Citation: LÜ Xue-Yi, LIU Jun-Guo, ZHU Yan-Yan. CoP Nanocage-Based Efficient Non-enzymatic Glucose Electrochemical Sensor[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(9): 1675-1682. doi: 10.11862/CJIC.2020.193 shu

CoP Nanocage-Based Efficient Non-enzymatic Glucose Electrochemical Sensor

1.
College of Biological Science and Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China
2.
College of Pharmacy, Hebei Medical University, Shijiazhuang 050017, China

Corresponding author: LIU Jun-Guo, 1308676013@qq.com ZHU Yan-Yan, zhuyanyan@hebmu.edu.cn
Received Date: 27 February 2020
Revised Date: 15 June 2020

Figures(6)

Transition metal cobalt phosphide (CoP) nanocage was prepared by a combination of hydrothermal and calcination method. Scanning electron microscope (SEM), transmission electron microscope (TEM), scanning trans-mission electron microscope (STEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) were used to characterize the morphology, structure, and elemental composition of CoP. The study found that the synthesized CoP had a hollow nanocage structure, which is conducive to providing more accessible catalytic active sites, promoting the transport of electrons or ions, and accelerating the catalytic reaction process. Cyclic voltammetry (CV) and chronoamperometry studies displayed that CoP nanocages had excellent electrocatalytic oxidation activity toward glucose. The non-enzymatic glucose electrochemical sensor based on the CoP nanocage modified glassy carbon electrode showed excellent performance. The sensor has wide linear ranges (0.04~3 mmol·L^-1 and 3~8 mmol·L^-1), low detection limit (3.8 μmol·L^-1), high sensitivity, good selectivity, repeatability, reproducibility and stability. In addition, the sensor can be applied to quickly determination of glucose in real human serum sample.
- electrochemistry,
- sensor,
- cyclic voltammetry,
- CoP nanocage,
- electrocatalytic activity,
- glucose
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1.
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