, Graham G W, et al. J. Phys. Chem. C, 2018, 122:25143-25157 doi: 10.1021/acs.jpcc.8b03959
52. [52]
  Choi Y, Liu P. J. Am. Chem. Soc., 2009, 131:13054-13061 doi: 10.1021/ja903013x
53. [53]
  Ro Ⅰ, Xu M J, Graham G W, et al. ACS Catal, 2019, 9:10899-10912 doi: 10.1021/acscatal.9b02111
54. [54]
  Hakim S H, Sener C, Alba-Rubio A C, et al. J. Catal., 2015, 328:75-90 doi: 10.1016/j.jcat.2014.12.015
55. [55]
  Aragao Ⅰ B, Ro Ⅰ, Liu Y, et al. Appl. Catal. B, 2018, 222:182-190 doi: 10.1016/j.apcatb.2017.10.004
56. [56]
  Singh J A, Yang N, Bent S. F. Annu. Rev. Chem. Biomol. Eng., 2017, 8:41-62 doi: 10.1146/annurev-chembioeng-060816-101547
57. [57]
  Lee J C, Jackson D H K, Li T, et al. Energy Environ. Sci., 2014, 7:1657-1660 doi: 10.1039/c4ee00379a
58. [58]
  Onn T M, Zhang S, Arroyo-Ramirez L, et al. ACS Catal., 2015, 5:5696-5701 doi: 10.1021/acscatal.5b01348
59. [59]
  Lu J L, Fu B S, Kung M C, et al. Science, 2012, 335:1205-1208 doi: 10.1126/science.1212906
60. [60]
  Singh J A, Thissen N F W, Kim W H, et al. Chem. Mater., 2018, 30:663-670 doi: 10.1021/acs.chemmater.7b03818
61. [61]
  Zhang L F, Ball M R, Liu Y F, et al. ACS Catal., 2019, 9:1810-1819 doi: 10.1021/acscatal.8b04649
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沈阳化工大学材料科学与工程学院沈阳 110142

Construction of Metal-Promoter (Support) Interfaces within Rh based Catalyst for Direct Synthesis of C2 Oxygenates from Syngas

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通讯作者: 陈斌, bchen63@163.com

Construction of Metal-Promoter (Support) Interfaces within Rh based Catalyst for Direct Synthesis of C₂ Oxygenates from Syngas