Citation: XU Zhong-Xuan, LI Li-Feng, XU Shi-Fei, CHEN Xue-Ting. Two Zinc(Ⅱ) Coordination Polymers with 4-Fold Interpenetration Frameworks and dia Nets Based on 5-(Hydroxymethyl) Isophthalic Acid: Syntheses, Crystal Structures and Fluorescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(11): 2087-2092. doi: 10.11862/CJIC.2020.230 shu

Two Zinc(Ⅱ) Coordination Polymers with 4-Fold Interpenetration Frameworks and dia Nets Based on 5-(Hydroxymethyl) Isophthalic Acid: Syntheses, Crystal Structures and Fluorescence Properties

School of Chemistry and Chemical Engineering, Zunyi Normal College, Zunyi, Guizhou 563002, China

Corresponding author: XU Zhong-Xuan, xuzhongxuan4201@163.com
Received Date: 4 May 2020
Revised Date: 25 June 2020

Figures(4)

Under solvothermal condition, 5-(hydroxymethyl) isophthalic acid (H₂HIPA) and Zn(Ⅱ) ions reacted with 1, 4-bis(2-methyl-1H-imidazol-1-yl) benzene (1, 4-BMIB) and 1, 2-di(pyridin-4-yl)ethene (dpee) to obtain two coordination polymers[Zn(HIPA)(1, 4-BMIB)]_n (1) and {[Zn(HIPA)(dpee)]·0.5dpee}_n (2), respectively. Single crystal X-ray diffraction analyses reveal that Zn(Ⅱ) center adopts a slightly distorted tetrahedral geometry in complex 1. And then, Zn (Ⅱ) ions are further connected together by HIPA^2- and 1, 4-BMIB ligands to form a 3D framework with nano-channels, which is up to 1.2 nm×2.0 nm. For such a very empty framework, structural interpenetration is difficult to avoid. Further analysis finds that the whole framework of complex 1 is a 4-fold interpenetration structure. From a topological viewpoint, the Zn(Ⅱ) ions are 4-connected nodes, whilst HIPA^2- and 1, 4-BMIB ligands are simple linkers. So, the whole framework of 1 is topologically represented as a 4-connected dia net. Although the Zn(Ⅱ) center in complex 2 has a different pentagonal bipyramid model, the HIPA^2- and dpee as simple linkers are connected by two Zn (Ⅱ) centers, respectively. Therefore, the final framework of 2 is still a 4-fold interpenetration dia net like 1. Furthermore, the dpee not only participates in constructing the framework as auxiliary ligand, but also exists in complex 2 as guest molecule. UV-Vis spectra showed that complexes 1 and 2 had strong absorption spectra in ultraviolet region, while solid fluorescence measurements revealed that they possessed blue fluorescence properties with emission peaks at about 414 and 440 nm, respectively.CCDC: 2000801, 1; 2000802, 2.
- zinc(Ⅱ) complex,
- 5-(hydroxymethyl) isophthalic acid,
- 4-fold interpenetration structure,
- dia net,
- fluorescence property
1. [1]
  Li J R, Sculley J, Zhou H C. Chem. Rev., 2012, 112:869-932 doi: 10.1021/cr200190s
2. [2]
  Yoon M, Srirambalaji R, Kim K. Chem. Rev., 2012, 112:1196-1231 doi: 10.1021/cr2003147
3. [3]
  Zhang W, Xiong R G. Chem. Rev., 2012, 112:1163-1195 doi: 10.1021/cr200174w
4. [4]
  Cui Y, Yue Y F, Qian G D, et al. Chem. Rev., 2012, 112:1126-1162 doi: 10.1021/cr200101d
5. [5]
  Zhang T, Jin Y H, Shi Y S, et al. Coord. Chem. Rev., 2019, 380:201-229 doi: 10.1016/j.ccr.2018.10.001
6. [6]
  Chen T F, Han S Y, Wang Z P, et al. Appl. Catal. B, 2019, 259:118047 doi: 10.1016/j.apcatb.2019.118047
7. [7]
  Lu L, Wu B Y, Shi W, et al. Inorg. Chem. Front., 2019, 6:3456-3467 doi: 10.1039/C9QI00964G
8. [8]
  Ganguly S, Mukherjee S, Dastidar P, et al. Cryst. Growth Des., 2016, 16:5247-5259 doi: 10.1021/acs.cgd.6b00805
9. [9]
  Sun Y X, Sun W Y. Chin. Chem. Lett., 2014, 25:823-828 doi: 10.1016/j.cclet.2014.04.032
10. [10]
  Deng W T, Shen Z B, Su L J, et al. Cryst. Growth Des., 2018, 18:587-591 doi: 10.1021/acs.cgd.7b01584
11. [11]
  Zhao Y, Wang L, Fan N N, et al. Cryst. Growth Des., 2018, 18:7114-7121 doi: 10.1021/acs.cgd.8b01290
12. [12]
  Zhao Y, Yang X G, Lu X M, et al. Inorg. Chem., 2019, 58:6215-6221 doi: 10.1021/acs.inorgchem.9b00450
13. [13]
  Zhu X F, Wang S T, Han H T, et al. Cryst. Growth Des., 2018, 18:225-229 doi: 10.1021/acs.cgd.7b01127
14. [14]
  Aulakh D, Islamoglu T, Bagundes V F, et al. Chem. Mater., 2018, 30:8332-8342 doi: 10.1021/acs.chemmater.8b03885
15. [15]
  Yu L L, Wang X M, Chen M L, et al. Cryst. Growth Des., 2018, 18:280-285 doi: 10.1021/acs.cgd.7b01219
16. [16]
  LI Xiu-Mei, YANG Jia-Qi, PAN Ya-Ru, et al. Chinese J. Inorg. Chem., 2020, 36(4):730-736
17. [17]
  Evans J D, Coudert F. J. Am. Chem. Soc., 2016, 138:6131-6134 doi: 10.1021/jacs.6b02781
18. [18]
  LIN Xing-Ye, YANG Ming-Xing, CHEN Li-Juan. Chinese J. Inorg. Chem., 2020, 36(4):643-650
19. [19]
  Corma A, García H, Xamena F X L I. Chem. Rev., 2010, 110:4606-4655 doi: 10.1021/cr9003924
20. [20]
  Xu Z X, Ma Y L. Chin. J. Struct. Chem., 2017, 36(7):1193-1198
21. [21]
  Kanoo P, Matsuda R, Sato H, et al. Inorg. Chem., 2013, 52:10735-10737 doi: 10.1021/ic401924d
22. [22]
  Liu Q F, Liu W, Cao Y P, et al. Inorg. Nano-Met. Chem., 2017, 47:65-68 doi: 10.1080/15533174.2016.1149719
23. [23]
  Dolomanov O V, Bourhis L J, Gildea R J, et al. J. Appl. Cryst., 2009, 42:339-341 doi: 10.1107/S0021889808042726
24. [24]
  Sheldrick G M. Acta Crystallogr. Sect. C, 2015, C71:3-8
25. [25]
  Speck A L. Acta Crystallogr. Sect. C, 2015, C71:9-18
26. [26]
  Aexandrov E V, Blatov V A, Kochetkov A V, et al. CrystEngComm, 2011, 13:3947-3958 doi: 10.1039/c0ce00636j
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