Citation: LUO Jie-Wei, ZHAO Bo, ZHANG Shi-Lu, JIA Fei-Yun, LIU Jun. Fluorescent Probe Based on Morpholine Derivatives for Fe³⁺/Cu²⁺[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(10): 1845-1852. doi: 10.11862/CJIC.2020.202 shu

Fluorescent Probe Based on Morpholine Derivatives for Fe³⁺/Cu²⁺

Basic Medical School, North Sichuan Medical College, Nanchong, Sichuan 637000, China

Corresponding author: LUO Jie-Wei, luojiewei198021@163.com
Received Date: 12 February 2020
Revised Date: 24 May 2020

Figures(14)

A fluorescent probe L was synthesized using 9-anthracene aldehyde as fluorescent group with pyrazoline and morpholine as recognition group, and its structure was characterized by ¹H NMR and ¹³C NMR. The ion recognition performance of probe L was investigated by fluorescence emission spectra and ultraviolet absorption spectra. The results show that L has strong selective recognition performance for Fe³⁺ and Cu²⁺ with the fluorescence quantum yield decreasing from 0.47 to 0.21 and 0.14, respectively. The selective recognition for L to Fe³⁺ and Cu²⁺ was distinguished by naked eye along with color change from pale yellow to brown and blue, respectively. In addition, a three-input"NOR"logic gate circuit was constructed at the molecular level by the quantum yield of L for Fe³⁺, Cu²⁺ and H⁺ in different combinations.
- morpholine derivative,
- "NOR" logic gate,
- iron ion,
- copper ion
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Fluorescent Probe Based on Morpholine Derivatives for Fe3+/Cu2+

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通讯作者: 陈斌, bchen63@163.com

Fluorescent Probe Based on Morpholine Derivatives for Fe³⁺/Cu²⁺