Citation: ZHANG Wei-Min, JIA Han-Qiong, HU Su-Fang, MA Jing-Hong, LI Rui-Feng. Promotion Effect of Surfactant AEO-3 on Synthesis of β Zeolites[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(10): 1917-1924. doi: 10.11862/CJIC.2020.219 shu

Promotion Effect of Surfactant AEO-3 on Synthesis of β Zeolites

College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: MA Jing-Hong, majinghong@tyut.edu.cn
Received Date: 23 April 2020
Revised Date: 20 August 2020

Figures(6)

The effect of the nonionic surfactant primary alcobol ethoxylate (AEO-3) as an additive on the crystallization of β zeolites was investigated by adding it into the conventional hydrothermal synthesis system of the β zeolites with a formula of n_Al₂O₃:n_SiO₂:n_Na₂O:n_TEAOH:n_H₂O:n_AEO-3:n_C₂H₅OH=(0.28~1):40:1.55:10:640:(0.45~7.69):11.37. It was indicated that the addition of AEO-3 could promote the formation of aluminosilicate sol and increase the degree of its homogenization, as well as the yield of the product. The as-synthesized samples were characterized by X-ray diffraction, N₂ and Ar adsorption-desorption, scanning electron microscope, NMR and n-decane adsorption. The results showed that the nano particles of β zeolites were more complete and uniform, the crystallinity and micropore volume increased by the addition of surfactant AEO-3, and the yield of product, Si/Al ratio and acid strength increased as well. In addition, the addition of AEO-3 increased the proportion of chiral polymorph A in the structure of β zeolites.
- zeolites,
- hydrothermal synthesis,
- AEO-3,
- crystallinity,
- yield of product,
- polymorph A
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