Citation: WU Nian-Nian, ZHAO Ming-Ming, LIU Sheng-Jun, LIU Bo. Preparation, Crystal Structure and Characterization of One-Dimensional Europium-Doped Titanium-Oxo Cluster of Ti₄Eu₂O₄(OOCC₆H₅)₁₄[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(11): 2080-2086. doi: 10.11862/CJIC.2020.231 shu

Preparation, Crystal Structure and Characterization of One-Dimensional Europium-Doped Titanium-Oxo Cluster of Ti₄Eu₂O₄(OOCC₆H₅)₁₄

WU Nian-Nian ¹ ,
ZHAO Ming-Ming ¹ ,
LIU Sheng-Jun ^1,2,, ,
LIU Bo ^1,,

1.
School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, China
2.
School of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan, Anhui 243032, China

Corresponding author: LIU Sheng-Jun, lsj1990@mail.ustc.edu.cn LIU Bo, liuchem@ustc.edu.cn
Received Date: 20 April 2020
Revised Date: 24 June 2020

Figures(7)

Single crystal Ti₄Eu₂O₄(OOCC₆H₅)₁₄ (denoted as POTi₄Eu₂) was prepared by the solvothermal method, via the strategy of concurrently fully carboxylate-coordinating and the lanthanide-Eu(Ⅲ)-ion-doping. Characterizations of POTi₄Eu₂ have been performed by elemental analysis, thermogravimetric analysis, solid-state UV-Vis absorption spectroscopy and FT-IR, and its particular optical properties have been shown by liquid-state fluorescence spectra, and solid-state fluorescence lifetime. The structure of POTi₄Eu₂ contains four TiO₆ octahedrons, two EuO₈ dodeca-hedrons and 14 bridged bidentate benzoic acid ligands. The cluster core Ti₄Eu₂ is stabilized by 14 benzoic acid ligands. The 14 benzoic acid ligands are coordinated by bidentate bridges and are distributed around the core clusters of the titanium oxide cluster. The adjacent clusters are bridged by benzoic acid ligands to form a one-dimensional chain structure. Thermogravimetric analysis data show that the structure of single crystal POTi₄Eu₂ could remain stable within 256℃ in air. The average fluorescence lifetime of single crystal POTi₄Eu₂ was 1.63 ms.CCDC: 1997261.
- polyoxotitanates,
- Eu(Ⅲ)-ion-doping,
- solvothermal method,
- single crystal,
- optical properties
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Preparation, Crystal Structure and Characterization of One-Dimensional Europium-Doped Titanium-Oxo Cluster of Ti4Eu2O4(OOCC6H5)14

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Preparation, Crystal Structure and Characterization of One-Dimensional Europium-Doped Titanium-Oxo Cluster of Ti₄Eu₂O₄(OOCC₆H₅)₁₄