Citation: ZHANG Wen-Yan, YANG Yang, HUANG Hui-Lin, JING Xu, DUAN Chun-Ying. Photocatalytic Hydrogen Production Based on Metal-Organic Triangle Modified by Fluorescein Isothiocyanate[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(10): 1988-1996. doi: 10.11862/CJIC.2020.206 shu

Photocatalytic Hydrogen Production Based on Metal-Organic Triangle Modified by Fluorescein Isothiocyanate

Zhang Dayu School of Chemistry, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: JING Xu, xjing@dlut.edu.cn
Received Date: 19 May 2020
Revised Date: 17 June 2020

Figures(8)

A cobalt based metal-organic[3+3] self-assembly macrocycle was constructed by tridentate Schiff base ligand L1 with N, O and P atoms (L1=1, 1'-biphenyl-4, 4'-di-carbohydrazide-bis-(2-diphenyphosphinobenzaldehyde)). The functionalized metal-organic triangle with amino groups was connected to photoactive fluorescein isothiocyanate (FITC) via post-assembly modification reaction. This modified complex Co-L3 was used as photocatalyst for hydrogen evolution from water splitting. It was a two-component system for hydrogen production without extra photosensitizer. Besides, compared with the three-component system, the metallosupramolecular catalyst Co-L3 underwent post-assembly modification reactions exhibited higher photocatalytic activity at the same metal catalyst and photosensitizer concentration with a turnover number (TON) of 80, which was approximately 30 times the photocatalytic efficiency of complex Co-L1.
- metal-organic macrocycle,
- cobalt,
- light-driven H₂ production,
- post-assembly modification
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