Citation: TANG Ai-Ju, MI Chang-Huan, CHEN Pei-Pei. Preparation of NiCoAl LDH with Different Ni Contents and Electrochemical Performance of CNT/Ni_0.3CoAl LDH Material[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(10): 1906-1916. doi: 10.11862/CJIC.2020.198 shu

Preparation of NiCoAl LDH with Different Ni Contents and Electrochemical Performance of CNT/Ni_0.3CoAl LDH Material

Jiangsu Key Laboratory of Electrochemical Energy Storage Technologies, College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China

Corresponding author: MI Chang-Huan, mchmse@nuaa.edu.cn
Received Date: 19 April 2020
Revised Date: 17 June 2020

Figures(10)

One-step synthesis of NiCoAl-layered double hydroxide (NiCoAl LDH) with different ratios of nickel and cobalt by hydrothermal method, and the electrochemical performance of NiCoAl LDH with different contents of Ni in nickel and cobalt metal elements were investigated. Ni_0.3CoAl LDH materials have the best electrochemical performance when the molar ratio of Ni to Co was 3:7. Part of Ni element in the lattice was replaced by Co element, which is helpful to reduce the oxidation potential and improve the chemical reversibility of the material. Then the CNT/Ni_0.3CoAl LDH composite was synthesized by hydrothermal method, and the carbon nanotubes improved the conductivity of the material. At a current density of 1 A·g^-1, the specific capacitance of CNT/Ni_0.3CoAl LDH was as high as 1 332 F·g^-1. When the current density was increased to 10 A·g^-1, the capacity retention can reach 60.4%, and the CNT/Ni_0.3CoAl LDH electrode still exhibited an cycling stability with 87.6% retention at a current density of 5 A·g^-1 for 3 000 cycles.
- carbon nanotubes,
- composite,
- hydrothermal method,
- electrochemical performance
1. [1]
  Zubi G, Rodolfo D L, Carvalho M, et al. Renewable Sustain-able Energy Rev., 2018, 89:292-308
2. [2]
  Zou C F, Hu X S, Wei Z B, et al. IEEE Trans. Ind. Electron., 2017, 65(8):6635-6645
3. [3]
  Tajik S, Dubal D P, Gomez-Romero P, et al. Int. J. Hydrogen Energy, 2017, 42(17):12384-12395 doi: 10.1016/j.ijhydene.2017.03.117
4. [4]
  Xia Q Y, Xu M, Xia H, et al. ChemNanoMat, 2016, 2(7):588-600 doi: 10.1002/cnma.201600110
5. [5]
  Gao L, Surjadi J U, Cao K, et al. ACS Appl. Mater. Interfaces, 2017, 9(6):5409-5418 doi: 10.1021/acsami.6b16101
6. [6]
  Zhang X, Wang S L, Xu L, et al. Ceram. Int., 2017, 43(16):14168-14175 doi: 10.1016/j.ceramint.2017.09.182
7. [7]
  Shao M F, Ning F Y, Zhao Y F, et al. Chem. Mater., 2012, 24(6):1192-1197 doi: 10.1021/cm203831p
8. [8]
  Yang J, Yu C, Fan X M, et al. Electrochim. Acta, 2017, 255:15-22 doi: 10.1016/j.electacta.2017.09.155
9. [9]
  NIE Hong-Qian, HOU Wan-Guo. Acta Phys.-Chim. Sin., 2011, 27(8):1783-1796 doi: 10.3866/PKU.WHXB20110826
10. [10]
  Corrigan D A, Bendert R M. J. Electrochem. Soc., 1989, 136(3):723-728
11. [11]
  Yang J, Yu C, Fan X M, et al. Adv. Energy Mater., 2014, 4(18):1400761 doi: 10.1002/aenm.201470099
12. [12]
  ZHANG Xiao-Gang, LIU Xian-Ming, BAO Shu-Juan, et al. Chinese J. Inorg. Chem., 2004, 20(1):94-98
13. [13]
  PU Ying-Hui, DU Dong-Feng, YU Shi-Fan, et al. Chinese J. Inorg. Chem., 2018, 34(11):1983-1990
14. [14]
  Zhang W M, Chen J, Swiegers G F, et al. Nanoscale, 2010, 2(2):282-286 doi: 10.1039/B9NR00140A
15. [15]
  Kaempgen M, Ma J, Gruner G, et al. Appl. Phys. Lett., 2007, 90(26):264104 doi: 10.1063/1.2749187
16. [16]
  Gueon D, Hwang J T, Yang S B, et al. ACS Nano, 2018, 12(1):226-233 doi: 10.1021/acsnano.7b05869
17. [17]
  Xia H, Wang Y, Lin J Y, et al. Nanoscale Res. Lett., 2012, 7(1):33-43 doi: 10.1186/1556-276X-7-33
18. [18]
  Xu C, Kong X, Zhou S, et al. J. Mater. Chem. A, 2018, 6(47):24050-24057
19. [19]
  Yang J, Yu C, Fan X M, et al. J. Mater. Chem. A, 2013, 1(6):1963-1968 doi: 10.1039/c2cp43642f
20. [20]
  Lai F, Huang Y, Miao Y E, et al. Electrochim. Acta, 2015, 100(174):456-463 doi: 10.1039/c2nr31750h
21. [21]
  Wang B, Williams G R, Chang Z, et al. ACS Appl. Mater. Interfaces, 2014, 6(18):16304-16311 doi: 10.1021/am504530e
22. [22]
  Zhang Y, Du D F, Li X J, et al. ACS Appl. Mater. Interfaces, 2017, 9(37):31699-31709 doi: 10.1021/acsami.7b04792
23. [23]
  Zhang X, Wang S L, Xu L, et al. Ceram. Int., 2017, 43(16):14168-14175 doi: 10.1016/j.ceramint.2017.07.159
24. [24]
  Liu F, Chen Y Y, Liu Y, et al. Nanoscale, 2019, 1(20):9896-9905
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Preparation of NiCoAl LDH with Different Ni Contents and Electrochemical Performance of CNT/Ni0.3CoAl LDH Material

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通讯作者: 陈斌, bchen63@163.com

Preparation of NiCoAl LDH with Different Ni Contents and Electrochemical Performance of CNT/Ni_0.3CoAl LDH Material