Citation: OU Jin-Hua, HU Bo-Nian, HE Sai-Yu, HAN Yu. Metal-Organic Framework Thin-Film Derived CoSe₂/N Co-doped Carbon Film as an Efficient Counter Electrode for Dye-Sensitized Solar Cells[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(9): 1683-1689. doi: 10.11862/CJIC.2020.195 shu

Metal-Organic Framework Thin-Film Derived CoSe₂/N Co-doped Carbon Film as an Efficient Counter Electrode for Dye-Sensitized Solar Cells

OU Jin-Hua ^1,, ,
HU Bo-Nian ¹ ,
HE Sai-Yu ¹ ,
HAN Yu ^2,3,,

1.
Department of Material and Chemical Engineering, Hunan Institute of Technology, Hengyang, Hunan 421002, China
2.
Faculty of Infrastructure Engineering, Dalian University of Technology, Dalian, Liaoning 116024, China
3.
Liaoning Province Building Science Research Institute Co., Ltd., Shenyang 110005, China

Corresponding author: OU Jin-Hua, oujinhua98@126.com HAN Yu, hanyu2010@mail.dlut.edu.cn
Received Date: 30 January 2020
Revised Date: 10 May 2020

Figures(6)

Aiming at the problems of complex preparation process and difficult to control film thickness of powder MOF-derived materials, we used a facile method to prepare the CoSe₂ and N co-doped carbon film (CoSe₂/N-CF) derived from metal-organic framework thin film materials (PIZA-1) as counter electrode in DSSC, which takes advantage of simple preparation, strong adhesion and adjustable thickness. The morphology, structure and electrochemical performance of CoSe₂/N-CF were systematic characterized and the relationship between film thickness and size of CoSe₂ with photovoltaic performance of DSSC was discussed. The CoSe₂/N-CF-15 exhibited outstanding catalytic activity and remarkable power conversion efficiency (PCE) of 8.68%, which is higher than that of Pt (7.97%).
- dye-sensitized solar cells,
- metal organic framework thin film,
- counter electrode,
- CoSe₂,
- carbon film
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Metal-Organic Framework Thin-Film Derived CoSe₂/N Co-doped Carbon Film as an Efficient Counter Electrode for Dye-Sensitized Solar Cells